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Control of Manganese Nodule Characteristics by Volcanic Activity in the NE Equatorial Pacific

북동 태평양 KR1 광구의 망간단괴 산출특성

  • Kim, Wonnyon (Deep-sea and Seabed Mineral Resources Research Center, KIOST) ;
  • Yang, Seung Jin (Deep-sea and Seabed Mineral Resources Research Center, KIOST) ;
  • Chi, Sang-Bum (Deep-sea and Seabed Mineral Resources Research Center, KIOST) ;
  • Lee, Hyun-Bok (South Sea Research Institute, KIOST)
  • 김원년 (한국해양과학기술원 심해저광물자원연구센터) ;
  • 양승진 (한국해양과학기술원 심해저광물자원연구센터) ;
  • 지상범 (한국해양과학기술원 심해저광물자원연구센터) ;
  • 이현복 (한국해양과학기술원 남해연구소)
  • Received : 2014.09.30
  • Accepted : 2014.11.11
  • Published : 2014.12.30

Abstract

Korea contract Mn-nodule field in the NE equatorial Pacific is composed of seven sectors with average water depths of 4,513-5,025 m. Of the various factors controlling the properties of Mn-nodule, it seems that water depth is likely connected to the chemical composition and occurrence of nodules. To test whether such an assumption held in each sector, we reviewed previous research data accumulated since 1994 for one of the northern sectors (hereafter KR1) where there are stark contrasts in water depth. High-resolution seabed mapping clearly separates a northern part (KR1N) from a deeper southern part (KR1S), cutting across in the middle of the KR1. In addition, significant volcanic activities forming numerous seamounts are distinctive especially in KR1N. In terms of nodule occurrence, manganese nodules in KR1S are comparatively larger (2-4 cm) with a discoidal shape, while those in KR1N are generally small (<2 cm) with poly-lobate and irregular shapes. Nodules in KR1N also have lower Co, Cu, Mn and Ni, and higher Fe contents. The spatial separation in nodule characteristics might be caused by volcanic activities in KR1N rather than water depth contrast. During the formation of the seamounts in KR1N, rock fragments and volcanic ashes as new nuclei of the nodules would have been continuously generated. As a result, the nodules could not grow larger than 2 cm and display the shapes of a newbie (i.e., irregular and poly-lobate shapes). Moreover, significant Fe supply from volcanic activities probably decreases the Mn/Fe ratio, which may lead to the KR1 nodules being misinterpreted as a hydrogenic in origin compared to other sectors where a high Mn/Fe ratio is present.

