• Title/Summary/Keyword: M2 polarization

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A study of polarized mode convertible, wavelength tunable optical filter utilizing acoustic barrier and acouxto-optic effect in $LiNbo_3$ ($LiNbo_3$의 음향광학효과와 음향파 장벽을 이용한 편광모드 변환형, 파장가변 광 필터에 관한 연구)

  • 임경훈;정홍식
    • Korean Journal of Optics and Photonics
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    • v.11 no.3
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    • pp.193-197
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    • 2000
  • A polarized mode convertible, wavelength tunable optical filters with acoustic barriers and acousto-optic effect have been produced in LiNb03 substrate utilizing the Ti double diffusion technique. Polarization conversion in excess of 81 % and a spectral width of -200 kHz (-1.83 nm) were achieved at a wavelength of 1551.6 nm and RF frequencies of 173.07 kHz and 173.05 kHz for both transverse electric (TE) and transverse magnetic (lM) input polarizations, respectively. The electrical driving power was 10.97 mW and reduced to about 10% of one for an optical filter without an acoustic barrier. A linear tuning rate of 8.2 nmlMHz and sidelobe intensity of -4 dB was demonstrated. rated.

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Operating Characteristics of Direct Methanol Fuel Cell Based on Pt-Ru/C Anode Catalyst (Pt-Ru/C 촉매를 이용한 직접메탄을 연료전지 운전 특성)

  • Jung, D.H.;Lee, C.H.;Kim, C.S.;Chun, Y.G.;Shin, D.R.
    • Proceedings of the KIEE Conference
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    • 1997.07d
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    • pp.1252-1254
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    • 1997
  • Direct methanol fuel cell based on a proton-exchange membrane electrolyte was investigated. 60% Pt-Ru/C and 60%Pt/C catalysts were employed for methanol oxidation and oxygen reduction, respectively. Morphologies of the catalysts were investigated by x-ray power diffraction, energy dispersive x-ray spectroscopy, and transmission microscopy. Electrochemical characteristics of the catalysts were tested by using cyclic voltametry technique. I-V characteristics of the fuel cell were tested by changing methanol concentration, temperature, and Nafion type as a proton-exchange membrane electrolyte. AC impedance technique was used to investigate the electrochemical performance of the fuel cell. The performance of single cell was enhance with increasing cell temperature. High operation temperature attributed to the combined effects of the reduction of ohmic resistance and polarization. High cell voltage was obtained from the concentration of 205M methanol. With Nafion 112, a current density of $230mA/cm^2$ at 0.55V was obtained from the concentration of 2.5M methanol.

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Corrosion Properties of Al-(Ga, Sn, Mn) Alloy Anodes for an Al-air Battery in 4 M KOH Aqueous and Ethanol Solutions (4 M KOH 수용액 및 에탄올 용액에서 알루미늄 공기 전지용 Al-(Ga, Sn, Mn) 합금 음극의 부식 특성)

  • Lee, Han-Ok;Park, Chan-Jin;Jang, HeeJin
    • Corrosion Science and Technology
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    • v.10 no.2
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    • pp.71-75
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    • 2011
  • Corrosion properties of Al-0.3Ga-0.3Sn, Al-0.3Mn-0.3Ga, and Al-0.3Mn-0.3Sn alloys were examined to develop an anode material for Al-air battery with alkaline aqueous or ethanol electrolyte. The results of potentiodynamic polarization tests showed that the electrode potential of the Al alloys were lower than the pure Al, implying the cell voltage can be increased by using one of these alloys for an anode in 4 M KOH aqueous solution. The corrosion rate appeared to be increased by alloying Ga but to be reduced by Sn and Mn in the aqueous solution. The ethanol solution is expected to improve the cell performance in that the electrode potential and the corrosion rate of Al were lower in ethanol solution than in aqueous solution. However the Al-(Ga, Sn, Mn) alloys are not favorable in ethanol solution because of the high potential and corrosion rate.

A study on the fabrication of porous cermet electrode for molten carbonate fuel cell anode (용융탄산염 연료전지 양극용 다공성 cermet 전극제조에 관한 연구)

  • Lee, K. H.;Chang, D. Y.;Kim, M.;Kang, S. G.
    • Journal of the Korean institute of surface engineering
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    • v.26 no.6
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    • pp.291-298
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    • 1993
  • In order to substitute for porous nickel anode in Molten Carbonate Fuel Cell(MCFC), porous cermet elec-trode was fabricated with Ni and Ni-P coated ceramic powder. Ni and Ni-P were coated by electroless plat-ing method in the nickel solution containing of hydrazine and sodium hypophosphate as a reducing agent. The plating solution was stirred by air and mechanical agitator. Ultrasonic irradiation was applied to the plating bath to improved the effect of agitation and coating speed. Electorde was formed by pressing method and doc-tor blade method followed by sinterd at$ 800^{\circ}C$ for 6 hours in H2 environment. Anode performance test carried out by potentiodynamic polarization technique in the MCFC operating condition and 154-161mA/$\textrm{cm}^2$ as ob-tained as a anode current density at the+100mV overpotential.

