• Title/Summary/Keyword: M-A Constituents

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Effects of M-A Constituents on Toughness in the ICCG HAZ of SA508-cl.3 Pressure Vessel Steel (SA508-cl.3강의 ICCG HAZ의 인성에 미치는 M-A Constituentsm의 영향)

  • 권기선;김주학;홍준화;이창희
    • Journal of Welding and Joining
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    • v.17 no.3
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    • pp.55-65
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    • 1999
  • Metallurgical factors influencing toughness of the Intercritically Reheated Coarse-Grained Heat Affected Zone (ICCG HAZ) of multiple welded SA508-cl.3 Reactor Pressure Vessel Steel were evaluated. The recrystallized austenite formed along the prior austenite grain boundaries and late interfaced on heating to the intercritical range was transformed to bainite and/or martensite during cooling. The newly formed martensite always included some retained austenite(M-A constituents). The characteristics(amount, hardness, density, and size) of M-A constituents were found to be strongly associated with both peak temperature and cooling time(△t8/5(2)) of last pass. Toughness in the ICCG HAZ was deteriorated with increasing amount of M-A constituents which was increased with increasing the last peak temperature within the intercritical temperature range. Meanwhile, for the same intercritical peak temperature, toughness was decreased with increasing cooling time. When cooling time was short, the dominant factor influencing toughness of the ICCG HAZ was amount of M-A constituents. However, when cooling time was lengthened, the hardness difference between M-A constituents and softened matrix(tempered martensite) was found to be the dominant factor.

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Correlation Between M-A Constituents and Tensile Properties in the Intercritical Coarse Grained HAZ of an Ultra Low Carbon Steel (극 저탄소강의 Intercritical coarse grained HAZ에서의 M-A상과 인장특성 간의 상관관계)

  • Lee, Yoon-Ki;Moon, Joon-Oh;Kim, Sang-Hoon;Lee, Chang-Hee
    • Journal of Welding and Joining
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    • v.28 no.3
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    • pp.99-103
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    • 2010
  • It is well known that martensite-austenite (M-A) constituents are formed in the intercritically reheated coarse grained heat affected zone (ICCGHAZ) of a multipass weld and they act on the local brittle zone (LBZ) in the welded structures. To investigate the effect of M-A constituents on the tensile properties of ICCGHAZ, specimens with M-A constituents of different volume fraction and size were prepared through the multipass welding cycles simulated by a Gleeble simulator and then tensile test was carried out. The results indicated that finely distributed M-A constituents contributed to decrease the yield ratio, which is mainly due to the increased tensile strength.

Comparison of Lipid Constituents in soybean and Beanpaste (대두와 된장의 지용성 성분 비교)

  • Cha, Bae-Cheon
    • Korean Journal of Pharmacognosy
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    • v.25 no.4 s.99
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    • pp.342-347
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    • 1994
  • Soybean and beanpaste have been used as ore of the important food in Korea. Beanpaste is made from soybean(seed of Glycine max $M_{ERRIL}$, Leguminosae) by traditional fermentation. It was expected that the secondary metabolites might be formed by the action of some microorganisms or enzymes on the constituents primarily contained in soybean during manufacturing or storage of beanpaste. A systematic investigation on the chemical constituents was carried out. As a result, sterol glycoside named daucosterin, lipo-daucosterin have been isolated from the lipid fraction soybean and their structures elucidated basis of chemical and physicochemical evidences. A ratio of composition of the lipid constituents in soybean and beanpaste were estimated.

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Impact of Dissolved Wastewater Constituents on Laccase-Catalyzed Treatment of Bisphenol A

  • Kim, Young-Jin
    • Journal of Environmental Health Sciences
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    • v.30 no.2
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    • pp.161-166
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    • 2004
  • The impact of dissolved wastewater constituents on the treatment of synthetic bisphenol A (BPA) solutions was investigated under a variety of reaction conditions. The laccase enzyme from Trametes vesicolor was used for the BPA treatment. The constituents studied included various inorganic salts, organic compounds and heavy metal ions. BPA degradation was inhibited by sulfate, thiosulfate, sulfide, nitrite, and cyanide ions at 25 mg/$\ell$, 100mg/$\ell$, 25 mg/$\ell$ 150 mg/$\ell$, and 2.5 mg/$\ell$, respectively. However, the inhibitive effects of sulfide and sulfite on BPA degradation were diminished by additional aeration to oxidize them. Formaldehyde significantly reduced the rate of BPA degradation at 1.0% among organic compounds studied. Among heavy metal ions tested, Fe(II) substantially suppressed BPA removal at 1 mM. MgCl$_2$ and CaCl$_2$ exhibited great inhibition of BPA degradation at 25mM.

