• 한국산업보건학회지
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• 제26권3호
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• pp.293-300
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• 2016

Objectives: This study is designed to survey the current status of trade secrets in GHS MSDS circulated in workplaces and indicate problems in the chemical information system. According to the survey results, we suggest management plans including political improvement of the trade secret system for MSDS and technical support to workplaces following enhanced chemical communication. Methods: To review this subject, we selected 153 manufacturers and six importers working in such fields as organic chemical production. We then investigated the retention status of GHS MSDS, application of trade secrets, and the content of trade secret components in MSDSs for mixtures. Results and Conclusions: Within the results, the content of trade secret ingredients was 67.4% (single: 9.0%, mixture: 75.6%). This is an increase compared with the previous results of 45.5% in 2011. Among 59,393 GHS MSDSs, 74.5% had ingredients less than 10% trade secret components, 19.1% had 10-30%, 1.8% had 30-50%, and 4.6% had more than 50%. To settle this issue, we recommend registration or evaluation of trade secrets as implemented in advanced countries. Also, business should be required to undergo regular evaluations of application status for trade secrets in workplace GHS MSDS.

• 한국대기환경학회지
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• 제19권6호
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• pp.663-677
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• 2003

The concentrations of volatile organic compounds (VOCs) in the ambient air were measured at three sites (Samil-dong, SRO and EFMC) in Yeosu industrial complex during September 2000 to August 2001. Air samples were collected for 24 hours in Silicocan canister (6l) with constant flow samplers every 6 days and analyzed using a cryogenic preconcentration system and a GC/MS. At each site, we identified 35 species known as on both the carcinogenic and mutagenicity by the EPA US (TO-14 manual). No relationship was found between YOCs concentration at three sampling points. Furthermore, the result shows that there appears to be a variety distribution of the concentration. BTX, vinyl chloride and high concentrations of 1,2-dichloroethane were observed at the sampling sites. Especially, high concentration of toxic VOCs, such as vinyl chloride, chloroform, 1,2-dichloroethane and benzene were shown at environmental facilities management cooperation (EMFC) site. They seem to be emitted from the facility of wastewater treatment in Yeosu industrial complex. It was difficult to tell the seasonal variation of total VOCs concentration. Nevertheless, the concentration in winter was typically higher than in summer The concentrations of toxic VOCs contents in Yeosu industrial complex were generally lower than those in Ulsan complex, although those were similar or less than in Seoul and Daegu. Whereas, toluene and styrene emitted from Yeosu industrial complex were higher than those of Edmonton industrial complex in Canada. Especially, toluene was third times higher than those observed from Texas, USA.

• 한국대기환경학회지
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• 제22권4호
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• pp.468-476
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• 2006

Hazardous air pollutants (HAPs) have high toxicity and bioaccurnulation potentials into human body even inbsmall amount (levels of ng/$m^3$). As the levels of HAPs might be controversial, it has been become essential to establish the analysis method for correct results. In this study, various analysis methods of VOCs and Aldehydes were compared in order to select the proper methods in our condition. Sampling and analysis method of VOCs were followed to EPA TO-14a and TO-17. VOCs were collected in absorption tube and separated by thermal desorption unit then analyzed by GC/MSD. Aldehydes were sampled in DNPH-cartridge and extracted into solution then analyzed by HPLC as the same condition of EPA TO-13a. This study also shows the results of QA/QC system of selected methods. Some experiments could be improving the data assurance blank test, calibration check, repetition precision check, the determination of detection limit and reproducibility of the retention time. Precisions of VOCs and aldehydes were ranged in 2$\sim$9% and 1$\sim$4% RSD, respectively. Recovery rate of VOCs showed variable ranges from 60 to 133.5%. MDL of VOCs and aldehydes were 0.044$\sim$0.284 ppb and 0.14$\sim$1.02 ng, respectively.

