• Bulletin of the Korean Chemical Society
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• v.28 no.12
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• pp.2359-2362
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• 2007

MALDI-TOF-MS technique was applied to obtain structural and compositional information of synthetic polyamides, Nylon6 and Nylon66. Mass spectra of both the original and the hydrolyzed polyamide samples were analyzed using the self calibration method as well as the internal calibration method with the standard materials of known masses. The MALDI-TOF mass spectra of Nylon6 samples showed the presence of protonated, sodiated, and potassiated ions that were assigned to cyclic and NH2/COOH terminated linear oligomers. From the MALDI-TOF mass spectra of Nylon66 samples, the potassiated linear oligomers with three different end groups are identified as well as the cyclic oligomers, i.e., NH2/COOH terminated oligomers, NH2/NH2 terminated oligomers, and COOH/COOH terminated oligomers. Full characterization of the molecular species and end groups present in the polyamide samples has been achieved, and also the changes in mass spectral patterns after the hydrolysis of the samples are presented.

• The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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• v.7 no.2
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• pp.43-50
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• 2002

This study focused on variability of the sea water temperatures observed off the Dangjin Power Plant in the central west coast of Korea for the period of 1998-1999. Spatial averaged temperature shows the annual range of $20.3^{\circ}C$, with minimum of $3.3^{\circ}C$ in February and maximum of $23.6^{\circ}C$ in August. Horizontal distribution patterns are seasonally reversing: The temperatures are increasing toward inshore of the period of April to October, while they are increasing toward of offshore for the rest of year. Spectral analyses of temperature records show significant peaks at M2 and S2 tidal periods, since the water movement in the study area is influenced by strong tide. The responses of temperature variations to tidal phase show different seasonal characteristics: The temperatures are increasing at flood phases in winter and ebb phases in summer. Amplitudes of the components at M2 and S2 periods are $0.8^{\circ}C\;and\;0.5^{\circ}C$, accounting for 70-80% of daily variation. Coherency analyses between non-tidal components of temperature and wind speed show that in summer, northerly wind components significantly coherent with temperature at 2.8 days period, while in winter, southerly wind component is coherent with 2.4 days period, with 0.6 and 0.7 day phase-lags, respectively.