• Title/Summary/Keyword: Magnetic nanocomposite

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Synthesis of conducting and magnetic nanocomposite of cross-linked aniline sulfide resin

  • Hosseini, Seyed Hossein
    • Advances in materials Research
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    • v.3 no.4
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    • pp.233-242
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    • 2014
  • Magnetic and conducting aniline sulfide resin cross-linked (ASC-Fe3O4) nanocomposite has been prepared in the presence of aniline sulfide resin (ASR), aniline, $Fe_3O_4$ coated by polyethylene glycol (PEG) and initiator. The magnetic properties of the resulting composites showed ferromagnetic behavior, such as high-saturated magnetization (Ms= 41 emu/g), and coercive force (Hc=1.5 Oe). The saturated magnetization was increased by increasing of $Fe_3O_4$ content and decreased by increasing aniline ratio. The transmission electron micrograph (TEM) and X-ray diffraction proved that nanometer-sized about 20-30 nm $Fe_3O_4$ in the composite. The average size of ASC-$Fe_3O_4$ nanocomposite with core-shell structure was about 50-60 nm, and polydisperse. This approach may also be extended to the synthesis and modification of other polymers. Electrical conductivity of aniline sulfide resin cross-linked (ASC) nanocomposite has been studied by four-point probe method and produced $3.3{\times}10^{-4}S/cm$ conductivity for it. The conductivity of the composites at room temperature depended on the $Fe_3O_4$, aniline ratio and doping degree. The thermogravimetry analysis (TGA) results showed that this resin is thermal resistance near of $500^{\circ}C$. So, It can be used for resistance thermal coating for military applications. $Fe_3O_4$-PASC nanocomposite has been flexible structure with electrical and magnetic properties.

Microstructure and Magnetic Properties of $Nd_2Fe_{14}B/{\alpha}-Fe$ Nanocomposite Prepared by HDDR Combined with Mechanical Milling

  • Hu, Lianxi;Wang, Erde;Guo, Bin;Shi, Gang
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09b
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    • pp.1286-1287
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    • 2006
  • [ $Nd_2Fe_{14}B/{\alpha}-Fe$ ] nanocomposite powders with a nominal composition of $Nd_{12}Fe_{82}B_6$ were prepared by HDDR combined with mechanical milling. The microstructure was studied by Mossbauer spectrometry and TEM. The magnetic properties were investigated by VSM using bonded magnet samples. The results showed that the annealing temperature had significant influence on both the recombination kinetics and the grain size of the $Nd_2Fe_{14}B$ and ${\alpha}-Fe$ phases, and the bonded magnets presented the best magnetic properties when the nanocomposite powders were prepared by annealing at $760^{\circ}C$ for 30 min.

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Buckling of sandwich plates with FG-CNT-reinforced layers resting on orthotropic elastic medium using Reddy plate theory

  • Shokravi, Maryam
    • Steel and Composite Structures
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    • v.23 no.6
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    • pp.623-631
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    • 2017
  • Present paper deals with the temperature-dependent buckling analysis of sandwich nanocomposite plates resting on elastic medium subjected to magnetic field. The lamina layers are reinforced with carbon nanotubes (CNTs) as uniform and functionally graded (FG). The elastic medium is considered as orthotropic Pasternak foundation with considering the effects of thermal loading on the spring and shear constants of medium. Mixture rule is utilized for obtaining the effective material properties of each layer. Adopting the Reddy shear deformation plate theory, the governing equations are derived based on energy method and Hamilton's principle. The buckling load of the structure is calculated with the Navier's method for the simply supported sandwich nanocomposite plates. Parametric study is conducted on the combined effects of the volume percent and distribution types of the CNTs, temperature change, elastic medium, magnetic field and geometrical parameters of the plates on the buckling load of the sandwich structure. The results show that FGX distribution of the CNTs leads to higher stiffness and consequently higher buckling load. In addition, considering the magnetic field increases the buckling load of the sandwich nanocomposite plate.

