• Title/Summary/Keyword: M67

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The Effect of $H^+$ on Reduction of $[Co(NH_3)_4(C_2O_4)]^+$ with $[Fe(H_2O)_6]^{2+}$

  • Lim, Joo-Sang;Lee, Jae-Weon;Kang, Seung-Gu;Park, Byung-Kak
    • Bulletin of the Korean Chemical Society
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    • v.11 no.4
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    • pp.303-306
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    • 1990
  • Kinetic studies were carried out for the redox reaction of $[Co(NH_3)_4(C_2O_4)]^+$ with aqueous $[Fe(H_2O)_6]^{2+}$ solution in the present of $H^+$ by UV/VIS-spectrophotometric method. It was found that the order of $H^+$ for the reaction is first one in the higher $H^+$ concentration range of $1.67×10^{-1} M{\sim}1.00 M,$ while second order in the lower range of $6.30×10^{-2} M{\sim}1.67{\times}10^{-1} M.$ Reaction order of the substrates was found to be first order with respect to each of them. Accordingly overall reactions are third or fourth order. The results of calculation for the Extended Huckel Molecular Orbital theory contribute to estimate the preferred intermediates, bridging form of binuclear complex. On the basis of these results, we propose that this redox reaction proceed via inner-sphere reaction mechanism.

Synthesis and Electrochemical Characterization of Polyaniline/Poly[1,2]bis-thio[1,8]-naphthylidine Composite as Polymer Cathode Material (Polyaniline/Poly[1,2]bis-thio[1,8]-naphthylidine 복합체 고분자 양극재료의 합성과 전기화학적 특성)

  • Oh, Ji-Woo;Ryu, Kwang-Sun
    • Journal of the Korean Electrochemical Society
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    • v.15 no.4
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    • pp.222-229
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    • 2012
  • We studied the electrochemical phenomena and increase of capacity according to the polymer composite electrode of two different polymeric materials with different the voltage range and capacity. Polyaniline (PANI) with relatively high voltage and small capacity and poly [1,2] bis-thio[1,8]-naphthylidine (PTND) with slightly low voltage and large capacity were used as polymer composite electrode materials. After PTND was synthesized, PANI was synthesized on the surface of PTND. The synthesis and the fine structure were analyzed by FT-IR, XPS, FE-SEM, and FE-TEM. Charge/discharge capacity and cyclic voltammetry measurements were carried out for the electrochemical performance as a polymer cathode active material for lithium secondary batteries. The discharge capacities of PANI/PTND after 1,5, and 10 cycles at 1.3~4.0 V voltage range and room temperature 167 mAh/g, 90 mAh/g, and 81 mAh/g. When we compared with PANI (80, 67, and 62 mAh/g), the discharge capacity after 10 cycles was improved about 30%. After 50 cycles, the discharge capacity of PANI/PTND was 67 mAh/g.

Study on DNA Content and Ki-67 Antibody Expression by Means of Image Analyzer for the Benign and Malignant Lesions of the Larynx (후두 편평상피의 전암성 및 악성병변에서 화상분석기를 이용한 DNA 배수성검사와 Ki-67 항체 양성세포의 분석에 관한 연구)

  • 주형로;이선희;최종욱;김인선
    • Proceedings of the KOR-BRONCHOESO Conference
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    • 1993.05a
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    • pp.89-89
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    • 1993
  • The laryngeal epithelial cell kinetics of 26 laryngeal lesions(invasive squamous cell carcinoma 14, epithelial hyperplasia 5, laryngeal nodule 7) were studied by immunehistochemical analysis with the monoclonal antibody Ki-67, which reacts with nuclear antigen in proliferating cells using paraffin embedded tissue. For DNA analysis, touch implint with fresh biopsy specimens were stained with feulgen and analyzed by image analyzer in 22 cases. 1) The proportion of Ki-67-positive cells were 32.65$\pm$ 11.59% in invasive squamous cell ca, 20.14$\pm$3.38% in epithelial hyperplasia lesion and 11.66$\pm$3.02% in laryngeal nodule. 2) DNA aneuploidy was found in 7 cases of 10(70%) invasive squamous cell carcinomas, 2 cases of 5(40%) epithelial hyperplasia lesions and all cases of laryngeal 3) Proliferation index(S phase+G2/M phase) show 23.42$\pm$11.33% in squamous cell carcinoma, 13.09$\pm$ 10.90% in epithelial hyperplasia lesion and 4.50$\pm$1.19% in laryngeal nodule. As the results, measuring the DNA content from touch imprint method together positivity of Ki-67 antibody from the microtissue during the laryngeal microscopic surgery, cell kinetics can be assessed as an effort of deciding the prognosis and provide a key to the management of precancerous lesions.

