• Title/Summary/Keyword: M-splitting

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Absorption Characteristics of Carbon Dioxide by Water-lean Diethylenetriamine Absorbents Mixed with Physical Solvents (물리 흡수제를 포함한 디에틸렌트리아민(Diethylenetriamine) 저수계 흡수제에서의 이산화탄소 흡수 특성)

  • Lee, Hwa Young;Seok, Chang Hwan;You, Jong-Kyun;Hong, Yeon Ki
    • Clean Technology
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    • v.24 no.1
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    • pp.50-54
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    • 2018
  • In this work, N-methyl-2-pyrrolidone (NMP) was added into diethylenetriamine (DETA) aqueous solution for high $CO_2$ loading via phase splitting of absorbents during $CO_2$ absorption. Immiscible two phases were formed in the range of more than 30 wt% of NMP in 2 M DETA + NMP + water absorbents because of low solubility of DETA-carbamate in NMP solution. As the composition of NMP in the absorbents increased, the difference of $CO_2$ loading between each phase increased and the volume of bottom phase decreased. In $CO_2$ absorption in packed column by 2 M DETA + NMP + water absorbents, the absorption rate decreased in the range of more than 40 wt% of NMP. It is due to the increasing of mass transfer resistance in liquid film of absorbents at the high concentration of NMP. DETA + NMP + water absorbent is expected as the promising one for reducing the regeneration energy of absorbents according to volume reduction of $CO_2-rich$ phase.

Mössbauer Spectroscopic Studies of NiZn Ferrite Prepared by the Sol-Gel Method

  • Niyaifar, Mohammad;Mohammadpour, Hory;Rodriguez, Anselmo F.R.
    • Journal of Magnetics
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    • v.20 no.3
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    • pp.246-251
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    • 2015
  • This study was aimed to study the effect of Zn content on the hyperfine parameters and the structural variation of $Ni_{1-x}Zn_xFe_2O_4$ for x = 0, 0.2, 0.4, 0.6, and 0.8. To achieve this, a sol-gel route was used for the preparation of samples and the obtained ferrites were investigated by X-ray diffraction, scanning electron microscopy, and $M{\ddot{o}}ssbauer$ spectroscopy. The formation of spinel phase without any impurity peak was identified by X-ray diffraction of all the samples. Moreover, the estimated crystallite size by X-ray line broadening indicates a decrease with increasing Zn content. This result was in agreement with the scanning electron microscopy result, indicating the reduction in grain growth with further zinc substitution. The room-temperature $M{\ddot{o}}ssbauer$ spectra show that the hyperfine fields at both the A and B sites decreased with increasing Zn content; however, the rate of reduction is not the same for different sites. Moreover, the best fit parameter showed that the quadrupole splitting values of B site increased from the pure nickel ferrite to the sample with x = 0.8.

Discovery of a Cloud Collision with the OMC-1

  • Kim, Kwang-Tae;Kim, Youngsik
    • The Bulletin of The Korean Astronomical Society
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    • v.42 no.1
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    • pp.32.3-33
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    • 2017
  • Utilizing both the existing observational data for Orion A and the TRAO $^{13}CO$, $^{12}CO$ data for $1^{\circ}{\times}1^{\circ}$ region centered on M42 collected in 2012, we found a clear piece of evidence for a collision of a cloud with the OMC-1. This cloud has a shape like a long cylinder of ${\sim}0.1pc{\times}2pc$ in size, and has a well developed train of clumps of about a few solar masses, and is situated in the dark dust complex between M42 and M43. The cloud's motion is analysed to be moving at about $2.6km\;s^{-1}$, and is calculated to transverse the Orion Nebula ~2 pc above from the nebula center, toward the direction of about $60^{\circ}$ to the line of sight. This cloud had undergone a tidal splitting about a million years ago and had formed a very thin and long cylindrical core well before being engaged in the collision. General implications of this phenomenon are discussed in relation to star formation mechanisms in the GMC.