Synthesis and Characterization of SiO2/Fe2O3 Nanocomposite Particles for Hyperthermia (온열치료용 SiO2/Fe2O3 나노복합입자의 제조와 특성)

  • Yu, Ji-Hun;Lee, Chang-Woo;Lee, Jai-Sung;Choa, Yong-Ho;Hofmann, Heinrich
    • Korean Journal of Materials Research
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    • v.13 no.9
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    • pp.613-618
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    • 2003
  • The magnetic heating effect of $SiO_2$coated $ \Upsilon-Fe_2$$O_3$nanocomposite particle due to magnetic relaxational loss of superparamagnetic regime was investigated by measuring the generated heat from nanocomposite particles in alternative applied magnetic fields. The commercial $ \Upsilon-Fe_2$$O_3$nanoparticles were coated by SiO$_2$in water solution with TEOS and the synthesized nanocomposite powders and its magnetic properties were characterized and compared with the raw$ \Upsilon-Fe_2$$O_3$nanoparticles. The 10∼30 nm sized $ \Upsilon-Fe_2$$O_3$. nanoparticles were coated by 5 nm thickness of amorphous $SiO_2$film. The nanocomposite particle has very low Mr and Hc value showing superparamagnetic behavior The magnetic heating effect of nanocomposite particle on surface coating phase of $SiO_2$was discussed in terms of superparamagnetic behaviors of each particles, and their potential for hyperthermia application was evaluated.

Design and Preparation of Magnetic CTAB/Montmorillonite Nanocomposite for Phenols Removal

  • Shen, Rong;Yu, Yichang;Wang, Yue;Xia, Zhining
    • Nano
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    • v.13 no.10
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    • pp.1850123.1-1850123.9
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    • 2018
  • The cetyltrimethyl ammonium bromide (CTAB)-modified montmorillonite (MMT) was synthesized via a novel "dissolution and reassembly" method. To determine the optimal formula, the adsorption of C.I. Reactive Red 2 (X3B) with CTAB/MMT was investigated. The optimal CTAB/MMT nanocomposite was used to remove 2,6-dichlorophenol and p-nitrophenol from aqueous solutions. The adsorption results can be described by Langmuir isotherm, and the adsorption capacities were 200 mg/g and 125 mg/g for 2,6-dichlorophenol and p-nitrophenol, respectively. To realize the quick separation and recycle, the magnetic CTAB/MMT was further strategized and synthesized. The adsorption equilibrium time was 15 min for both contaminants; the ions' strength showed a little bit of influence on the adsorption performance. In addition, compared with acidic condition, neutral condition was more beneficial to the adsorption reaction. Due to the addition of $Fe_3O_4$, the adsorption capacities of this magnetic nanocomposite for 2,6-dichlorophenol and p-nitrophenol were a little bit decreased, which were 170 mg/g and 91 mg/g, respectively. However, the magnetic nanocomposite can be separated within 30 s under an external magnetic field, which would be useful in the practical application.

Effect of α-Fe Content on the Magnetic Properties of MnBi/α-Fe Nanocomposite Permanent Magnets by Micro-magnetic Calculation

  • Li, Y.Q.;Yue, M.;Zuo, J.H.;Zhang, D.T.;Liu, W.Q.;Zhang, J.X.;Guo, Z.H.;Li, W.
    • Journal of Magnetics
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    • v.18 no.3
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    • pp.245-249
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    • 2013
  • A finite element model was built for MnBi/${\alpha}$-Fe nanocomposite permanent magnets, and the demagnetization curves of the magnets were simulated by micro-magnetic calculation. The microstructure of the cubic model is composed of 64 irregular grains with an average grain size of 20 nm. With the volume fraction of soft magnetic phase (t vol. %) ranged from 5 to 20 vol. %, both isotropic and anisotropic nanocomposite magnets show typical single-phase permanent magnets behavior in their demagnetization curves, illustrating good intergranular exchange coupling effect between soft and hard magnetic phases. With the increase of volume fraction of soft magnetic phase in both isotropic and anisotropic magnets, the coercive force of the magnets decreases monotonically, while the remanence rises at first to a peak value, then decreases. The optimal values of maximum energy products of isotropic and anisotropic magnets are 84 and $200kJ/m^3$, respectively. Our simulation shows that the MnBi/${\alpha}$-Fe nanocomposite permanent magnets own excellent magnetic properties and therefore good potential for practical applications.

