• Korean Journal of Environmental Agriculture
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• v.34 no.4
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• pp.309-317
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• 2015

BACKGROUND: An analytical method was developed using GC-ECD/MS to precisely determine the residue of fipronil, a phenylpyrazole insecticide used to control a wide range of foliar and soil-borne pests.METHOD AND RESULTS: Fipronil residue was extracted with acetone from representative samples of five raw products which comprised hulled rice, soybean, Kimchi cabbage, green pepper, and apple. The extract was diluted with saline water, and fipronil was partitioned into n-hexane/dichloromethane (20/80, v/v) to remove polar co-extractives in the aqueous phase. Florisil column chromatography was additionally employed for final purification of the extract. Fipronil was separated and quantitated by GC-ECD using a DB-17 capillary column. Accuracy of the proposed method was validated by the recovery from crop samples fortified with fipronil at 3 levels per crop in each triplication.CONCLUSION: Mean recoveries ranged from 86.6% to 106.0% in five representative agricultural commodities. The coefficients of variation were less than 10%. Limit of quantitation of fipronil was 0.004 mg/kg as verified by the recovery experiment. A confirmatory technique using GC/MS with selected-ion monitoring was also provided to clearly identify the suspected residue. Therefore, this analytical method was reproducible and sensitive enough to determine the residue of fipronil in agricultural commodities.

• Journal of the Korean Society of International Agriculture
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• v.30 no.4
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• pp.339-346
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• 2018

Cyanazine is a member of the triazine family of herbicides. Cyanazine is used as a pre- and post-emergence herbicide for the control of annual grasses and broadleaf weeds. This experiment was conducted to establish a determination method for cyanazine, as domestic unregistered pesticide, residue in major agricultural commodities using HPLC-DAD/MS. Cyanazine was extracted with acetone from representative samples of five raw products which comprised apple, green pepper, Kimchi cabbage, hulled rice and soybean. The extract was diluted with saline water and partitioned to dichloromethane for remove polar extractive in the aqueous phase. For the hulled rice and soybean samples, n-hexane/acetonitrile partition was additionally employed to remove non-polar lipids. The extract was finally purified by optimized florisil column chromatography. On a $C_{18}$ column in HPLC, cyanazine was successfully separated from co-extractives of sample, and sensitively quantitated by diode array detection at 220 nm. Accuracy and precision of the proposed method was validated by the recovery experiment on every major agricultural commodity samples fortified with cyanazine at 3 concentration levels per agricultural commodity in each triplication. Mean recoveries were ranged from 83.6 to 93.3% in five major representative agricultural commodities. The coefficients of variation were all less than 10%, irrespective of sample types and fortification levels. Limit of quantitation(LOQ) of cyanazine was 0.02 mg/kg as verified by the recovery experiment. A confirmatory method using LC/MS with selected-ion monitoring(SIM) technique was also provided to clearly identify the suspected residue.

• Bulletin of the Korean Chemical Society
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• v.31 no.5
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• pp.1377-1380
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• 2010

• Korean Journal of Mathematics
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• v.28 no.3
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• pp.509-524
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• 2020

The notion of fuzzy closure filters is introduced and discussed in an MS-algebra. In particular, we characterize the prime fuzzy closure filters in terms of boosters. Some relationship between the lattice of fuzzy closure filters and the fuzzy ideal lattice of boosters are explored and investigated.

• Proceedings of the Korea Contents Association Conference
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• 2015.05a
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• pp.267-268
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• 2015

카카오에 함유되어 있는 향기성분을 열탈착 가스크로마토 질량분석기(TD GC/MS)를 이용하여 실시하였다. 그 결과 hydrocarbone류 10종, alcohol류 3종, aldehyde류 7종, ketone류 3종 및 carboxylic acid류 4종 등 총 27종의 향기성분이 동정되었다. 그 중에서 carboxylic acid류의 향기성분이 55.88%로 가장 많이 함유되어 있었다. 그 다음으로 알데히드류가 13.80%, 케톤 화합물이 11.90% 그리고 모노테르펜 화합물이 11.7% 함유되어 있음을 확인하였다.

• Journal of Biomedical Engineering Research
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• v.10 no.3
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• pp.223-228
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• 1989

In this paper, the computerized interpretation of the analytical chemical data, especially GC/MS data, was performed for the purpose of prescreening of the target compounds. First, the data from the analytical instrument was analyzed to get the information about the retention time of the ISTD and the time inteval between the records. Second, the identification of the characteristic ion peaks was performed by calculating the ratio of the heights and the relative slope sensitivity of the characteristic mass abundance.

• Mass Spectrometry Letters
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• v.3 no.4
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• pp.101-103
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• 2012

The ultraviolet (UV) degradation products of photochromic naphthoxazine and naphthopyran derivatives in acetonitrile were separated and identified using liquid chromatography-mass spectrometry (LC-MS). Photodegradation resulted in oxidation of products.

• Korean Journal of Mathematics
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• v.27 no.3
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• pp.595-612
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• 2019

In this paper, we introduce the concept of ${\beta}$-fuzzy filters in MS-algebras and ${\beta}$-fuzzy filters are characterized in terms of boosters. It is proved that the lattice of ${\beta}$-fuzzy filters is isomorphic to the fuzzy ideal lattice of boosters.

• 한국정보통신설비학회:학술대회논문집
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• 2002.08a
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• pp.27-30
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• 2002

10-bit 해상도, 10MS/s의 ADC를 Stage 당 1.5-Bit의 Resolution을 가지는 Redundant signed digit(RSD) 방식의 파이프라인 구조를 이용하여 설계하였다. Error Correction Logic을 사용함으로써 비교기를 Coarse하게 설계하였고 잔류 전압 증폭기의 최적 Scaling을 통하여 일반적인 ADC에 비해 성능 저하 없이 효율적으로 소비 전력을 감소시켰다. 또한, Charge Pump의 선택적 사용을 통해 기생 커패시턴스의 영향을 최소화함으로써 잔류전압 증폭기의 출력 전압 특성을 향상 시켰다. 삼성 0.35u CMOS 공정 파라미터를 이용하여 입력 전압 $-1{\sim}1V$, 공급 전압 $-1.5{\sim}1.5V$에서 18.73mW로 설계하였으며 HSPICE로 시뮬레이션 하였다.

• Proceedings of the IEEK Conference
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• 1999.11a
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• pp.263-266
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• 1999

In this work, a A/D converter is implemented to obtain 8bit resolution at a conversion rate of 10MS/s for video applications. This architecture is proposed using the Pipelined architecture for high speed conversion rate and the Successive - Approximation architecture for low power consumption, and consists of two identical stages that consist of sample/hold circuit, low power comparator, voltage reference circuit and MDAC of binary weighted capacitor array. Proposed A/D converter is designed using 0.25${\mu}{\textrm}{m}$ CMOS technology The SNR is 80㏈ at a sampling rate of 10MHz with 1.95MHz sine input signal. When an 8bit 10MS/s A/D converter is simulated, the Differential Nonlinearity / Integral Nonlinearity (DNL/ INL) error are $\pm$0.5 / $\pm$2 LSB, respectively. The power consumption is 13㎽ at 10MS/s.