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Concave Surface Boundary Layer Flows in the Presence of Streamwise Vortices

  • Winoto, Sonny H.;Tandiono, Tandiono;Shah, Dilip A.;Mitsudharmadi, Hatsari
    • International Journal of Fluid Machinery and Systems
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    • v.4 no.1
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    • pp.33-46
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    • 2011
  • Concave surface boundary-layer flows are subjected to centrifugal instability which results in the formation of streamwise counter-rotating vortices. Such boundary layer flows have been experimentally investigated on concave surfaces of 1 m and 2 m radius of curvature. In the experiments, to obtain uniform vortex wavelengths, thin perturbation wires placed upstream and perpendicular to the concave surface leading edge, were used to pre-set the wavelengths. Velocity contours were obtained from hot-wire anemometer velocity measurements. The most amplified vortex wavelengths can be pre-set by the spanwise spacing of the thin wires and the free-stream velocity. The velocity contours on the cross-sectional planes at several streamwise locations show the growth and breakdown of the vortices. Three different vortex growth regions can be identified. The occurrence of a secondary instability mode is also shown as mushroom-like structures as a consequence of the non-linear growth of the streamwise vortices. Wall shear stress measurements on concave surface of 1 m radius of curvature reveal that the spanwise-averaged wall shear stress increases well beyond the flat plate boundary layer values. By pre-setting much larger or much smaller vortex wavelength than the most amplified one, the splitting or merging of the streamwise vortices will respectively occur.

Bond strength prediction of spliced GFRP bars in concrete beams using soft computing methods

  • Shahri, Saeed Farahi;Mousavi, Seyed Roohollah
    • Computers and Concrete
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    • v.27 no.4
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    • pp.305-317
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    • 2021
  • The bond between the concrete and bar is a main factor affecting the performance of the reinforced concrete (RC) members, and since the steel corrosion reduces the bond strength, studying the bond behavior of concrete and GFRP bars is quite necessary. In this research, a database including 112 concrete beam test specimens reinforced with spliced GFRP bars in the splitting failure mode has been collected and used to estimate the concrete-GFRP bar bond strength. This paper aims to accurately estimate the bond strength of spliced GFRP bars in concrete beams by applying three soft computing models including multivariate adaptive regression spline (MARS), Kriging, and M5 model tree. Since the selection of regularization parameters greatly affects the fitting of MARS, Kriging, and M5 models, the regularization parameters have been so optimized as to maximize the training data convergence coefficient. Three hybrid model coupling soft computing methods and genetic algorithm is proposed to automatically perform the trial and error process for finding appropriate modeling regularization parameters. Results have shown that proposed models have significantly increased the prediction accuracy compared to previous models. The proposed MARS, Kriging, and M5 models have improved the convergence coefficient by about 65, 63 and 49%, respectively, compared to the best previous model.

Performance of self-compacting geopolymer concrete with and without GGBFS and steel fiber

  • Al-Rawi, Saad;Taysi, Nildem
    • Advances in concrete construction
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    • v.6 no.4
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    • pp.323-344
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    • 2018
  • The study herein reports the impact of Steel Fiber (SF) and Ground Granulated Blast Furnaces slag (GGBFS) content on the fresh and hardened properties of fly ash (FA) based Self-Compacting Geopolymer Concrete (SCGC). Two series of self-compacting geopolymer concrete (SCGC) were formulated with a constant binder content of $450kg/m^3$ and at an alkaline-to-binder (a/b) ratio of 0.50. Fly ash (FA) was substituted with GGBFS with the replacement levels being 0%, 25%, 50%, 75%, and 100% by weight in each SCGC series. Steel fiber (SF) wasn't employed in the assembly of the initial concrete series whereas, within the second concrete series, an SF combination was achieved by a constant additional level of 1% by volume. Fresh properties of mixtures were through an experiment investigated in terms of slump flow diameter, T50 slump flow time, V-funnel flow time, and L-box height ratio. Moreover, the mechanical performance of the SCGCs was evaluated in terms of compressive strength, splitting tensile strength, and fracture toughness. Furthermore, a statistical analysis was applied in order to judge the importance of the experimental parameters, like GGBFS and SF contents. The experimental results indicated that the incorporation of SF had no vital impact on the fresh characteristics of the SCGC mixtures whereas GGBFS aggravated them. However, the incorporation of GGBFS was considerably improved the mechanical properties of SCGCs. Moreover, the incorporation of SF with the total different quantity of GGBFS replacement has considerably increased the mechanical properties of SCGCs, by close to (65%) for the splitting strength and (200%) for compressive strength.

