• Title/Summary/Keyword: MN Test

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Cation Self-Diffusin and Impurity Diffusion of Mn and Zn in CoO: (I) A comparison of the Residual Activity and the Tracer Sectioning Method

  • Lee, Jong-Ho;Martin, Manfred
    • The Korean Journal of Ceramics
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    • v.4 no.2
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    • pp.90-94
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    • 1998
  • Self diffusion coefficients of $^{67}$Co and impurity diffusion coefficients of $^{51}$Mn and $^{65}$Zn in single crystalline CoO have been measured by applying different radioactive isotopes simultaneously. To compare the residual activity method and the tracer sectioning method we analyzed our tracer diffusion experiments by using both methods simultaneously. According to our experimental results, the diffusion coefficients obtained from both methods are identical within experimental error, demonstrating the relibility of our experimental procedures. The diffusion coefficients of all the isotopes obtained during these test experiments for the methodology are similar in magnitude and show similar dependences on oxygen partial pressure. These first observations indicate that impurity diffusion of Mn and Zn occur via a vacancy mechanism as known for self diffusion of cobalt.

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The Resilient Characteristics of Typical Subgrade Soils in Korea (우리나라 대표적 노상토의 회복탄성 특성)

  • 조천환;우제윤
    • Geotechnical Engineering
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    • v.7 no.1
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    • pp.15-32
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    • 1991
  • Recently, the rational methods of pavement design and analysis using the resilient modulus, MR, as fundamental input material property have been increasingly adopted in major advanced countries. Since the development of 1986 AASHTO Guide for Design of Pavement Structures, many researches concerning the resilient characteristics of various pavement materials as well . as development of reliable testing methods have been actively performed. Anticipating the use of Mn-based pavement design and analysis such as resilient characteristics and Mn - CBR relat - ionship of domestic subgrade soils were performed including development of a standard MR test procedure suitable for subgrade soils in our country.

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Effect of Third Elements on the Microstructures and Mechanical Properties of Ti-Al Intermetallic Compounds (Ti-Al 금속간화합물의 미세조직 및 기계적 성질에 미치는 제3원소의 영향)

  • Choi, Chang-Woo;Hong, Chun-Pyo
    • Journal of Korea Foundry Society
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    • v.12 no.2
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    • pp.139-148
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    • 1992
  • The mechanical properties of Ti-Al intermetallic compounds which contain Mn, Zr, or Cr as the third element have been evaluated by means of hardness and compression tests. Microstructures have also been examined using an optical microscope. The cast structures of Ti-Al alloys are coarsened and the lamellar volume fraction is increased by the additions of Mn or V, but the cast structures are refined by the addition of Zr. Hardness tests of room temperature and compression tests at $600^{\circ}C$ showed that the mechanical properties of Ti-Al alloys were mainly dependent on the volume fraction of the ${\alpha}_2$ phase, grain size and solid solution hardening. However according to the compression test at $1000^{\circ}C$, the yield strength of Ti-Al alloys decreased with an increase in Mn or Cr content, but increased with an increase in the Zr content.

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Luminescent Properties of Two-Ions Doped Phosphors for LED Application

  • Kim, Tae-Gon;Kim, Young-Sic;Im, Seoung-Jae
    • 한국정보디스플레이학회:학술대회논문집
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    • 2009.10a
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    • pp.52-55
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    • 2009
  • A red phosphor, $(Sr,Ca)_2P_2O_7:Eu^{2+},Mn^{2+}$, for UV-LED was synthesized under a reducing atmosphere, and its luminescent properties were investigated. The phosphor absorbs ultraviolet light at around 400 nm and efficiently emits red light at approximately 610 nm through an energy transfer from $Eu^{2+}$ to $Mn^{2+}$. Using the varied input current test for the phosphor-loaded LED lamps, it was found that the luminescent efficiency of the phosphor decreased with increasing light flux. This might be due to an increased probability of excited-state absorption and the consequent non-radiative relaxation in $Mn^{2+}$ ions in the condition of high photon influx.

