• 한국자기학회:학술대회 개요집
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• 한국자기학회 2009년도 정기총회 및 동계학술연구발표회
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• pp.192-192
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• 2009

Magnetic and magnetotransport properties of (1-x) $La_{0.7}Sr_{0.3}MnO_3-xRE_2O_3$ (RE=La, Nd) (x = 0.025, 0.05, 0.075, 0.1, 0.2, 0.3) composite polycrystalline samples were systematically studied. Samples were prepared using conventional solid-state reaction. LSMO and $RE_2O_3$ react at high temperature and become chemically compatible. The ferromagnetic-paramagnetic transition temperatures ($T_c$) of the LSMO-$Nd_2O_3$ composite samples were decreased 313K~349K with increasing x, while the $T_c$ values of the LSMO-$La_2O_3$ composite samples were almost unaltered in the range of 355K~358K, representing that the ferromagnetism of LSMO might be more seriously degraded by Nd substitution on the ($La_{0.7}Sr_{0.3}$) site. However, LSMO-$RE_2O_3$ composite samples exhibit greatly enhanced low field magnetoresistance (LFMR) and dMR/dH value without an appreciable increase in its resistivity. Remarkably improved LFMR properties are attributed to LSMO grain boundaries acting as effective spin-dependent scattering centers. The relationship among the $RE_2O_3$ addition, microstructure, magnetic and magnetotransport properties will be discussed in this paper.

• Composites Research
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• 제30권1호
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• pp.41-45
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• 2017

Magnetite nanoparticles were synthesized by adding an ammonium hydroxide to a mixed solution of iron (II) and (III) chlorides. A silicon surfactant of ${\alpha},{\omega}$-(3-aminopropyl)polydimethylsiloxane was adsorbed on the particles as dispersant and a polydimethylsiloxane polymer was used to prepare ferrofluids of silicone oil base. Fluorinated surfactants of anionic ammoniated perfluoroalkyl sulfonamide and nonionic fluoroaliphatic polymeric esters were applied to the particles and a perfluoropolyether was used to prepare ferrofluids of fluorine oil base. The experimental conditions were used for preparing the ferrofluids with concentrations of 200, 300 and 400 mg/mL, and density, magnetization and viscosity of the products were characterized. The density values increased in proportion to the concentration, indicating 1.11-1.27 g/mL for silicone-oil-based fluids and 1.95-2.10 g/mL for fluorine-oil-based fluids in the range of 200-400 mg/mL. The saturation magnetization of the silicone-oil-based and fluorine-oil-based fluids indicated 14.7, 24.4, and 30.7 mT and 15.8, 23.3, and 33.7 mT for 200, 300, and 400 mg/mL, respectively, depending on the content of magnetic particles in the fluid. The viscosity of the silicone-oil-based ferrofluids was highly stable compared to that of the fluorine-oil-based with increasing temperatures. The ferrofluids are usually applied to seals and speakers with the silicone base and to seals with the fluorine base.

• 대한전기학회:학술대회논문집
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• 대한전기학회 2006년도 추계학술대회 논문집 전기기기 및 에너지변환시스템부문
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• pp.9-11
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• 2006

본 논문은 모터 코어용으로 사용되어지는 연자성체 분말의 열처리 조건에 따른 기계적 특성 및 자기적 특성에 대한 논문이다. 연자성체는 모터 코어 형상 제작이 일반 실리콘 강판에 비해 우수하고 고주파에서 자기적 특성이 우수한 것으로 나타났다. 따라서 현재 모터 코어용으로 많은 제작이 이루어지고 있다. 이런 연자성체는 압분 압력 및 열처리 조건 등 다양한 제조 공정에 따라 상이한 자기적 특성결과를 가져온다. 따라서 본 논문에서는 다양한 열처리 조건 중에서 연자성체의 각 온도별, holding time별 조건에 대한 자기적 특성 및 기계적 특성을 알아보고, 온도와 holding time에 대해 가장 적합한 연자성체 열처리 조건을 연구하였다. 또한 열처리시료의 재열처리를 통한 시편의 자기적 특성을 연구 제시 하였다.

• Elastomers and Composites
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• 제50권1호
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• pp.18-23
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• 2015

Vinyl acetate (VA) contents of poly(ethylene-co-vinyl acetate) (EVA) analyzed by infrared spectroscopy (IR), nuclear magnetic spectroscopy (NMR), and thermogravimetric analysis (TGA) were compared. Four grade EVAs supplied by Aldrich Co. and four grade EVAs manufactured by DuPont Co. were used. For IR analysis, VA contents were determined using calibration curve (absorbance ratio of $1739cm^{-1}/2922cm^{-1}$ or $609cm^{-1}/1464cm^{-1}$) of reference EVAs. Correlation coefficients of the calibration curves were not sufficiently high ($r^2{\leq}0.96$). For NMR analysis, VA contents were determined using peaks of $CH_3$, $CH_2$, and CH. VA contents determined by NMR analysis were less than those marked by suppliers more than 10%. For TGA, VA contents were determined using weight loss through deacetylation. VA contents determined by TGA were slightly different with those marked by suppliers. Difference in the VA contents determined by different analytical methods was discussed, and difference in the analytical results according to the EVA suppliers was also examined.