Keywords

References

  1. 김현섭, 정미숙, 박정기, 고영탁 (2007) 해저면 영상 관찰을 통한 망간단괴 채광 장애지역 분포 특성 연구. 물리탐사 10(3):173-182(Kim H, Jung MS, Park CK, Ko Y (2007) A study on the distributional characteristics of unminable manganese Nodule Area from the investigation of Seafloor photographs. J Korean Geophys Soc 10(3):173-182 (in Korean))
  2. 박상준, 문재운, 이경용, 지상범 (2010) 한국이 탐사 중인 해저광물자원의 희유금속 함량과 의미. 자원환경지질 43(5):455-466(Pak SJ, Moon JW, Lee KY, Chi SB (2010) Rare metal contents and their implications of seabed mineral resources explored by Korea. Econ Environ Geol 43(5):455-466 (in Korean))
  3. 이찬희, 장세원, 이성록, 공기수, 강중석, 장정해 (1995) 태평양, 클라리온-클리퍼톤 균열대에서 산출되는 망간단괴의 형태적 분류. 지질학회지 31(5):560-565(Lee CH, Chang SW, Lee SR, Kong GS, Kang JS, Chang JH (1995) Morphological classification of the manganese Nodules from the Clarion-Clipperton Fracture Zones, Pacific. J Geol Soc Korea 31(5):560-565 (in Korean))
  4. 이현복, 고영탁, 김종욱, 지상범, 김원년 (2011) KODOS 남쪽광구에서 자유낙하식 채취기로 채취된 망간단괴 부존 률 평가를 위한 보정상수 검증. 자원환경지질 44(6):475-483(Lee HB, Ko Y, Kim J, Chi SB, Kim W (2011) Evaluation of correction parameter for the free-fall grab based Mn Nodule. Econ Environ Geol 44(6): 475-483 (in Korean))
  5. 이현복, 김원년, 고영탁, 김종욱, 지상범, 박정기 (2012) 북동 태평양 한국 KODOS 연구지역 중 KR1 지역 망간단괴의 지역적인 특성 변화. 자원환경지질 45(5):477-486(Lee HB, Kim W, Ko Y, Kim J, Chi SB, Park CK (2012) Regional variability of manganese nodule facies in the KR1 Area in KODOS Area, Northeastern Equatorial Pacific. Econ Environ Geol 45(5):477-486 (in Korean))
  6. 정미숙, 김현섭, 박정기 (2007) 북동태평양 KR1 광구 수심자료의 지형분석: 웨이브렛 필터의 적용. Ocean and Polar Res 29(4):303-310(Jung MS, Kim HS, Park CK (2007) Topographic analysis of bathymetry data acquired from the KR1 Area of Northeastern Pacific : Application of wavelet-based filter. Ocean and Polar Res 29(4):303-310 (in Korean)) https://doi.org/10.4217/OPR.2007.29.4.303
  7. 지상범, 형기성, 김종욱, 김현섭, 이근창, 손승규 (2003) 북동 태평양 클라리온-클리퍼톤 균열대 KODOS 지역 심해저 퇴적물의 지질공학적 특성에 따른 유형분류. Ocean and Polar Res 25(4):529-543(Chi SB, Hyeong K, Kim J, Kim HS, Lee GC, Son SK (2003) Classification of deep-sea sediment by geotechnical properties from the KODOS Area in the C-C Zone of the Northeast Equatorial Pacific. Ocean and Polar Res 25(4):529-543 (in Korean)) https://doi.org/10.4217/OPR.2003.25.4.529
  8. 최헌수, 장세원, 이성록 (2000) 망간단괴 미세조직에 따른 광물조성과 화학조성의 상관관계. 한국광물학회지 13(4):205-220(Choi H, Chang SW, Lee SR (2000) Correlation between mineralogical and chemical compositions of the microtextures in manganese Nodules. J Miner Soc Korea 13(4):205-220 (in Korean))
  9. 최헌수, 강중석, 장세원, 고상모, 엄인권 (2007) 망간단괴의 분화율과 망간단괴 분말 및 해저퇴적물의 물리적 특성. 한국광물학회지 20(4):277-287(Choi H, Kang JS, Chang SW, Koh SM, Um I (2007) Shattering ratio of manganese nodule and physical properties of powdered manganese nodule and sea eottom sediment. J Miner Soc Korea 20(4):277-287 (in Korean))
  10. Aleksandrova OA, Poluyaktov VF (1996) Fatty acid composition of the iron manganese nodules and surrounding sediments in the Pacific and Indian oceans. Oceanology 35(5):630-637
  11. Biscaye P (1965) Mineralogy and sedimentation of recent deep-sea clay in the atlantic ocean and adjacent Seas and Oceans. Geol Soc Am Bull 76(7):803-832 https://doi.org/10.1130/0016-7606(1965)76[803:MASORD]2.0.CO;2
  12. Bischcoff JC, Piper DZ, Leong K (1981) The aluminosilicate fraction of North Pacific manganese nodules. Geochim Cosmochim Ac 45:2047-2049 https://doi.org/10.1016/0016-7037(81)90059-4
  13. Craig JD (1979) The relationship between bathymetry and ferromanganese deposits in the north equatorial Pacific. Mar Geol 29:165-186 https://doi.org/10.1016/0025-3227(79)90107-5