Growth and characterization of ZnIn$_2$S$_4$ single crystal thin film using Hot Wall Epitaxy method (Hot Wall Epitaxy (W)에 의한 ZnIn$_2$S$_4$ 단결정 박막 성장과 특성)

  • 윤석진;홍광준
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2002.07a
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    • pp.266-272
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    • 2002
  • The stochiometric mixture of evaporating materials for the ZnIn$_2$S$_4$ single crystal thin film was prepared from horizontal furnace. To obtain the ZnIn$_2$S$_4$ single crystal thin film, ZnIn$_2$S$_4$ mixed crystal was deposited on throughly etched semi-insulating GaAs(100) in the Hot Wall Epitaxy(HWE) system. The source and substrate temperature were 610 $^{\circ}C$ and 450 $^{\circ}C$, respectively and the growth rate of the ZnIn$_2$S$_4$ single crystal thin film was about 0.5 $\mu\textrm{m}$/hr. The crystalline structure of ZnIn$_2$S$_4$ single crystal thin film was investigated by photo1uminescence and double crystal X-ray diffraction(DCXD) measurement. The carrier density and mobility of ZnIn$_2$S$_4$ single crystal thin film measured from Hall effect by van der Pauw method are 8.51${\times}$10$\^$17/ cm$\^$-3/, 291 $\textrm{cm}^2$/V$.$s at 293 $^{\circ}$K, respectively. From the photocurrent spectrum by illumination of perpendicular light on the c - axis of the ZnIn$_2$S$_4$ single crystal thin film, we have found that the values of spin orbit splitting ΔSo and the crystal field splitting ΔCr were 0.0148 eV and 0.1678 eV at 10 $^{\circ}$K, respectively. From the photoluminescence measurement of ZnIn$_2$S$_4$ single crystal thin film, we observed free excition (E$\_$X/) typically observed only in high quality crystal and neutral donor bound exciton (D$^{\circ}$,X) having very strong peak intensity. The full width at half maximum and binding energy of neutral donor bound excition were 9 meV and 26 meV, respectively. The activation energy of impurity measured by Haynes rule was 130 meV.

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Growth and Optoelectrical Properties for $AgGaSe_2$ Single Crystal Thin Films ($AgGaSe_2$ 단결정 박막 성장과 광전기적 특성)

  • Hong, Kwang-Joon;You, Sang-Ha
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2004.11a
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    • pp.171-174
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    • 2004
  • The stochiometric $AgGaSe_2$ polycrystalline mixture of evaporating materials for the $AgGaSe_2$ single crystal thin film was prepared from horizontal furnace. To obtain the single crystal thin films, $AgGaSe_2$ mixed crystal and semi-insulating GaAs(100) wafer were used as source material and substrate for the Hot Wall Epitaxy (HWE) system, respectively. The source and substrate temperature were fixed at $630^{\circ}C$ and $420^{\circ}C$, respectively. The thickness of grown single crystal thin films is $2.1{\mu}m$. The single crystal thin films were investigated by photoluminescence and double crystal X-ray diffraction(DCXD) measurement. The carrier density and mobility of $AgGaSe_2$ single crystal thin films measured from Hall effect by van der Pauw method are $4.89{\times}10^{17}\;cm^{-3},\;129cm^2/V{\cdot}s$ at 293K, respectively. From the photocurrent spectrum by illumination of perpendicular light on the c - axis of the $AgGaSe_2$ single crystal thin film, we have found that the values of spin orbit splitting ${\Delta}S_o$ and the crystal field splitting ${\Delta}C_r$ were 0.1762 eV and 0.2494 eV at 10 K, respectively. From the photoluminescence measurement of $AgGaSe_2$ single crystal thin film, we observed free excition $(E_X)$ observable only in high quality crystal and neutral bound exciton $(D^o,X)$ having very strong peak intensity And, the full width at half maximum and binding energy of neutral donor bound excition were 8 meV and 14.1 meV, respectively. By Haynes rule, an activation energy of impurity was 141 meV.