• 한국산업보건학회지
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• 제16권2호
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• pp.81-90
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• 2006

The Strain Index(SI) has been commonly used to evaluate the musculoskeletal disorders(MSDs) of upper extremities. Recently, the American Conference of Governmental Industrial Hygienists(ACGIH) adopted the Threshold Limit Value for hand activity level (HAL TLV) focused on the hand, wrist, and forearm. The MSDs risks of 37 repetitive works conducted at an automobile climate control system manufacturing factory were evaluated using both the HAL TLV and the SI, and the results by two methods were compared. Also, measured repetitive frequencies of upper limbs joint were mesured using electromyogram and electrogoniometer. The evaluation results of the HAL were related with the repetitive frequency data of upper limbs joint by electrogoniometer, and the NPF was related with %MVC of ECU. The evaluation result of HAL TLV was highly related with the SI score(r=0.66, p<0.01). Of total 37 tasks, 25 tasks(67.6%) were exceeded the TLV and 34 tasks(91.9%) exceeded the SI limit. Although there was a high relationship between the HAL TLV and SI score, the HAL TLV underestimated the risk in comparison with the SI. The correlation coefficients(r) between the HAL TLV data and the repetitive frequency of upper limbs joint were 0.45~0.55(p<0.01). The MSD symptoms was significantly different between high risk groups and low risk groups evaluated by HAL TLV(p<0.01), but was not different between two groups by SI. In conclusion, the HAL TLV is a proper tool for repetitive works.

• 분석과학
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• 제15권3호
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• pp.300-316
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• 2002

수질 및 토양 시료 중의 PBBs의 분석방법 확립을 위해 표준물질이 준비된 PBBs 22종을 대상으로 추출 및 정제 등의 전처리 회수율 및 검출한계를 환경시료로부터 얻었다. PBBs의 시료 추출법으로 액/액, 속실렛, 초음파 추출법을 적용하였고, 실리카겔, 플로리실 정제컬럼의 적용성 검토 후 GC/MS로 분석하였다. 수질 시료의 경우 검출한계는 브롬화된 정도에 따라 약간의 차이를 보였고 5~10 ng/L이었으며, n-hexane, dichloromethane 및 toluene 등의 단일 용매의 평균회수율은 96~107%, n-hexane:acetone (1:1) 및 (9:1)의 혼합용매의 평균 회수율은 60~80%로 나타났다. 또한, 토양 시료의 경우 검출한계는 0.5~3.5 ng/g이었으며, 선정 용매의 평균 회수율은 속실렛 추출이 67~97% 및 초음파 추출이 64~76%로 나타났다.

• 한국대기환경학회지
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• 제22권5호
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• pp.724-730
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• 2006

A study on the electron beam(E-Beam) decompositions of volatile organic compounds(VOCs) under background gases(helium, nitrogen, oxygen, air) has been carried out. Hexane selected as aliphatic VOCs was irradiated with electron beam using a batch reactor in the dose range of $0{\sim}10kGy$ and at ambient temperature. The concentrations of Hexane were 140 ppmC, 300 ppmC and 600 ppmC, respectively. Irradiation treatment efficiency of Hexane was evaluated by the GC/FID, GC/MSD, and the by-products were analyzed by $CO/CO_2\;and\;O_3$ analyzers. In different concentration, the maximum degrees of Hexane decomposition at 10 kGy were 96.4%(140 ppmC), 88.3%(300 ppmC), and 49.9%(600 ppmC). It was found that the decomposition efficiency of Hexane was higher than that of toluene at the same conditions(140 ppmC). In addition, the formation of acetone, benzene, 2-hexanone, and 3-hexanone were observed after the treatment of Hexane.