• Applied Microscopy
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• 제45권2호
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• pp.52-57
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• 2015

Bulk metallic glass (BMG) shows higth strength, high elastic limit, corrosion resistance and good wear resistance and soft magnetic properties and has been considering as a candidate for new structural materials. But they show limited macroscopic plasticity and lack of tensile ductility due to highly localized shear deformation, which should be solved for real structural application. In this paper researches on the enhancement of plasticity of BMG were reviewed briefly. Introducing heterogeneous structure in glass is effective to induce more shear transformation zones (STZs) active for multiple shear band initiation and also to block the propagating shear band. Several methods such as BMG alloy design for high Poisson's ratio, addition of alloying element having positive heat of mixing, pre-straining BMG and variety of BMG composites have been developed for homogenous distribution of locally weak region, where local strain can be initiated. Therefore enhancement of plasticity of BMG is normally accompanied with some penalty of strength loss.

• 한국소성가공학회:학술대회논문집
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• 한국소성가공학회 1997년도 고액공존금속의 성형기술 심포지엄
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• pp.16-27
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• 1997

A semi-solid forming has a lot of advantages compared to the die casting, squeeze costing and convenctional forging, therefore, semi-solid forming process are now becoming of industial interest for the production of metal components and metal matrix composites. However, the material behaviour in the semi-solid temperature range is not sufficiently known although it controls the whole process through forces and geometry evolutions bcause the behaviour of metal slurries is complex. The semi-solid materials(SSM) fabricated under electric-magnetic stirring condition is necessary to be applicate in forming process. A reheating conditions were studied with the reheating time, holing time and reheating temperatures. The microstructure of SSM (which specimen size:d 40${\times}$i60) on condition of heating time 10min and heating temperature 590$^{\circ}C$ is most globular and finest one. The microstructure of SSM(specimen size:d75${\times}$i60) reheated under the three step reheating conditions is most globular and finest.

• Elastomers and Composites
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• 제53권2호
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• pp.67-74
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• 2018

Magneto-rheological elastomers (MREs) are smart materials in which the inherent stiffness and damping properties can be changed by the influence of an external magnetic field. The magneto-rheological (MR) effect depends on the orientation characteristics of the dispersed magneto-responsible particles (MRPs) in the matrix. In this study, natural rubber (NR) and ethylene propylene diene rubber (EPDM) were blended and used as a matrix of an MRE. EPDM was pre-cured before blending with NR. The Mooney viscosity, curing characteristics, and mechanical properties were analyzed with various pre-curing conditions of EPDM and the NR/EPDM blend. The results show that excellent mechanical properties of the NR/EPDM blend-based MRE were obtained when the pre-curing time of EPDM was 60 min. The aging property of the NR-based MRE was improved by the introduction of pre-cured EPDM. Also, the anisotropic MRE showed a higher MR effect than that of the isotropic MRE.

• Elastomers and Composites
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• 제55권2호
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• pp.103-107
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• 2020

Herein, resin-formed polysilsesquioxanes (PSSQs) were synthesized using monomolecular fluoro silane as a precursor. The synthesized PSSQs exhibited anti-smudge performance and were used as coating liquid. Two structures were acquired by controlling the amount of the silane precursor and the K₂CO₃ catalyst; these materials were used to prepare the anti-smudge coating liquid solution. The synthesized product was analyzed by various methods such as nuclear magnetic resonance spectroscopy, X-ray diffraction analysis, gel permeation chromatography, and water contact angle measurement. The results confirmed that the as-synthesized PSSQs exhibited the ladder structure and had a molecular weight of 5,117 g/mol and water contact angle of 102.31°.

• 한국막학회:학술대회논문집
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• 한국막학회 2003년도 The 4th Korea-Italy Workshop
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• pp.47-50
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• 2003

Carbon-silica membranes were Prepared by Pyrolyzing polyimide/silica composite obtained from ill-situ polymerization of alkoxy silanes via sol-gel reaction. In this study, effects of silica content and silica network in polyimide matrix were focused on the gas permeation and separation properties of the final carbon-silica membrane. The membranes prepared were characterized with a field emission scanning electron microscopy (FE-SEM), a solid state $^{29}$ Si nuclear magnetic resonance spectroscopy ($^{29}$ Si-NMR), an electron spectroscopy for chemical analysis (ESCA), a thermogravimetric analysis (TGA) and gas permeation tests.

• 대한전기학회논문지
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• 제39권7호
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• pp.653-667
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• 1990

Superconductor is consolidated, for required current capacity, with proper numbers of basic strands which are multifilamentary composites. Althouth superconductors are perfectly loss-free under DC conditions of current and field, AC losses occur under time-varying condition of the current and field. The AC losses are a controllable inherent characteristics of supercondectors. The AC losses dependent on the changing rate of current and field can be reduced by reducing the filament diameter. On the other hand, finer filament results in manufacturing cost increase. Therefore, in this paper optimization technique of superconductor for SMES is proposed from the viewpoint of AC loss reduction and manufacturing cost increase. The case study shows that the technique can be effectively used for the design of superconductor for SMES, appreciating the influence of various parameters related to superconductor itself and operating condition of SMES. As a result of the case study, it is confirmed that the technique is more effective for the design of superconductor for SMES for electric power power system stabilization rather then SMES for energy storage.