• Journal of Hydrogen and New Energy
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• v.16 no.1
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• pp.31-39
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• 2005

Direct methanol fuel cell (DMFC) is considered as a candidate for portable power sources, that could overcome the disadvantages of lithium battery. But in order to attain commercial viability the long term stability of the DMFC should be achieved. Understanding the long-term behavior of membrane-electrode assembly (MEA) is a prerequisite to this purpose and the optimization of the MEA is also needed. In this study we have investigated the changes in performance and electrochemical properties of the MEA during extended operation and the effects of heat treatment of MEA on the long-term performance. The MEAs have been treated in an autoclave with saturated water vapor at 120$^{\circ}C$, vacuum oven at 140$^{\circ}C$ and boiling in organic solvents. The autoclaved MEA was found to be have the best long term performance. The on-off operation mode also increased the performance probably due to effective removal of products from the electrodes. Physical and electrochemical analyses using a scanning electron microscope, impedance analyser and half-cell technique have been done to characterize the MEAs.

• 한국신재생에너지학회:학술대회논문집
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• 2010.11a
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• pp.86.2-86.2
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• 2010

In order to improve polymer electrolyte membrane fuel cell (PEMFC) durability, the durability of membrane electrode assemblies (MEA), in which the electrochemical reactions actually occur, is one of the vital issues. Many articles have dealt with catalyst layer degradation of the durability-related factors on MEAs in relation to loss of catalyst surface area caused by agglomeration, dissolution, migration, formation of metal complexes and oxides, and/or instability of the carbon support. Degradation of catalyst layer during long-term operation includes cracking or delamination of the layer which result either from change in the catalyst microstructure or loss of electronic or ionic contact with the active surface, can result in apparent activity loss in the catalyst layer. Membrane degradation of the durability-related factors on MEAs can be caused by mechanical or thermal stress resulting in formation of pinholes and tears and/or by chemical attack of hydrogen peroxide radicals formed during the electrochemical reactions. All of these effects, the mechanical damage of membrane and degradation of catalyst layers are more facilitated by uneven stress or improper MEA fabrication process. In order to improve the PEMFC durability, therefore, it is most important to minimize the uneven stress or improper MEA fabrication process in the course of the fabrication of MEA. We analyzed the effects of the MEA fabrication condition on the PEMFC durability with MEA produced using CCM (catalyst coated membrane) method. This paper also investigated the effects of MEA fabrication condition on the PEMFC durability by adding additional treatment process, hot pressing and pressing, on the MEA produced using CCM method.

• Journal of Hydrogen and New Energy
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• v.22 no.6
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• pp.842-851
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• 2011

A multi-cell test system with 25 independent cells is used to test different electrode materials simultaneously for polymer electrolyte membrane fuel cells (PEMFCs). Twenty-five segmented membrane electrode assemblies (MEAs) having the same or different Pt-loading are prepared to analyze the performance deviation of cells in the multi-cell test system. Improvements in the multi-cell test system are made by ensuring that the system performs voltage sensing for the cells individually and inserting optimum gaskets between the MEAs and the graphite plates. The cell performances are improved and their deviations are significantly decreased by these modifications. The performance deviations changed according to various cell configurations because the operating conditions of the cells, such as the gas flow and concentration, differed. This cell system can be used to test multiple electrodes simultaneously because it shows relatively uniform performance under the same conditions as well as linear correlation with various catalyst loadings.

• New & Renewable Energy
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• v.17 no.2
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• pp.50-58
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• 2021

We proposed an MEA development methodology that accurately measures intrinsic MEA performance while considering the uneven reaction environments formed inside a large-area BP. To facilitate measurement of the inherent MEA performance, we miniaturized the active area of the MEA to 3 cm², and prepared two MEAs with different ionomer contents of 0.65 and 0.80 (I/C). By simulating the operating conditions of a 100 cm² BP at the inlet (I), center (C), and outlet (O), the oxygen concentration and relative humidity were determined to be 20.7, 13.8, 11.7%, and 50, 66.1, and 70.1% respectively. We measured the performance and electrochemical analysis of the prepared MEAs under the three simulated conditions. Based on the results of statistical analysis of the evaluated MEA performance data, I/C 0.65 MEA had a higher average performance and lower performance deviation than I/C 0.80 MEA. Hence, it can be concluded that an I/C 0.65 MEA is a more effective MEA for large-area BP. Based on the above research process, we confirmed the effectiveness of the proposed MEA development methodology.

