• Title/Summary/Keyword: MOF-5

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The Characteristics of Diisopropyl Methylphosphonate Adsorption on Zirconium-based Metal Organic Frameworks Manufactured by using Different Acids as Modulators (서로 다른 산을 조절인자로 활용하여 제조한 지르코늄 기반 금속유기골격체의 Diisopropyl Methylphosphonate 흡착 특성)

  • Jang, Wonhyeong;Kim, Honghyun;Jeong, Sangjo
    • Applied Chemistry for Engineering
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    • v.32 no.5
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    • pp.524-531
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    • 2021
  • Depending on the type and amount of acid used as a modulator in the manufacturing process, the structural properties of UiO-66 can be modified and the adsorbability of chemical warfare agents can be enhanced. In this study, several acids as a modulator were used to synthesize UiO-66. Their properties were analyzed with FT-IR, XRD, titrator, and adsorption isotherms using chemical warfare agent simulant, DIMP. The UiO-66, structurally damaged by hydrochloric acid as a modulator, showed lower crystallinity and DIMP adsorption capacity and also smaller specific surface area and volume of voids compared to those of UiO-66, which was manufactured using acetic acid, and formic acid as a modulator. Additionally, UiO-66 which was synthesized by adding formic acid and hydrochloric acid as a modulator, showed the highest DIMP adsorption capacity and is likely to be used as an adsorbent for chemical warfare agent in the future.

Distribution Patterns of Halophytes in the Coastal Area in Korea (우리나라 해안에 서식하는 염생식물의 분포 특징)

  • LEE, MINSOO;KIM, SEONGHWAN;JUNG, HOEIN
    • The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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    • v.24 no.1
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    • pp.139-159
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    • 2019
  • This survey was conducted from May 2017 to August 2018 as part of the National Marine Ecosystem Surveys sponsored by MOF (Ministry of Oceans and Fisheries) and KOEM (Korea Marine Environment Management Corporation). The survey was conducted at 157 stations including intertidal zones, coastal sand dunes and beaches. A total of 72 species of halophytes were identified and the total vegetated area was $1,813,546m^2$ in coastal waters of Korea. In the west coast region, Suaeda japonica was the dominant species, Phragmites communis in the southern coast, and Carex kobomugi in the east coast. Phragmites communis was the most dominant with $1,136,643m^2$ (62.7%) in the whole surveyed area. The top 11 dominant plants are Phragmites communis, Suaeda japonica, Suaeda maritima, Zoysia sinica, Carex kobomugi, Elymus mollis, Suaeda malacosperma, Phacelurus latifolius, Triglochin maritimum, Carex pumila and Carex scabrifolia, and Phragmites communis and Suaeda japonica accounted for 75.9% of the total vegetated area. The distribution of halophyte on the coast of Korea was determined by the habitat types rather than the climate ranges, and there was a difference in the species diversity and habitat range of the halophyte depending on the habitat diversities within the same area.

Acute Respiratory Distress Syndrome in Respiratory Intensive Care Unit (호흡기계 중환자실에서 치료 관리된 급성호흡곤란증후군의 임상특성)

  • Moon, Seung-Hyug;Song, Sang-Hoon;Jung, Ho-Seuk;Yeun, Dong-Jin;Uh, Su-Tack;Kim, Yong-Hoon;Park, Choon-Sik
    • Tuberculosis and Respiratory Diseases
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    • v.45 no.6
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    • pp.1252-1264
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    • 1998
  • Background : Patients with established ARDS have a mortality rate that exceeds 50 percent despite of intensive care including artificial ventilation modality, Mortality has been associated with sepsis and organ failure preceding or following ARDS ; APACHE II score ; old age and predisposing factors. Revised ventilator strategy over last 10 years especially at ARDS appeared to improve the mortality of it. We retrospectively investigated 40 ARDS patients of respiratory-care unit to examine how these factors influence outcome. Methods : A retrospective investigation of 40 ARDS patients in respiratory-care unit with ventilator management over 46 months was performed. We investigated the clinical characteristics such as a risk factor, cause of death and mortality, and also parameters such as APACHE II score, number of organ dysfunction, and hypoxia score (HS, $PaO_2/FIO_2$) at day 1, 3, 7 of severe acute lung injury, and simultaneously the PEEP level and tidal volume. Results : Clinical conditions associated with ARDS were sepsis 50%, pneumonia 30%, aspiration pneumonia 20%, and mortality rate based on the etiology of ARDS was sepsis 50%, pneumonia 67%(p<0.01 vs sepsis), aspiration pneumonia 38%. Overall mortality rate was 60%. In 28 day-nonsurvivors, leading cause of death was severe sepsis(42.9%) followed by MOF(28.6%), respiratory failure(19.1 %), and others(9.5%). There were no differences in variables of age, sex, APACHE II score, HS, and numbers of organ dysfunction at day 1 of ARDS between 28-days survivor and nonsurvivors. In view of categorized variables of age(>70), APACHE II score(>26), HS(<150) at day 1 of ARDS, there were significant differences between 28-days survivor and nonsurvivors(p<0.05). After day 1 of ARDS, the survivors have improved their APACHE II score, HS, numbers of organ dysfunction over the first 3d to 7d, but nonsurvivors did not improve over a seven-day course. There were significant differences in APACHE II score and numbers of organ dysfunction of day 3, 7 of ARDS, and HS of day 7 of ARDS between survivors and nonsurvivors(p<0.05). Fatality rate of ARDS has been declined from 68% to less than 40% between 1995 and 1998. There were no differences in APACHE II score, HS, numbers of organ dysfunction, old age at presentation of ARDS. In last years, mean PEEP level was significantly higher and mean tidal volume was significantly lower than previous years during seven days of ARDS(p<0.01). Conclusions : Improvement of HS, APACHE II score, organ dysfunction over the first 3d to 7d is associated with increased survival Decline in ARDS fatality rates between 1995 and 1998 seems that this trend must be attributed to improved supportive therapy including at least high PEEP instead of conventional-least PEEP approach in ventilator management of acute respiratory distress syndrome.

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