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SPMLD: Sub-Packet based Multipath Load Distribution for Real-Time Multimedia Traffic

  • Wu, Jiyan;Yang, Jingqi;Shang, Yanlei;Cheng, Bo;Chen, Junliang
    • Journal of Communications and Networks
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    • v.16 no.5
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    • pp.548-558
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    • 2014
  • Load distribution is vital to the performance of multipath transport. The task becomes more challenging in real-time multimedia applications (RTMA), which impose stringent delay requirements. Two key issues to be addressed are: 1) How to minimize end-to-end delay and 2) how to alleviate packet reordering that incurs additional recovery time at the receiver. In this paper, we propose sub-packet based multipath load distribution (SPMLD), a new model that splits traffic at the granularity of sub-packet. Our SPMLD model aims to minimize total packet delay by effectively aggregating multiple parallel paths as a single virtual path. First, we formulate the packet splitting over multiple paths as a constrained optimization problem and derive its solution based on progressive approximation method. Second, in the solution, we analyze queuing delay by introducing D/M/1 model and obtain the expression of dynamic packet splitting ratio for each path. Third, in order to describe SPMLD's scheduling policy, we propose two distributed algorithms respectively implemented in the source and destination nodes. We evaluate the performance of SPMLD through extensive simulations in QualNet using real-time H.264 video streaming. Experimental results demonstrate that: SPMLD outperforms previous flow and packet based load distribution models in terms of video peak signal-to-noise ratio, total packet delay, end-to-end delay, and risk of packet reordering. Besides, SPMLD's extra overhead is tiny compared to the input video streaming.

Distribution of Anatase Phase Depending on the Thermal Treatment Temperature of Tio2 Nanotubes and Its Effects on the Photocatalytic Efficiency (Tio2 나노튜브의 열처리 온도에 따른 Anatase 상의 분포와 그에 따른 광 촉매 효율)

  • Kim, Se-Im;Hwang, Ji-Hun;Lee, Seung-Wook;Kim, Rak-Kyoung;Son, Su-Min;Shaislamov, Ulugbek;Yang, Jun-Mo;Yang, Bee-Lyong
    • Journal of the Korean Ceramic Society
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    • v.45 no.6
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    • pp.331-335
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    • 2008
  • The purpose of this study is to characterize the photo-catalytic efficiency of $TiO_2$ nanotube with respect to the distribution of anatase phase which can be changed by the annealing temperature of $TiO_2$ nanotube. $TiO_2$ nanotube was fabricated by the anodization method in the 0.5 wt% HF electrolyte. And then the $TiO_2$ nanotube was annealed at temperatures ranging from $380^{\circ}C$ to $780^{\circ}C$ in dry oxygen ambient for 2 h. For the photo-catalytic water-splitting tests, the photocurrent density was measured as a function of applied potential with a potentiostat using a Ag/AgCl reference, Pt counter electrode, and 1 M KOH electrolyte under illumination of UV by a Xe arc lamp of 1 KW. According to the UV photo-catalytic water-splitting tests, the nanotube annealed at $560^{\circ}C$ was found to show the highest photocurrent density.