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Comparative Assessment of INAA and ICP-MS for the Determination of Trace Elements in Airborne Particulate Matter (대기입자 중 미량원소의 정량을 위한 기기 중성자방사화분석과 유도결합플라즈마 질량분석법의 비교 평가)

  • Lim, Jong-Myoung;Lee, Jin-Hong;Chung, Yong-Sam
    • Journal of Korean Society of Environmental Engineers
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    • v.28 no.10
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    • pp.1038-1045
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    • 2006
  • A series of experiments was conducted to test the compatibilities of two different techniques to determine elemental concentrations by INAA and ICP-MS based on both the NIST SRM 2783(air particulate on filter media) and the field samples for PM10. For NIST SRM the results of INAA were more accurate and precise for all target elements than those of ICP-MS. The comparative data set for PM10 samples collected in an industrial complex area showed that mean of concentration ratio, derived for the two different methods such as C(INNA/ICP-MS), were distinguished from each other: (1) Ba, Cu, K Mg, Na, and Sb: $0.9{\sim}1.1$; (2) Al, Co, Fe, and Mn: $0.8{\sim}1.2$; and (3) Se, Ti, and Zn: >1.3. When the results obtained from both methods were evaluated in terms of regression analysis, paired t-test, and Wilcoxon signed-rank test, the results of many elements determined from PM10 samples(such as Al, Ba, Co, Cu, Fe, K, Mn, Nd, and Sb) exhibited a fairly good agreement between the two methods, despite a wide range of variation.

Effect of Ti, B, Zr Elements on Grain Refinement and Castability of Al-4wt%Mg-0.9wt%Si-0.3wt%Mn-0.15wt%Fe Casting Alloy (주조용 Al-4wt%Mg-0.9wt%Si-0.3wt%Mn-0.15wt%Fe 합금의 결정립 미세화와 주조특성에 미치는 Ti, B, Zr 첨가원소의 영향)

  • Kim, Heon-Joo;Park, Su-Min
    • Journal of Korea Foundry Society
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    • v.35 no.5
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    • pp.120-127
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    • 2015
  • The effects of Ti, B and Zr on grain refinement and castability were investigated in Al-4wt%Mg-0.9wt%Si-0.3wt%Mn-0.15wt%Fe alloy. Measurement of cooling curve and micro-structure observation were performed to analyze the effects of the addition of minor elements Ti, B and Zr during solidification. The prominence of effect on grain refinement was in increasing order for Ti, Zr and B element. Fine grain size and an increase of the crystallization temperature for ${\alpha}$-Al solution were evident as the amount of addition elements increased in this study. Addition of 0.15wt% Ti was most effective for grain refinement, and the resulting grain size of ${\alpha}$-Al solution for shell mold and steel mold were $72.3{\mu}m$ and $23.5{\mu}m$, respectively. Fluidity and shrinkage tests were perform to evaluate the castability of the alloy. Maximum fluidity length and minimum ratio of micro shrinkage were recorded for 0.15wt% Ti addition due to the effect of the finest grain size.

Establishment of micronuclus assay as biological dosimetry in pig lymphocytes after gamma-irradiation (돼지 림프구의 미소핵 형성을 지표로 방사선 생물학적 선량측정법 확립)

  • Kim, Se-ra;Lee, Hae-june;Lee, Jin-hee;Kang, Chang-mo;Kim, Tae-hwan;Jo, Sung-kee;Kim, Jong-choon;Kim, Sung-ho
    • Korean Journal of Veterinary Research
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    • v.44 no.3
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    • pp.323-327
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    • 2004
  • The purpose of the present experiment was to investigate the micronuclei(MN) frequency in cytokinesis-blocked(CB) cells after various doses of gamma-rays in pig (Landrace, male, 3-month-old) and so to contribute to the clarification of the question whether these species are suitable as a target organism in the test system. The frequencies of binucleated cells, and gamma-ray-induced MN in CB cells at several doses were measured in three donors. The peaks of binucleated lymphocyte formation(22%) were found at a concentration of 2% phytohaemagglutinin(PHA) and $4{\mu}g/ml$ Cytochalasin B(Cyt-B) in pig at 72 hours after incubation. Measurements performed after irradiation showed a dose-related increases in MN frequency in each of the donors studied. When analysed by linear-quadratic model the line of best fit was $y=0.0183D+0.0124D^2+0.0133$(y = number of MN/CB cells and D=irradiation dose in Gy). In conclusion, the results demonstrate that it appears feasible to use pig as target organisms in the micronucleus test to estimate the cytogenetic damage caused by ionizing radiations or, potentially, chemical compounds.

