• Korean Journal of Fisheries and Aquatic Sciences
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• v.9 no.3
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• pp.169-175
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• 1976

A solvent extraction-atomic absorption spectrophotometry for determination of trace amount of cadmium, copper, lead and zinc and a flameless atomic absorption spectrophotometry for mercury in sea water were studied. The optimum pH range for solvent extraction was pH 4-7. A better solvent extraction efficiency was obtained with MIBK solvent than nitrobenzene, benzene, isoamylalcohol, n-buthylacetate. DDTC was more advantageous than APDC as chelating agent. The metals, chelated with DDTC and concentrated into MIBK by solvent extraction with a volume of $1\iota$ of sea water for cadmium, copper and lead, and 200m1 for zinc, were determined simultaneously by atomic absorption spectrophotometry. For mercury determination, 500ml of sea water was digested with permanganate-sulfuric acid and mercury( II ) was reduced by stannous chloride and aerated the solution with air pump until the absorbance reached a constant value. The precisions, in standard deviation, of these methods were 0.058ppb for cadmium, 0.084 ppb for copper, 0.44ppb for lead, 2.49ppb for zinc and 0.08 ppb for mercury. The sensitivities, expressed in $ppb/1\%$ absorption, were 0.058 ppb cadmium, 0. 15 ppb copper, 0.6 ppb lead, 1.2 ppb zinc and 0.01 ppb mercury respectively. No significant adsorption on the wall of polyethylene sample bottle occurred during 30 days of storing by acidification to pH 1.5 with nitric acid except zinc. Poor reproducibility was found for zinc with this method.

• Proceedings of the KAIS Fall Conference
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• 2002.11a
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• pp.283-286
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• 2002

막-용매 추출을 이용하여 모사폐수로부터 페놀을 분리하였으며, 이때 미세기공 비친수성 중공사형 모듈을 사용하였다. 전체적인 시스템은 향류, 및 병류로 운영되었으며, 유기오염물은 tube 안쪽으로, 용매는 shell쪽으로 흐르게 하였다. MIBK를 추출용매로 사용하였으며, 페놀의 분리효율은 향류 흐름이 병류흐름보다 더 우수함을 알 수 있었다.

• 한국생물공학회:학술대회논문집
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• 2000.04a
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• pp.121-124
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• 2000

Organic acids were produced from wastes streams in food industries by cell-recycle fermentation using Propionibacterium acidipropionici ATCC 4965. As a results of continuous fermentation, maximum productivity was 3.32g organic acid/L/hr at the dilution rate of 0.2/hr. Compared to batch fermentation, maximum productivity was improved by as much as 13 times and cell mass production was increased by as much as 22 times. The diluted organic acids in the fermenter were selectively separated by liquid-liquid extraction using 30%(w/w) trioctylamine(TOA) dissolved in methylisobutylketone(MIBK). The degree of extraction was reached above 90% for both acetic and propionic acid through repeated extraction of organic acids in fermentation broth.

• Journal of Korean Society of Occupational and Environmental Hygiene
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• v.1 no.2
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• pp.214-220
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• 1991

As chromium in urine remains as oxychromic acid ions, chromium was extracted by using ion pair formed by anion exchanger trioctylamine. then after it is noted whether this TOA-MIBK method is effective or not for the chromium analysis by using flame method of Atomic absorption Spectrophotometric Analysis. The result is as following. 1. Effects of various acids on the extraction of Cr with MIBK including TOA are good in order $NHO_3$, $H_2SO_4$, HCl in distilled water sample and its proper concentration of HCl is 0.2 N. 2. For the analysis of urine sample, the best result can be achieved by following condition. After finished pretreatment adjusted to pH 6.5-7.5 by NaOH and again controlled pH 0.5-0.6 by HCl. 3. Though TOA concentration slightly affects the analytic value, best result is noted in 1-3% concentration. 4. Recovery rates of urine samples made by $0.3mg/l{\cdot}urine$, $0.6mg/l{\cdot}urine$, $0.9mg/l{\cdot}urine$ are shown from 96.7% to 104.8%. 5. Recovery rates of urine samples made by $0.01mg/l{\cdot}urine$, $10.03mg/{\cdot}urine$, $0.05mg/l{\cdot}urine$ are shown from 89.3% to 98.6%.