Thermal Properties of Ploymide Nanocomposite (전력용 Nanocomposite의 열화학 특성)

  • Lee, Sang-Heon
    • Proceedings of the KIEE Conference
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    • 2006.10a
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    • pp.44-45
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    • 2006
  • We have fabricated superconductor ceramics by chemical process. A high Tc superconductor with a nominal composition of ${Bi_2}{Sr_2}{Ca_2}{Cu_3}{O_y}$ was prepared by the organic metal salts method. Experimental results suggest that the intermediate phase formed before the formation of the superconductorphase may be the most important factor. The relation between electromagnetic properties of Bi HTS and external applied magnetic field was studied. The electrical resistance of the superconductor was increased by the application of the external magnetic field. But the increase in the electrical resistance continues even after the removal of the magnetic field. The reason is as followsthe magnetic flux due to the external magnetic field penetrates through the superconductor and the penetrated magnetic flux is trapped after the removal of the magnetic flux.

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Dynamic stability of nanocomposite Mindlin pipes conveying pulsating fluid flow subjected to magnetic field

  • Esmaeili, Hemat Ali;Khaki, Mehran;Abbasi, Morteza
    • Structural Engineering and Mechanics
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    • v.67 no.1
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    • pp.21-31
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    • 2018
  • In this work, the dynamic stability of carbon nanotubes (CNTs) reinforced composite pipes conveying pulsating fluid flow is investigated. The pipe is surrounded by viscoelastic medium containing spring, shear and damper coefficients. Due to the existence of CNTs, the pipe is subjected to a 2D magnetic field. The radial induced force by pulsating fluid is obtained by the Navier-Stokes equation. The equivalent characteristics of the nanocomposite structure are calculated using Mori-Tanaka model. Based on first order shear deformation theory (FSDT) or Mindlin theory, energy method and Hamilton's principle, the motion equations are derived. Using harmonic differential quadrature method (HDQM) in conjunction with the Bolotin's method, the dynamic instability region (DIR) of the system is calculated. The effects of different parameters such as volume fraction of CNTs, magnetic field, boundary conditions, fluid velocity and geometrical parameters of pipe are shown on the DIR of the structure. Results show that with increasing volume fraction of CNTs, the DIR shifts to the higher frequency. In addition, the DIR of the structure will be happened at lower excitation frequencies with increasing the fluid velocity.

Exchange-coupling Interaction and Magnetic Properties of BaFe12O19/Ni0.5Zn0.5Fe2O4 Nanocomposite Ferrite (BaFe12O19/Ni0.5Zn0.5Fe2O4 나노복합체 Ferrite의 Exchange-coupling 상호 작용과 자기 특성)

  • Oh, Young-Woo
    • Journal of the Korean Magnetics Society
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    • v.24 no.3
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    • pp.81-85
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    • 2014
  • Nano-sized Ba-ferrite, Ni-Zn ferrite and $BaFe_{12}O_{19}/Ni_{0.5}Zn_{0.5}Fe_2O_4$ nanocomposite ferrite were prepared by sol-gel combustion method. Nanocomposite was calcined at temperature range of $600{\sim}900^{\circ}C$ for 1 h. According to the diffraction patterns, hard/soft nanocomposite was indicated to the coexistence of the magnetoplumbite structural $BaFe_{12}O_{19}$ and spinel $Ni_{0.5}Zn_{0.5}Fe_2O_4$ and agree with the standard data (JCPDS 10-0325). The particle size of nanocomposite turn out to be less than 90 nm. The nanocomposite ferrite shows a single-phase magnetization behavior, implying that the hard magnetic phase and soft magnetic phase were well exchange-coupled. The specific saturation magnetization ($M_s$) of the nanocomposite is located between hard ($BaFe_{12}O_{19}$) and soft ferrite ($Ni_{0.5}Zn_{0.5}Fe_2O_4$). The remanence (Mr) of nanocomposite ferrite is much higher than that for the individual $BaFe_{12}O_{19}$ and $Ni_{0.5}Zn_{0.5}Fe_2O_4$ ferrite. $(BH)_{max}$ is increased, generally.