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The polarimetric study of (331471) 1984QY1: an asteroid in comet-like orbit

  • Kim, Jooyeon;Ishiguro, Masateru;Bach, Yoonsoo P.;Kuroda, Daisuke;Naito, Hiroyuki;Kim, Yoonyoung;Kwon, Yuna G.;Imai, Masataka;Kuramoto, Kiyoshi;Watanabe, Makoto
    • The Bulletin of The Korean Astronomical Society
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    • v.42 no.2
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    • pp.50.2-50.2
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    • 2017
  • Spatial distribution of atmosphereless bodies in the solar system provides an important clue as to their origins, namely asteroids from Mainbelt or comets from outer solar system. It is, however, difficult to distinguish asteroids and dormant comets due to their similar appearances. In this study, we conducted a unique observation to differentiate asteroids and dormant comets in terms of 'polarimetry'. We observed (331471) 1984 QY1 (hereafter QY1) at large phase angles using the Multi-Spectral Imager (MSI) on the 1.6-m Pirka Telescope from UT 2016 May 25 to June 24. QY1 is a dormant comet candidate in terms of the dynamical properties (i.e. the Tisserand parameter with respect to Jupiter, TJ = 2.68). We analyzed the polarization degree of QY1 as a function of phase angle and found its maximum polarization degree, $Pmax=8.68{\pm}0.28%$ and $8.72{\pm}0.38%$, in RC-and V-band, respectively, around the phase angle of ${\alpha}=100^{\circ}$. In addition, we obtained the geometric albedo, $pV=0.16{\pm}0.02$ by means of an empirical slope-albedo law. The polarimetric properties and the albedo value we acquired are similar to those of S-type asteroids rather than cometary nuclei. In this presentation, we introduce our observation and findings. In addition, we further discuss a dynamical transportation process from Mainbelt to the current orbit.

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Effectiveness of Calcium Nitrite in Retarding Corrosion of Steel in Concrete

  • Abosrra, L.;Youseffi, M.;Ashour, A.F.
    • International Journal of Concrete Structures and Materials
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    • v.5 no.1
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    • pp.65-73
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    • 2011
  • Corrosion of steel bars embedded in concrete admixed with 0%, 2% and 4% calcium nitrite (CN), having compressive strengths of 20 and 46 MPa was investigated. Reinforced concrete specimens were immersed in 3% NaCl solutions for 1, 7 and 15 days where 0.4A external current was applied to accelerate the chemical reactions. Corrosion rate was measured by retrieving electrochemical data via potentiodynamic polarization technique. Pull-out tests of reinforced concrete specimens were then conducted to assess the corroded steel-concrete bond characteristics. Experimental results showed that corrosion rate of steel bars and steel-concrete bond strength were dependent on concrete strength, amount of CN added and accelerated corrosion period. As concrete strength increased from 20 to 46 MPa, corrosion rate of embedded steel decreased. The addition of 2% CN to concrete of 20 MPa was not effective in retarding corrosion of steel at long time of exposure. However, the combination of higher strength concrete and 2% or 4% CN appear to be a desirable approach to reduce the effect of chloride-induced corrosion of steel reinforcement. After 1 day of corrosion acceleration, specimens without CN showed higher bond strength in both concrete mixes than those with CN. After 7 and 15 days of exposure, the higher concentration of CN, the higher bond strength in both concrete mixes achieved, except for the concrete specimen of 20 MPa compressive strength with 2% CN that recorded the highest deterioration in bond strength at 15 days of exposure.

AN ELECTROCHEMICAL STUDY ON THE OXIDATION' AND REDUCTION OF DENTAL AMALGAM (치과용 아말감의 산화환원에 관한 전기화학적 연구)

  • Yi, In-Bog;Lee, Myong-Jong
    • Restorative Dentistry and Endodontics
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    • v.18 no.2
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    • pp.431-445
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    • 1993
  • The purpose of this study was to observe corrosion characteristics of six dental amalgams and was to analyse corrosion products electrochemically. After each amalgam alloy and Hg was triturated as the direction of the manufacturer by using mechanical amalgamator, the triturated mass was inserted into the cylinderical metal mold ($12{\times}10mm$) and was condensed with 160kg/$cm^2$ by using the hydrolic press. The specimen was removed from the mold and was stored at room temperature for 1 week, and was polished with amalgam polishing kit. The anodic and cathodic polarization curve was obtained by using cyclic voltammetric method with 3-electrode potentiostat in saline for each amalgam and Ag, Sn, Cu plate specimen at $37{\pm}0.5^{\circ}C$. The potential sweep range was -1.7V~0. 4V(vs SCE) in working electrode and scan rate was 50mV/s and the exposed surface area of each specimen to the electrolytic solution was $0.79cm^2$. The results were as follows. 1. In anodic-cathodic polarization curve of amalgam specimens, two anodic current rising areas and two cathodic current peaks were obtained at the low Cu amalgam(CF, CS) specimen and three anodic current rising areas and three cathodic current peaks were obtained at the high Cu amalgam (TY, DS, HV) specimen. 2. As this compared with the anodic and cathodic current peak potentials of Sn, Cu and Ag specimen, the first cathodic current peak I c was caused by the reduction of divalent tin salt, second cathodic current peak IIIc results from the reduction of quadravalent tin salt, and third cathodic current peak me results from the reduction of copper salt. 3. As reverse potential sweeping was done repeatedly, anodic current was decreased slightly in all amalgam specimens.