Local brittle zone of offshore structural steel welds (해양구조용 강재의 국부취화영역에 관한 연구)

  • 김병천;엄정현;이종섭;이성학;이두영
    • Journal of Welding and Joining
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    • v.7 no.2
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    • pp.35-48
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    • 1989
  • This study is concerned with a correlation of microstructure and local brittle zone (LBZ) in offshore structural steel welds. The influence of the LBZ on fracture toughness was investigated by means of simulated heat-affected zone (HAZ) tests as well as welded joint tests. Micromechanical processes involved in void and cleavage microcrack formation were also identified using notched round tensile tests and subsequent SEM observations. The LBZ in the HAZ of a multiphase welded joint is the interstitially reheated coarse grained HAZ, which is influenced by metallurgical factors such as effective grain size, the major matrix structure and the amount of high-carbon martensite-austenite (M-A) constituents. The experimental results indicate that Chirpy energy was found to scale monotonically with the amount of M-A constituents, confirming that the M-A constituent is the major microstructural factor controlling the HAZ toughness. In addition, voids and microcracks are observed to initiate at M-A constituents by the shear cracking process. Thus, the M-A constituent played an important role in initiating the voids and microcracks, and consequently caused brittle fracture.

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Evaluation of Nigella sativa Seed Constituents for Their in vivo Toxicity in Mice

  • EI-Hadiyah, T.M.;Raza, M.;Mohammed, O.Y.;Abdallah, A.A.
    • Natural Product Sciences
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    • v.9 no.1
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    • pp.22-27
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    • 2003
  • This study was designed to investigate the effects of main constituents of Nigella sativa (NS) seed on the survival and CNS responses in experimental animals. The toxicological investigations were conducted for the determination of median lethal doses $(LD_{50})$ of NS seed constituents [i.e. aqueous extract (AE), fixed oil (FO), volatile oil (VO)] and main components of its VO [i.e. thymoquinone (TQ), ${\alpha}-pinene$ (AP) and p-cymene (PC)]. A part of this study includes evaluation NS constituents in the induction of minimal neurological deficit (MND) as a parameter for neurotoxicity using chimney test. In this study, the i.p. $LD_{50}$ values of AE, FO, VO, TQ (suspended In 0.5%CMC), TQ (dissolved in corn oil), AP and PC, were 3020, 3371, 1853, 616.6, 90.3, 1726 and 1523 mg/kg, respectively. All the NS constituents can be considered moderately toxic ($LD_{50}$ ranged from 616.6 to 3371 mg/kg), except the oily solution of TQ, which was very toxic ($LD_{50}$ was 90.3 mg/kg). It appeared that the toxicity of the whole VO is mainly due to its content of TQ and to some extent PC. All the NS constituents induced different degrees of MND at certain dose levels. The median neurotoxic (or sedating) doses $(TD_{50})$ of AE, FO, VO, TQ (suspended in CMC) and AP and PC, were 950, 1403, 306, 88.1, >173 and 368 mg/kg, respectively. TQ was the most potent component in inducing MND, whereas the FO and AE were the least. Neurotoxicity induced by the VO in the chimney test may refer basically to its contents of TQ and to some extent PC and AP.

Nonlinear Tidal Characteristics along the Uldolmok Waterway off the Southwestern Tip of the Korean Peninsula

  • Kang, Sok-Kuh;Yum, Ki-Dai;So, Jae-Kwi;Song, Won-Oh
    • Ocean and Polar Research
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    • v.25 no.1
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    • pp.89-106
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    • 2003
  • Analyses of tidal observations and a numerical model of the $M_2$ and $M_4$ tides in the Uldolmok waterway located at the southwestern tip of the Korean Peninsula are described. This waterway is well known fer its strong tidal flows of up to more than 10 knots at the narrowest part of the channel. Harmonic analysis of the observed water level at five tidal stations reveals dramatic changes in the amplitude and phase of the shallow water constituents at the station near the narrowest part, while survey results show a decreasing trend in local mean sea levels toward the narrow section. It was also observed that the amplitudes of semi-diurnal constituents, $M_2$ and $S_2$ are diminishing toward the narrowest part of the waterway. Two-dimensional numerical modeling shows that the $M_2$ energy flux is dominated by the component coming from the eastern boundary. The $M_2$ energy is inward from both open boundaries and is transported toward the narrow region of the channel, where it is frictionally dissipated or transferred to other constituents due to a strong non-linear advection effect. It is also shown that the $M_4$ generation is strong around the narrow region, and the abrupt decrease in the M4 amplitude in the region is due to a cancellation of the locally generated M4 with the component propagated from open boundaries. The superposition of both propagated and generated M4 contributions also explains the discontinuity of the M4 phase lag in the region. The tide-induced residual sea level change and the regeneration effect of the $M_2$ tide through interaction with $M_4$ are also examined.