• 제어로봇시스템학회:학술대회논문집
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• 1997.10a
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• pp.1553-1556
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• 1997

In the paper, we porpose a new mehtod of extending PLS(Partial Least Squares) regressiion method to nonlinear framework and apply it to the estimation of product compositions in high-purity distillation column. There have veen similar efforets to overcome drawbacks of PLS by using nonlinear-mapping ability of meural networks, however, they failed to show great improvement over PLS since they focused only in capturing nonlinear functional relationship between input data, not on nonlinear correlation inthe data set. By incorporating the structure of Robust Auto Associative Networks(RAAN) into that of previous nonlinear PLS, we can handle nonlinear correlation as well as nonlinear functional relationship. The application result shows that the proposed method performs better than previous ones even for nonlinearities caused by changing operating conditions, limited observations, and existence of meas-unrement noises.

• Journal of Korean Society of Occupational and Environmental Hygiene
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• v.18 no.2
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• pp.115-121
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• 2008

In winter season, the survey was performed in three commercial office buildings in the metropolitan Seoul, Pusan, and Gwangju city. The purpose of the survey was to evaluate the effectiveness of ventilation for offices in commercial buildings. The data were compared to standard of applicable to the indoor ventilation in office. The results indicated that the most commercial office buildings used the air handing unit and fan coil unit as HVAC system, and the intake amount of fresh outdoor air were very inadequate to compared to the ASHRAE standard value of $0.57\;m^3/min/person$. Also the surveyed all commercial office building used the HVAC system as a meas of controlling temperature for office indoor air. Ultimately, these results presented that there were possibility of evoking indoor air quality problems by the insufficient ventilation.

• Journal of Technologic Dentistry
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• v.33 no.2
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• pp.137-145
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• 2011

Purpose: To evaluate the accuracy of zirconia copings in terms of clinical verified for the clinical application of CAD/CAM. Methods: Zirconia copings (n=5) were prepared using CAD/CAM system and were sintered using the relevant electrical induction furnace, which uses a 2h sintering program with a maximum temperature of $1500^{\circ}C$. The copings placed at the models and the interval values were measured. Results: The meas interval values between the die and the zirconia copings were $44.14{\mu}m$(A), $44.57{\mu}m$(B), $44.72{\mu}m$(C). 51.05 ${\mu}m$(D). Conclusion: The maximum interval values between the die and the zirconia copings were $51.3{\mu}m$ which is acceptable for clinical use. ${\mu}m$ Proper understanding of the test conditions will help enhancing the accuracy of zirconia coping.

• Proceedings of the Korea Air Pollution Research Association Conference
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• 2004.11a
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• pp.151-154
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• 2004

The estimated emissions from proposed four ESTs for each measurement period were compared with the estimated emissions from baseline farms, after the later are adjusted for the average environmental parameters (lagoon temperature and air temperature) observed at the EST sites. The ESTs at Barham Farm and Grinnell's Laboratory were more effective in reducing the ammonia emission during one of the two sampling periods. However, based on the current research results and analysis, and available information in the scientific literature, the evaluated alternative technologies may require additional technical modifications to be qualified as Environmentally Superior as defined by the NC Attorney General Agreements.

• Proceedings of the KIPE Conference
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• 2012.11a
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• pp.85-87
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• 2012

This paper describes the design and analysis of an integrated transformer magnetic core which comprises of two different power cores with PFC inductor and LLC resonant transformer magnetic cores. The equivalent magnetic circuit modeling approach is employed to analyze the variations in coupling coefficient and inductance in terms of air gaps under the operations of the respective power core. Simulation and experimental studies are performed with a fabricated prototype integrated core and their results are discussed.

• The Journal of Korean Institute of Communications and Information Sciences
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• v.9 no.4
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• pp.153-156
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• 1984

A local area network(LAN) controller is designed according to non-persistent CSMA protocols. By meas of a buffer register, a microcomputer interfaces with the LAN controller. To keep bus utilization near the optimal efficiencies, the transmission intervals are adjusted as a function of $2^n$. A message in the form of a packet consisting of 128bytes is transitted to the bus. The maximum transmission rate of 19.2Kbps is obtained at layer 1.