  14. Dekov VM, Savelli C (2004) Hydrothermal activity in the SE Tyrrhenian Sea: an overview of 30 years of research. Mar Geol 204:161-185 https://doi.org/10.1016/S0025-3227(03)00355-4
  15. Dymond J, Lyle M, Finney B, Piper DZ, Murphy K, Conard R, Pisias N (1984) Ferromanganese nodules from MANOP Sites H, S and R-control of mineralogical and chemical composition by multiple accretionary processes. Geochim Cosmochim Acta 48:931-949 https://doi.org/10.1016/0016-7037(84)90186-8
  16. Evans AM (1980) An Introduction to Ore Geology. Blackwell Sci Pub, Oxford, 356 p
  17. Glasby GP (1977) Marine Manganese Deposits. Elsevier Oceanography Series, Vol. 15, Elsevier, Amsterdam, 523 p
  18. Gonzalez FJ, Somoz L, Lunar R, Martínez-Frias J, Martin Rubi JA, Torres T, Ortiz JE, Diaz-del-Río V (2010) Internal features, mineralogy and geochemistry of ferromanganese nodules from the Gulf of Cadiz: The role of the Mediterranean Outflow Water undercurrent. J Marine Syst 80:203-218 https://doi.org/10.1016/j.jmarsys.2009.10.010
  19. Halbach P, Friedrich G, von Stackelberg U (1988) The manganese nodule belt of the Pacific ocean. Ferdinand Enke Verlag, Stuttgart, 270 p
  20. Hein JR, Koski RA (1987) Bacterially mediated diagenetic origin for chert-hosted manganese deposits in the Franciscan Complex, California Coast Ranges. Geology 15(8):722-726 https://doi.org/10.1130/0091-7613(1987)15<722:BMDOFC>2.0.CO;2
  21. Hein JR, Koschinsky A, Halbach P, Manheim FT, Bau M, Kang JK, Lubick, N (1997) Iron and manganese oxide mineralization in the Pacific. Manganese Mineralization: Geochemistry and Mineralogy of Terrestrial and Marine Deposits. In: Nicholson K, Hein JR, Buhn B, Dasgupta S (eds). Special Publication Geological Society of London, Vol. 119, pp 123-138
  22. Hunter P, Parson L (2007) Gridded bathymetry of the Clarion-Clipperton fracture zone International Seabed Area. In: Bathymetric compilation in the East Pacific (for the ISA), Geological Model for the CCZ - A Prospectors Guide. The Assembly, July 2007
  23. Jeong KS, Kang JK, Chough SK (1994) Sedimentary processes and manganese nodule formation in the Korea Deep Ocean Study (KODOS) area, western part of Clarion-Clipperton fracture zones, northeast equatorial Pacific. Mar Geol 122(1-2):125-150 https://doi.org/10.1016/0025-3227(94)90208-9
  24. Klitgord KD, Mammerickx J (1982) Northern east Pacific rise: Magnetic anomaly and bathymetric framework. J Geophys Res 87(B8):6725-6750 https://doi.org/10.1029/JB087iB08p06725
  25. Ko Y, Lee S, Kim J, Kim KH, Jung MS (2006) Relationship between Mn nodule abundance and other geological factors in the northeastern Pacific: Application of GIS and probability method. Ocean Sci J 41(3):149-161 https://doi.org/10.1007/BF03022420
  26. Lee CH, Lee SR (1998) Authigenic phillipsite in deep-sea manganese nodules from the Clarion-Clipperton area, NE equatorial Pacific. Mar Geol 148:125-133 https://doi.org/10.1016/S0025-3227(98)00004-8
  27. Lee SH, Kim KH (2004) Side-scan sonar characteristics and manganese nodule abundance in the Clarion-Clipperton Fracture Zones, NE equatorial Pacific. Mar Georesour Geotec 22:103-114 https://doi.org/10.1080/10641190490473434
  28. Murray J, Rnard AF (1891) Reports on deep-sea deposits based on specimens collected during the voyage of H.M.S. CHALLENGER in the years 1872-1876. London, 525 p
  29. Rona P (2002) Marine minerals for 21st century. Episodes 25:2-12
  30. Rona P (2003) Resources of the sea floor. Science 299:673-674 https://doi.org/10.1126/science.1080679