• Title/Summary/Keyword: M2 polarization

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An Investigation on the Tetrahydropyrimidine Derivatives as Acid Corrosion Inhibitors for Mild Steel

  • Chitra, S.;Gayathri, N.;Parameswari, K.
    • Corrosion Science and Technology
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    • v.8 no.2
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    • pp.45-52
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    • 2009
  • The corrosive behavior of mild steel in 0.05 M to 10 M $H_2SO_4$ solutions containing different concentrations of tetrahydropyrimidine derivatives (THPM) was investigated using weight loss method, gasometric technique, electrochemical studies which include AC - impedance and potentiodynamic polarization method, atomic absorption studies and synergistic effect. The results obtained reveal that THPM derivatives is an efficient mixed type inhibitor but slightly anodic and it is more effective in reducing corrosion of mild steel in $H_2SO_4$ media. The adsorption of the inhibitor on the mild steel surface obeys the Langmuir adsorption isotherm. The thermodynamic parameters of adsorption reveal a strong interaction and spontaneous adsorption of THPM on the mild steel surface. The influence of temperature and inhibitor concentration on the corrosion of mild steel has also been investigated.

A Study on the Galvanic corrosion and its Protection on Heat Exchanger Tube Plate (열교환기 관판의 전지작용부식과 방지에 관한 연구)

  • 임우조;홍성희;윤병두
    • Journal of Advanced Marine Engineering and Technology
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    • v.25 no.2
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    • pp.344-350
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    • 2001
  • This paper was studied on the characteristics of galvanic corrosion and its protection on heat exchanger tube plate in the sea water. In this paper, behavior of pitting corrosion of Ni-al bronze connected with Ti tube was measured af flow velocity of 0 m/s and 2.4 m/s. To protect galvanic corrosion, the protection characteristics of Ni-Al bronze connected with Ti tube by Zn-base alloys galvanic anode and hexagonal nylon insert was investigated. Main results obtained asre al follows: 1) The galvanic corrosion of Ni-Al bronze connected with Ti-tube is more active than single Ni-al bronze. 2) As the circuit resistance increase under the cathodic protection employing Zn-base alloys galvanic anode, Ni-al bronze connected with Ti tube is cathodically unpolarized. 3) The corrosion of Ni-Al bronze connected with Ti tube by nylon insert controls approximately 73% than not nylon insert.

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A Study on the Galvanic corrosion and its Protection on Heat Exchanger Tube Plate (열교환기 관판의 전지작용부식과 방지에 관한 연구)

  • U-J Lim;S-H Hong;B-D Yun
    • Journal of Advanced Marine Engineering and Technology
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    • v.25 no.2
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    • pp.345-345
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    • 2001
  • This paper was studied on the characteristics of galvanic corrosion and its protection on heat exchanger tube plate in the sea water. In this paper, behavior of pitting corrosion of Ni-al bronze connected with Ti tube was measured af flow velocity of 0 m/s and 2.4 m/s. To protect galvanic corrosion, the protection characteristics of Ni-Al bronze connected with Ti tube by Zn-base alloys galvanic anode and hexagonal nylon insert was investigated. Main results obtained asre al follows: 1) The galvanic corrosion of Ni-Al bronze connected with Ti-tube is more active than single Ni-al bronze. 2) As the circuit resistance increase under the cathodic protection employing Zn-base alloys galvanic anode, Ni-al bronze connected with Ti tube is cathodically unpolarized. 3) The corrosion of Ni-Al bronze connected with Ti tube by nylon insert controls approximately 73% than not nylon insert.