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A Novel Performance in Hairpin Oscillator using Aperture and PBG (Aperture와 PBG를 이용한 Hairpin 발진기의 성능 개선에 관한 연구)

  • 장욱태;서철헌
    • The Journal of Korean Institute of Electromagnetic Engineering and Science
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    • v.15 no.5
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    • pp.437-443
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    • 2004
  • Aperture has been employed on the ground plane in the hairpin resonator. Aperture has been fabricated by etching the part of the ground effected coupling coefficient and then quality factor of hairpin resonator has been increased. When the hairpin oscillator using aperture has been compared with the conventional hairpin oscillator using microstrip, it has been improved the phase noise about 19 ㏈c @100 ㎑. As a result of PBG connecting to the output of the employing aperture hairpin oscillator, the second and third harmonics are suppressed. In this paper, oscillator has been designed and fabricated in operating 5.8 ㎓ band. The output power has been obtained 0,67 ㏈m and the second harmonic has been suppressed about -53,67 ㏈c.

Effect of Fertilizer and Shading on Emergence of Echinochloa glabrescens, Monochoria vaginalis and Cyperus difformis (Echinochloa glabrescens, Monochoria vaginalis 및 Cyperus difformis 발아(發芽)에 미치는 비료시용(肥料施用)과 차광(遮光)의 영향(影響))

  • Kim, Jong-Seog
    • Korean Journal of Weed Science
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    • v.8 no.1
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    • pp.33-36
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    • 1988
  • The emergences of Echinochloa glabrescens, Monochoria vaginalis, and Cyperus difformis seeds were little affected by fertilizer application. All shading treaments resulted in decrease in emergence of E. glabrescens, while shading up to 67% slightly stimulated emergence of M. vaginalis and C. difformis. The peak emergence of E. glabrescens was at two week after sowing in the full sunlight, 31, and 52% shading, but no peak emergence at the 67% shading. Emergence peaks of C. difformis were observed during 6 to 8 weeks after sowing for all shading levels employed.

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A Study on Standing Crops in Phragmitis communis Communities and their Environmental Factors (갈대군락의 현존량과 환경요인에 관한 연구)

  • 김철수
    • Journal of Plant Biology
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    • v.18 no.3
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    • pp.129-134
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    • 1975
  • It was studied of relation between biomass of reed communities (Phragmitis communis) and several environmental factors concerned with such as chlor ine, pH, humus content in soil and depth of seawater submerged. Two sites where were the different geographical conditions were set up. One site had two plots: H plot, at theshallows of seawater, was not submerged except at full tide or at heavy rainfall, and M plot, at medium depth of seawater, submerged at every common tide at inside of a bank along the west seashore of Mu-An-peninsula. The other site also two plots: M' plot, at medium depth, submerged about 10 hours at each tide, and L plot, at deep seawater submerged every tims at tide at the outside of a bank along the eastside estuary of Youngsan river. Maximum standing crop of the reed community was shown on 25th of June: biomass at H M, M' and L plot were respectively 4.65, 3.60, 0.98, and 0.67 kg dry weight per $m^2$. Density of individual at H, M, M' and L plot was 67, 78, 244 and 333 plants per $m^2$. Net production of the terrestrial parts of rred community on the outside of the bank were lesser as much as a sixth than that on inside, but the density of the plant on outside of the bank was higher as much 4 or 5 times than that on inside. It was assumed that the growth of reed plant was inhibited by high chlorine, high pH, less humus in soil and submergence of seawater for long period.