Effects of Alloying Elements on the High Pressure Wear Characteristics of Ductile Cast Iron I-Cu, Mn (구상흑연주철의 고압하 마멸특성에 미치는 합금원소의 영향 I-Cu, Mn)

  • Bang, Woong-Ho;Kang, Choon-Sik;Park, Jae-Hyun;Kweon, Young-Gak
    • Journal of Korea Foundry Society
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    • v.20 no.4
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    • pp.230-239
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    • 2000
  • High pressure wear characteristics of DCI(Ductile Cast Iron) were investigated through unlubricated pin-on-disc wear test. Wear test were carried out at speed of 23m/min, under pressure of 3MPa and 3.3 MPa. Cu and/or Mn were added to examine the effect of alloying elements on the high pressure wear characteristics of DCI. To investigate the relationship between wear characteristics and mechanical properties of DCI, Brinell hardness and V-notched Charpy impact energy were tested. Wear surface of each specimen was observed by SEM to determine the wear mechanism of DCI under high pressure wear condition. In the mild wear region, wear characteristics of alloyed DCI specimens were very similar to that of unalloyed DCI. But mild-severe wear transition was occurred at different wear distance and wear rate of DCI specimens were changed by alloying elements. In severe wear condition, wear rate of DCI was dramatically increased by the addition of Mn. Although the addition of Cu 0.46wt% did not decrease the wear rate of DCI in the severe wear region, but it delayed the mild-severe wear transition. Under high pressure wear condition, wear rate and mild-severe wear transition were not concerned with hardness of DCI specimens, but they were deeply associated with impact energy changed by alloying elements.

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Control of Manganese Nodule Characteristics by Volcanic Activity in the NE Equatorial Pacific (북동 태평양 KR1 광구의 망간단괴 산출특성)

  • Kim, Wonnyon;Yang, Seung Jin;Chi, Sang-Bum;Lee, Hyun-Bok
    • Ocean and Polar Research
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    • v.36 no.4
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    • pp.373-381
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    • 2014
  • Korea contract Mn-nodule field in the NE equatorial Pacific is composed of seven sectors with average water depths of 4,513-5,025 m. Of the various factors controlling the properties of Mn-nodule, it seems that water depth is likely connected to the chemical composition and occurrence of nodules. To test whether such an assumption held in each sector, we reviewed previous research data accumulated since 1994 for one of the northern sectors (hereafter KR1) where there are stark contrasts in water depth. High-resolution seabed mapping clearly separates a northern part (KR1N) from a deeper southern part (KR1S), cutting across in the middle of the KR1. In addition, significant volcanic activities forming numerous seamounts are distinctive especially in KR1N. In terms of nodule occurrence, manganese nodules in KR1S are comparatively larger (2-4 cm) with a discoidal shape, while those in KR1N are generally small (<2 cm) with poly-lobate and irregular shapes. Nodules in KR1N also have lower Co, Cu, Mn and Ni, and higher Fe contents. The spatial separation in nodule characteristics might be caused by volcanic activities in KR1N rather than water depth contrast. During the formation of the seamounts in KR1N, rock fragments and volcanic ashes as new nuclei of the nodules would have been continuously generated. As a result, the nodules could not grow larger than 2 cm and display the shapes of a newbie (i.e., irregular and poly-lobate shapes). Moreover, significant Fe supply from volcanic activities probably decreases the Mn/Fe ratio, which may lead to the KR1 nodules being misinterpreted as a hydrogenic in origin compared to other sectors where a high Mn/Fe ratio is present.

Effects of Cr and Ni on Damping Capacity and Corrosion Resistance of Fe-17%Mn Alloy (Fe-17%Mn 합금의 진동감쇠능 및 내식성에 미치는 Cr, Ni 첨가의 영향)

  • Kim, Jung-Chul;Han, Dong-Woon;Back, Jin-Hyun;Kim, Tai-Hoon;Baik, Seung-Han;Lee, Young-Kook
    • Journal of Korea Foundry Society
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    • v.25 no.2
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    • pp.73-79
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    • 2005
  • Effects of Cr and Ni addition on damping capacity, mechanical property, and corrosion resistance of Fe-17%Mn martensitic alloy have been studied. Martensite start temperature($M_{S}$) of the alloy decreases linearly with increasing Cr and Ni contents up to 15%. The damping capacity decreases gradually from 27 to 22% in specific damping capacity(SDC) with increasing Cr and Ni contents from zero to 10%, and decreases rapidly with further Cr and Ni content in Fe-17%Mn alloy. The tensile strength of the alloy maintains a level of 60 $kgf/mm^{2}$ regardless of Cr content with an elongation of 20 to 25%. But, in case of Fe-17%Mn-x%Ni alloy, the tensile strength decreased rapidly with the Ni content of above 10% because of austenite morphology. Immersion test in 5% NaCl solution leads to the result that the corrosion resistance of the alloy becomes excellent above 10% Cr. From the above results, it is concluded that the optimum Cr content to improve the mechanical property and corrosion resistance of the alloy in 5%NaCl solution with a lesser decrease in damping capacity is about 10%. In the case of 5% $H_{2}SO_{4}$ condition, the Fe-17%Mn-10%Ni is an optimum alloy.