• Journal of the Korean Chemical Society
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• v.43 no.4
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• pp.401-406
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• 1999

Trace amount of cadmium was quantitatively extracted with 1% Aliquat 336-MIBK from 0.2M KSCN and 0.01M-HCl. Test tubes with a screw cap stopper were used for extraction in place of conventional separating funnels and organic solvents used were less dense than water. In this analysis, 22 times concentration effect was achieved with higher selectivity without interference. The detection limit of cadmium was 0.7ppb, therefore trace cadmium was easily analyzed by this method. The proposed method was applied to the determination of cadmium in blood serum and extraction mechanism was elucidated.

• Analytical Science and Technology
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• v.20 no.1
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• pp.41-48
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• 2007

The determination method for the trace lead and cadmium in glass materials was developed by ICP-AES. The lead- and cadmium-DDTC chelates were formed by adding Na-DDTC (sodium diethyldithiocarbamate) as a chelating agent and extracted into MIBK (methyl-isobutyl ketone). Direct measuring of the trace lead and cadmium in glass was not possible because of the interferences of matrix elements as Na, Si, Mg and Ca of glasses unless solvent extraction of lead and cadmium was applied. This procedure was confirmed to be valid quantitative method of Pb and Cd analysis in glass did not influence of sample matrix, by applying it procedure to artifact sample and NIST SRM 1412.

• Proceedings of the Korea Society for Energy Engineering kosee Conference
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• 2000.11a
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• pp.205-210
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• 2000

VOC는 volatile organic compound의 약자로서 toluene, benzene, MEK, MIBK등 자동차 운행, 도장산업, 인쇄업, 대형 세탁시설, 유류저장 및 출하시설에서 주로 배출되는 유기성 배기배출물을 총칭하는 개념이다. VOC는 작업현장에서 악취를 발생시켜 작업현장에서의 쾌적성을 해치기도 하지만, 태양에너지를 받아 오존을 형성하기 때문에 인체에 크게 해로운 역할을 한다. 정부에서는 대기환경보전법을 제정하여 휘발성유기화합물질 배출억제 정책을 실시하고 있으며, 배출업소에 대하여 휘발성유기화합물질 방지시설 설치를 의무화하고 있다.(중략)

• Journal of Environmental Health Sciences
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• v.19 no.2
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• pp.40-45
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• 1993

A solvent extraction system of copper-thiocyanate complex into various types of alkylamines such as secondary, tertiary and quaternary ammonium salt for the determination of trace copper by atomic absorption spectrometry is presented. The maximum extraction of copper shows at 0.1 M-thiocyanate and single extraction with 10 ml of 1% amine-MIBK from 50 ml of aqueous solution is enough to be quantitative for micro amounts of copper. The effect of amine diluents and of diverse ions are also examined.

• YAKHAK HOEJI
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• v.29 no.4
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• pp.220-222
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• 1985

Rifampicin reacts with cupric ion to produce rifampicin-Cu(II) chelate (2:1) at pH 6.5, which can be extracted with methylisobutylketone (MIBK). Therefore, rifampicin can be quantitatively, determined by measuring the quantity of Cu(II) in the organic phase by atomic absorption spectrophotometry. Because higher absorbance ratio was obtained in pH 6.0~7.0, buffer solution at pH 6.5 was used in this measurement. Linear relationship was found between absorbance and concentration in the range of 1.0~4.0${\times}10^{-4}M$. This method might be applicable to the determination of rifampicin in the preparations.

• Analytical Science and Technology
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• v.12 no.5
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• pp.355-359
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• 1999

Trace cadmium was determined in urine by flame and nameless AAS. Inflame method, cadmium was extracted into MIBK from Cd-DDTC complex. In flameless method, samples were pretreated with 1%, Triton X-100. 1% $HNO_3$ and matrix modifier $Pd(NO_3)_2$. Analysis of cadmium was, performed at $450-750^{\circ}C$ ashing temperature by use of pyrocoated tubes. Results of analysis, flameless method superior in sample treatment and reproducibility to flame method and highest absorbance was obtained at $550^{\circ}C$ ashing temperature. 100 mg/L $Pd(NO_3)_2$ concentration. Proposed method were applied to the determination of cadmium in standard urine Lononorm-Metalle 3.