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The Electrochemical Property of the Single-Chamber Solid Oxide Fuel Cell Based on a Zirconia Electrolyte (지르코니아 전해질을 이용한 단실형 고체산화물 연료전지의 전기화학 특성)

  • Park, Hee Jung;Joo, Jong Hoon;Yang, Jae-Kyo;Jin, Yun Ho;Lee, Kyu Hyoung
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.29 no.8
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    • pp.510-515
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    • 2016
  • Single-chamber solid oxide fuel cells (SC-SOFCs) consist of only one gas chamber, in which both the anode and the cathode are exposed to the same fuel-oxidant mixture. Thus, this configuration shows good thermal and mechanical resistance and allows rapid start-up and -down. In this study, the unit cell consisting of $La_{0.8}Sr_{0.2}MnO_3$ (cathode) / $Zr_{0.84}Y_{0.16}O_{2-x}$ (electrolyte) / $Ni-Zr_{0.84}Y_{0.16}O_{2-x}$ (anode) was fabricated and its electrochemical property was investigated as a function of temperature and the volume ratio of fuel and oxidant for SC-SOFCs. Impedance spectra were also investigated in order to figure out the electrical characteristics of the cell. As a result, the cell performance was governed by the polarization resistances of the electrodes. The cell exhibited an acceptable cell-performance of $86mW/cm^2$ at $800^{\circ}C$ and stable performance for 3 hs under 0.7 V.

Structural Stability During Charge-Discharge Cycles in Zr-doped LiCoO2 Powders (충방전 과정중 구조가 안정한 Zr이 도핑된 LiCoO2 분말)

  • Kim, Seon-Hye;Shim, Kwang-Bo;Ahn, Jae-Pyoung;Kim, Chang-Sam
    • Journal of the Korean Ceramic Society
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    • v.45 no.3
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    • pp.167-171
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    • 2008
  • Zirconium-doped $Li_{1.1}Co_{1-x}Zr_xO_2(0{\leq}x{\leq}0.05)$ powders as cathode materials for lithium ion batteries were synthesized using an ultrasonic spray pyrolysis method. Cyclic voltammetry and cyclic stability tests were performed, and the changes of microstructure were observed. The solubility limit of zirconium into $Li_{1.1}CoO_2$ was less than 5 mol%, and monoclinic $Li_2ZrO_3$ phase was formed above the limit. The Zr-doping suppressed the grain growth and increased the lattice parameters of the hexagonal $LiCoO_2$ phase. The Zr-dopiong of 1mol% resulted in the best cyclic performance in the range of $3.0{\sim}4.3V$ at 1C rate (140 mA/g); the initial discharge capacity decreased from 158 mAh/g to 60 mAh/g in the undoped powder, while from 154 mAh/g to 135 mAh/g in the Zr-doped powder of 1 mol% after 30 cycles. The excellent cycle stability of Zr-doped powder was due to the low polarization during chargedischarge processes which resulted from the delayed collapse of the crystal structure of the active materials with Zr-doping.

A High-Resolution Heterodyne Interferometer using Beat Frequency between Two-Axial Modes of a HeNe Laser (2-종 모드 레이저를 이용한 고분해능 헤터로다인 간섭계)

  • 김민석;김승우
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 1997.10a
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    • pp.214-219
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    • 1997
  • We propose a new scheme of high-resolution heterodyne interferometer that employs the two-axial mode He-Ne laser with an inter-mode beat frequency of 600-1000 MHz. An electronic RF-heterodyne circuit lowers the beat frequency down to 5 MHz, so that the phase change of the interferometer output is precisely measured with a displacement resolution of 0.1 nanometer without significant loss of dynamic bandwidth. A thermal control scheme is adopted to stabilize the cavity length with aims to suppress frequency drifts caused by the phenomena of frequency pulling and polarization anisotropy of the two-axial mode laser to a stability level of 2 parts in $10^9$. The two-axial mode HeNe laser yields a high output power of 2.0 mW, whlch allows us to perform multiple measurements of up to 10 machine axes simultaneously.

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