Pyroelectricity of Ni-doped PMNT Ferroelectric for Pyroelectric Detector

  • Kim, Yeon Jung
    • Applied Science and Convergence Technology
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    • v.24 no.6
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    • pp.215-218
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    • 2015
  • A pyroelctric properties of Ni(x)-doped PMNT systems were analyzed. Modified PMNT samples were prepared using the columbite structure method. Pyroelectric current, polarization, dielectric constant and dissipation factor of Ni-doped PMNT samples were measured as a function of temperature. By adding a small amount of NiO, pyroelectricity of PMNT is increased. Unlike the normal $ABO_3$ ferroelectric, Ni-doped PMNT showed properties for relaxor ferroelectric of causing the successive phase transition over a wide temperature. The optimum conditions for obtaining compositions with improvement ferroelectric properties are a nominal addition of 0.02 mole% Ni. Also, Ni-doped PMNT ferroelectric showed excellent pyroelectric figures of merit in the vicinity of room temperature. The pyroelectric coefficient ($0.00524C/m^2K$ at $25^{\circ}C$) and figures of merit ($F_v{\sim}0.039m^2/C$ and $F_d{\sim}0.664{\times}10^{-4}Pa^{-1/2}$) of composition PMNT with 0.02 mole% Ni are comparable to the earlier reports on lead-type pyroelectrics.

MOGABA: Monitoring of Gamma-ray Bright AGN with KVN 21-m radio telescopes at 22 and 43GHz

  • Lee, Sang-Sung;Yang, Ji-Hae;Byun, Do-Young;Sohn, Bong-Won
    • The Bulletin of The Korean Astronomical Society
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    • v.36 no.2
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    • pp.59.2-59.2
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    • 2011
  • We introduce an ongoing project for monitoring total flux density at 22 and 43GHz, linearly polarized flux, and polarization angle at 22GHz of Gamma-ray bright AGN (Active Galactic Nuclei) with KVN (Korean VLBI Network) 21-m radio telescopes. The project started in May, 2011 with an effective monitoring cycle of 4 days, observing four main objects (3C 454.3, BL Lac, 3C 273, and 3C 279). More objects were included in the source list when they had flared in Gamma-ray. In this paper, we report the current status of the project and preliminary results for the monitoring observations.

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Fabrication and Characterizations of Thick PZT Films for Micro Piezoelectric Devices (마이크로 압전 소자용 후막 PZT의 제조 및 물성 평가)

  • 박준식;박광범;윤대원;박효덕;강성군;최태훈;이낙규;나경환
    • Transactions of Materials Processing
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    • v.11 no.7
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    • pp.569-574
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    • 2002
  • Recently, thick PZT films are required for the cases of micro piezoelectric devices with high driving force, high breakdown voltage and high sensitivity, and so on. In this work, thick PZT films were fabricated by Sol-Gel multi-coating method. Microstructures, and electrical properties of films were investigated by XRD, FESEM, impedance analyzer, and P-E hysteresis. PZT films with 2.7$mu extrm{m}$ to 4.4${\mu}{\textrm}{m}$ thickness were fabricated. Dielectric constant, loss, remnant polarization and coercive field of them were 880~1650 at 1kHz, 2~3% at 1kHz, 26~32 $\mu$C/$ extrm{cm}^2$, and 33~60kV/cm, respectively. Also a transverse piezoelectric coefficient $(e_{31,f})$ measurement system was fabricated and tested for thick film samples.

Complex Detection Between Transcription Regulator and Promoter DNA by UV Spectroscopic Method

  • Lee, Kyungmin;Gang, Jongback
    • Journal of Integrative Natural Science
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    • v.5 no.3
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    • pp.163-167
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    • 2012
  • UV spectrophotometer was used to detect protein-DNA complex from DNA melting profile under constant temperature increase. Melting temperature (Tm) was $43^{\circ}C$ in copA duplex DNA alone. In the presence of Proteus mirabilis transcription regulator protein (PMTR) protein at 0.2 and 0.4 ${\mu}M$, Tm's were $45{\pm}0.5$ and $47.6{\pm}0.6^{\circ}C$, respectively. According to fluorescence polarization and gel shift assay. PMTR:copA complex was detected by the retarded migration on gel and the dissociation constant ($K_d$) was $(9.2{\pm}2.8){\times}10^{-9}M$.