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Extracting Input Features and Fuzzy Rules for forecasting KOSPI Stock Index Based on NEWFM (KOSPI 예측을 위한 NEWFM 기반의 특징입력 및 퍼지규칙 추출)

  • Lee, Sang-Hong;Lim, Joon-S.
    • Journal of Internet Computing and Services
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    • v.9 no.1
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    • pp.129-135
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    • 2008
  • This paper presents a methodology to forecast KOSPI index by extracting fuzzy rules based on the neural network with weighted fuzzy membership functions (NEWFM) and the minimized number of input features using the distributed non-overlap area measurement method. NEWFM classifies upward and downward cases of KOSPI using the recent 32 days of CPPn,m (Current Price Position of day n for n-1 to n-m days) of KOSPI. The five most important input features among CPPn,m and 38 wavelet transformed coefficients produced by the recent 32 days of CPPn,m are selected by the non-overlap area distribution measurement method. For the data sets, from 1991 to 1998, the proposed method shows that the average of forecast rate is 67.62%.

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Evaluation of Bone Marrow Involvement in Leukemic Patients using Bone Marrow Scan (백혈병 환자에서 골수주사를 이용한 골수침범 유무의 평가)

  • Cho, Jae-Hyun;Kim, Myoung-Joon;Lee, Jong-Doo;Park, Chang-Yoon;Kim, Kill-Young;Kim, Yong-Soo
    • The Korean Journal of Nuclear Medicine
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    • v.27 no.2
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    • pp.298-304
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    • 1993
  • To estimate the bone marrow involvement of leukemia, we peformed scintigraphies using $^{99m}Tc$ antimony sulfide colloid and Gallium-67. Total 13 patients were included and obtained 14 study sets of $^{99m}Tc$ antimony sulfide colloid and gallium-67 and compared with bone marrow aspiration biopsy and clinicolaboratory datas. $^{99m}Tc$ Antimony scan showed localized defect in 4 patients who had relapse. No false positive or negative results were observed. Gallium 67 showed localized increased uptake in 2 of 4 relapsed patients. Therefore, bone marrow scan is useful for the evaluation of marrow infiltration in ieukemic patients.

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THE MILK PRODUCTION PERFORMANCES OF BARBARI, ANGLO-NUBIAN AND BARBARI × BLACK BENGAL GOATS UNDER INTENSIVE MANAGEMENT IN BANGLADESH

  • Mia, M.M.;Ali, A.;Howlider, M.A.R.;Amin, R.
    • Asian-Australasian Journal of Animal Sciences
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    • v.7 no.2
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    • pp.171-174
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    • 1994
  • The milk production of Anglo-Nubian, Barbari and Barbari $\times$ Black Bengal goats were compared. The respective average lactation yield of those genotypes were $171.27\;{\pm}\;16.90$, $88.22\;{\pm}\;8.67$ and $52.31\;{\pm}\;13.51$ kg; mean annual milk yield $208.41\;{\pm}\;24.57$, $117.13\;{\pm}\;12.44$ and $84.19\;{\pm}\;23.45$ kg; per day milk yield $0.82\;{\pm}\;0.07$, $0.61\;{\pm}\;0.05$ and $0.43\;{\pm}\;0.06$ kg and lactation length $207.67\;{\pm}\;7.36$, $143.89\;{\pm}\;6.67$ and $116.75\;{\pm}\;13.86$ days. All traits recorded were influenced significantly (p<0.01) by the genetic group. Introduction of Barbari genes to Black Bengal goats had a positive effect in improving milk yield.

Effect of Die Geometry on Expansion of Corn Flour Extrudate (사출구 구조에 따른 옥수수가루 압출성형물의 팽화특성)

  • Gu, Bon-Jae;Ryu, Gi-Hyung
    • Food Engineering Progress
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    • v.15 no.2
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    • pp.148-154
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    • 2011
  • The objective of this study was to determine the effect of die geometry on expansion index of extruded corn flour. Water solubility index, water absorption index and specific mechanical energy (SME) input were analyzed to observe the relationship with die geometry. The feed moisture content was 20 and 25%. Die dimensions were tapered angle (57, 95o) and length/diameter (L/D) ratio of die land (0.67, 1.67 and 2.67). The SME input was the highest at 20% moisture content and 2.23E-10 m3 die constant. The sectional and volumetric expansion indices at 20% moisture were increased with increase in die constant. However, die constant did not influence sectional expansion index of corn flour extrudate at 25% moisture content. The extruded corn flour at 25% moisture content had higher longitudinal expansion index than those of extruded corn flour at 20% moisture content. Sectional expansion and longitudinal expansion index were negatively correlated. The water absorption index and water solubility index were not affected with the die constant.