• 한국환경과학회지
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• 제1권1호
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• pp.53-68
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• 1992

In order to research the adsorption removal characteristics of trace organic by-products in disinfection of drinking water by biological activated carbon(BAC), water samples disinfect- ted with $Cl_2$, $O_3$ and $ClO_2$ after treatment by fluidized-bed system with water added with humic acid(10mg/L) were investigated the formation and the removal of trihalomethanes (THMs), and the trace organic by-products by gas chromatography(GC) II gas chromatography/mass selective detector(GC/MSD). Control was used by activated carbon(AC) and water added with humic acid(HA). The results were summarized as follow : The THMs removal effect of BAC by chlorination was in lower 90 % than that of control(HA), the sorts of oxidants formed by $Cl_2$ , $O_3$ and $ClO_2$ were that $O_3$ was very fewer than $Cl_2$ or $ClO_2$, and that $ClO_2$ was fewer than $Cl_2$. The trace organic by-products were esters and phthalates etc. Based on results above, it is concluded that BAC was appeared the more desirable adsorbtion-degradation removal characteristics than that of AC.

• Safety and Health at Work
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• 제9권3호
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• pp.314-318
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• 2018

Background: Musculoskeletal disorders (MSDs) in the health industry are quite common, however, there have only been a few studies regarding physiotherapists, while in Greece, there is an apparent lack of research and data. The aim of this study is to investigate MSDs experienced by physiotherapists in Greece, their causes and specific measures, and good practices followed. Additional emerging risk factors will be examined. Methods: A questionnaire of MSDs followed by individual and workplace characteristics was completed by 252 physiotherapists. It covered the major workplace categories such as public hospitals, private rehabilitation centers, and private practices. Results: Analysis indicated that 89% of the respondents had experienced a work-related MSD; 32.2% of those injuries occurred within the first 5 years of working. The most lumbered physiotherapists were those working as private practitioners and almost half of the injured respondents chose to work while injured. The most common measure taken to tackle work related MSDs was found to be physical therapy sessions. Job satisfaction and psychosocial issues were also identified as side-effects of the economic slowdown. Conclusion: Physiotherapists in Greece were found to suffer from MSDs; workplace musculoskeletal injuries were quite common but under-reported. The body parts most affected were the lower back, the upper back, the shoulders, and the neck. There was a strong correlation between the workplace setting and the number of MSDs. A well-defined occupational safety and health management system and strict administration steering were found to reduce MSDs. The economic slowdown experienced in Greece during the execution of this study placed additional pressure on physiotherapists.

• 한국정보통신학회논문지
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• 제26권3호
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• pp.443-448
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• 2022

긴 길이의 적응 필터와 높은 상관도의 입력신호를 사용하는 적응 필터링 응용에서 적응 필터의 수렴성능을 향상 시키기 위해 가변 스텝사이즈를 이용하는 부밴드 인접투사 알고리즘을 제안한다. 제안한 알고리즘은 다위상 분해와 노블아이덴티티를 적용한 M-부밴드 구조에서 각 적응 부필터별 서로 다른 스텝사이즈를 사용함으로써 빠른 수렴속도와 작은 정상상태오차를 얻을 수 있다. 각 갱신시점에서 적응 필터의 평균자승오차를 최소화하도록 유도된 스텝사이즈는 가변 스텝사이즈를 사용하는 기존 알고리즘에 비해 좋은 수렴성능을 보인다. 기존 알고리즘에 비해 우수한 제안한 알고리즘의 수렴성능을 확인하기 위해 시스템 식별 모델을 고려하여 AR(1)과 AR(2) 유색 입력 신호에 대한 최소자승편차에 대한 컴퓨터 시뮬레이션을 수행한다.

• 한국산업보건학회지
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• 제34권1호
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• pp.8-13
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• 2024

Objectives: To evaluate the levels of exposure to organic compounds during aircraft disinfection and seat cover replacement operations. Methods: According to the working schedule, organic compounds were collected using activated carbon tubes and then analyzed by GC/FID and GC/MSD. Results: In the disinfection task, the main substances listed in the material safety data sheet (MSDS) of the disinfectant were not detected. However, 1-bromopropane, which had been used in the previous task of replacing seat covers, was detected at a level of 2.37 ppm at the measurement time. During seat cover replacement, bonding workers were exposed to 2.48 ppm on an eight-hour time-weighted average, and seat cover replacement workers were exposed to 0.22 ppm. Conclusions: It is necessary to ensure the reliability of MSDS. A work environment management system is necessary when different companies alternate working in the same place.