Micromachining of the Si Wafer Surface Using Femtoseocond Laser Pulses (펨토초 레이저를 이용한 실리콘 웨이퍼 표면 미세가공 특성)

  • Kim, Jae-Gu;Chang, Won-Seok;Cho, Sung-Hak;Whang, Kyung-Hyun;Na, Suck-Joo
    • Journal of the Korean Society for Precision Engineering
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    • v.22 no.12 s.177
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    • pp.184-189
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    • 2005
  • An experimental study of the femtosecond laser machining of Si materials was carried out. Direct laser machining of the materials for the feature size of a few micron scale has the advantage of low cost and simple process comparing to the semiconductor process, E-beam lithography, ECM and other machining process. Further, the femtosecond laser is the better tool to machine the micro parts due to its characteristics of minimizing the heat affected zone(HAZ). As a result of line cutting of Si, the optimal condition had the region of the effective energy of 2mJ/mm-2.5mJ/mm with the power of 0.5mW-1.5mW. The polarization effects of the incident beam existed in the machining qualities, therefore the sample motion should be perpendicular to the projection of the electric vector. We also observed the periodic ripple patterns which come out in condition of the pulse overlap with the threshold energy. Finally, we could machined the groove with the linewidth of below $2{\mu}m$ for the application of MEMS device repairing, scribing and arbitrary patterning.

The Effects of Surface Condition and Flow Rate to the Cathodic Protection Potential and Current on Steel (강의 음극방식에 미치는 표면상태와 유속의 영향)

  • Kyeong-soo, Chung;Seong- Jong, Kim;Myung-Hoon, Lee;Ki-Joon, Kim;Kyung-Man, Moon
    • Journal of Advanced Marine Engineering and Technology
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    • v.28 no.6
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    • pp.972-980
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    • 2004
  • Cathodic protection is being widely used to protect steel structures in sea water environment, In order to protect steel structures completely, the flow condition of sea water surrounding with this structures and the surface condition of the structures must be considered for a desirable design of cathodic protection. In this study, the optimum protection potential and current density were investigated in terms of cathodic current density, surface condition and a flow condition of sea water. The optium protection potential of the cleaned specimen was -770 mV(SCE) and below. However in the case of the rusted specimen, its potential was -700 mV(SCE) and below, which was somewhat positive than the cleaned one irrespective of flow condition. The optimum cathodic protection current density for both the cleaned and rusted specimens was 100 mA/$\textrm{m}^2$, however, on the flow condition, 200 mA/$\textrm{m}^2$ to be supplied for cathodic protection of steel structures completely for both cleaned and rusted specimens.

Electrochemical Corrosion Behaviors of Amorphous $Zr_{65}Al_8Ni_{15}Cu_{12}$ Alloy (비정질 $Zr_{65}Al_8Ni_{15}Cu_{12}$ 금속합금의 전기화학적 부식 특성)

  • Kim, Hyun-Goo
    • Journal of Integrative Natural Science
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    • v.2 no.4
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    • pp.233-236
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    • 2009
  • This study was undertaken to measure the electrochemical corrosion of amorphous $Zr_{65}Al_8Ni_{15}Cu_{12}$ (at.%) alloy ribbon under various conditions, including 0.4 mM HCl solution, and for various values of the pH and the immersion time. The corrosion potentials($E_{corr}$) for the amorphous $Zr_{65}Al_8Ni_{15}Cu_{12}$ alloy in 0.4 mM HCl decreased with increasing temperature; the corrosion current density($I_{corr}$) increased with increasing temperature in general. The polarization resistance($R_p$) was inversely proportional to the corrosion rate. While pH=7, 9, 11 was not as sensitive as pH=3, 5, pH=3 was more sensitive for amorphous $Zr_{65}Al_8Ni_{15}Cu_{12}$ alloy than other pHs specially. The change of mass in the 70 mM $H_2SO_4$ solution with immersion time was the greatest in the first 100 h.

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