Estimating Ocean Tidal Constituents Using SAR Interferometric Time Series over the Sulzberger Ice Shelf, W. Antarctica

  • Baek, Sang-Ho;Shum, C.K.
    • Journal of the Korean Society of Surveying, Geodesy, Photogrammetry and Cartography
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    • v.36 no.5
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    • pp.343-353
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    • 2018
  • Ocean tides in Antarctica are not well constrained mostly due to the lack of tidal observations. Especially, tides underneath and around ice shelves are uncertain. InSAR (Interferometric Synthetic Aperture Radar) data has been used to observe ice shelf movements primarily caused by ocean tides. Here, we demonstrate that it is possible to estimate tidal constituents underneath the Sulzberger ice shelf, West Antarctica, solely using ERS-1/2 tandem mission DInSAR (differential InSAR) observations. In addition, the tidal constituents can be estimated in a high-resolution (~200 m) grid which is beyond any tidal model resolution. We assume that InSAR observed ocean tidal heights can be derived after correcting the InSAR data for the effect of atmospheric loading using the inverse barometric effect, solid earth tides, and ocean tide loading. The ERS (European Remote Sensing) tandem orbit configuration of a 1-day separation between SAR data takes diminishes the sensitivity to major tidal constituents including $K_1$ and $S_2$. Here, the dominant tidal constituent $O_1$ is estimated using 8 differential interferograms underneath the Sulzberger ice shelf. The resulting tidal constituent is compared with a contemporary regional tide model (CATS2008a) and a global tide model (TPXO7.1). The InSAR estimated tidal amplitude agrees well with both models with RMS (root-mean-square) differences of < 2.2 cm and the phase estimate corroborating both tide models to within $8^{\circ}$. We conclude that fine spatial scale (~200 m) Antarctic ice shelf ocean tide determination is feasible for dominant constituents using C-band ERS-1/2 tandem mission InSAR.

A Case Study on the Effect of Hypobaric-Hypoxic Intermittent Training on the Blood Constituents and Average Heart rate of Professional Handicapped Cyclists

  • Kim, Sang Hoon;Song, Young Wha;Kim, Hong Rae;Heo, Seo Yoon;Kim, Yong Youn
    • Journal of International Academy of Physical Therapy Research
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    • v.8 no.1
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    • pp.1114-1121
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    • 2017
  • The purpose of this study was to investigate the effects of hypobarichypoxic training program on competitive performance. This was done by observing their conditioning and measuring their blood constituents before and after a multi-staged intermittent training program, over 2 weeks. Three national handicapped cyclists were placed in a multi-leveled hypobaric-hypoxic (flat-4000 meter (m) high elevation) environment with consistent temperature and humidity ($23{\pm}2^{\circ}C$, $50{\pm}5%$) for 2 weeks. After the training, the blood constituents and average heart rate (HR) were measured and the following results were obtained. In all three athletes, there were no unique changes in red blood cell count, hemoglobin, and hematocrit, while there was a rise in the reticulocyte count. Observations of the difference in average HR during exercise at varying altitudes showed that athlete A had an average increase in the HR for the first 5 days at 2000 m. For athlete B, the comparison of the first and last training sessions at an altitude of 2000 m showed an HR increase of approximately 17%. For athlete C, there was a steady increase in the HR until day 7 of the training. As such, hypobaric-hypoxic training suggested that improvement of aerobic exercise performance in these athletes and it is recommended that there be a development for future training programs at high altitude, geared towards handicapped athletes of various disciplines.

Simultaneous Quantitation of Nine Constituents of Fraxinus rhynchophylla using High Performance Liquid Chromatography - Diode Array Detector

  • Ahn, Jong Hoon;Hwang, Bang Yeon;Lee, Mi Kyeong
    • Natural Product Sciences
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    • v.19 no.3
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    • pp.236-241
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    • 2013
  • A high-performance liquid chromatography-diode array detector (HPLC-DAD) method was established for quantitative evaluation of nine constituents of Fraxinus rhynchophylla such as four coumarins, esculin (1), fraxin (2), esculetin (3), fraxetin (4), three lignans, syringaresinol 4,4'-O-${\beta}$-diglucoside (5), pinoresinol 4-O-${\beta}$-glucoside (6), pinoresinol (9), one secoiridoid, oleuropein (7), and one coumarinolignan, cleomiscosin C (8). The preferred chromatographic condition was obtained on Phenomenex Gemini-NX (3 ${\mu}m$, C18 110A, $150{\times}4.60$ mm) and the mobile phase was composed of water and acetonitrile using a gradient elution. The wavelength was set at 220 nm. Extraction condition of these constituents in F. rhynchophylla was also optimized through extraction time, extraction solvent and extraction method using established method. From this study, extraction at $70^{\circ}C$ with the mixture of ethanol and water for more than 12 h was suggested to be good extraction condition for these constituents. Quantitation of nine constituents in different F. rhynchophylla samples was also successfully accomplished with the newly established method.