• 제목/요약/키워드: M&C

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공기 중에서 금속 헥사카르보닐 착물 $M(CO)_6$ (M=Cr, Mo, W)를 이용한 폴러렌 산화물 $[C_{70}O_n](n=1{\sim}2)$의 초음파화학 합성 (Sonochemical Synthesis of Fullerene Oxides $[C_{70}O_n](n=1{\sim}2)$ Using Metal Hexacarbonyl Complexes $M(CO)_6$ (M=Cr, Mo, W) Under Air Atmosphere)

  • 고원배;박영환
    • Elastomers and Composites
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    • 제40권3호
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    • pp.174-180
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    • 2005
  • 공기 중 초음파 조건에서 풀러렌$[C_{70}]$과 금속 헥사카르보닐 착물 $M(CO)_6$ (M=Cr, Mo, W)을 반응시켜 풀러렌 산화물 $[C_{70}O_n](n=1{\sim}2)$을 합성하였다. 동일한 초음파 조건에서 풀러렌$[C_{70}]$과 여러 가지 금속 헥사카르보닐 착물 $M(CO)_6$ (M=Cr, Mo, W)의 반응성은 $Mo(CO)_6$ > $W(CO)_6$ > $Cr(CO)_6$ 순으로 증가함을 나타냈다. MALDI-TOF-MS, UV-visible 스펙트럼과 HPLC를 사용하여 분석한 결과 초음파화학 반응의 생성물은 $[C_{70}O_n](n=1{\sim}2)$ 임을 알 수 있었다.

Molecular Characterization of Three cDNA Clones Encoding Calmodulin Isoforms of Rice

  • Lee, Sung-Ho;Kim, Cha Young;Lim, Chae Oh;Lee, Soo In;Gal, Sang Wan;Choi, Young Ju
    • Journal of Applied Biological Chemistry
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    • 제43권1호
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    • pp.5-11
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    • 2000
  • Three cDNA clones encoding rice calmodulin (CaM) isoforms (OsCaM-1, OsCaM-2, and OsCaM-3) were isolated from a rice cDNA library constructed from suspension-cultured rice cells treated with fungal elicitor. The coding regions of OsCaM-1 and O.sCaM-2 were 89% homologous at DNA Ievel, whereas the 5' and 3' untranslated regions were highly divergent. The polypeptides encoded by OsCaM-1 and OsCaM-2 was identical except two conservative substitution at position 8 and 75. The coding region of OsCaM-3 was consist of a typical conserved CaM domain and an additional C-terminal extension. The amino acid sequence of conserved CaM domain of OsCaM-3 shared only 86% identity with that OsCaM-1. The OsCaM-3 cDNA is belongs to a novel group of calmodulin gene due to its C-terminal extension of 38 amino acids, a large number of which are positively charged. The extension also contains a C-terminal CaaX-box prenylation site (CVlL). Genomic Southern analysis revealed at least six copies of CaM or CaM-related genes, suggesting that calmodulin may be represented by a small multigene family in the rice geneme. Expression of OsCaM gene was examined through Northern blot analysis. Transcript level of OsCaM-3 was increased by treatment with a fungal elicitor, whereas the OsCaM-1 and OsCaM-2 genes did not respond to the fungal elicitor. The expression of OsCaM-3 gene was remarkable inhibited in the rice cells treated with cyclosporine A, calcinurin inhibitor.

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REDUCED CROSSED PRODUCTS BY SEMIGROUPS OF AUTOMORPHISMS

  • Jang, Sun-Young
    • 대한수학회지
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    • 제36권1호
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    • pp.97-107
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    • 1999
  • Given a C-dynamical system (A, G, $\alpha$) with a locally compact group G, two kinds of C-algebras are made from it, called the full C-crossed product and the reduced C-crossed product. In this paper, we extend the theory of the classical C-crossed product to the C-dynamical system (A, G, $\alpha$) with a left-cancellative semigroup M with unit. We construct a new C-algebra A $\alpha$rM, the reduced crossed product of A by the semigroup M under the action $\alpha$ and investigate some properties of A $\alpha$rM.

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ON REGULAR-QUASICONFORMAL MAPPINGS

  • Shin, Yong-Soon
    • 한국수학교육학회지시리즈B:순수및응용수학
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    • 제2권2호
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    • pp.111-114
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    • 1995
  • A C$\^$$\infty$/ manifold is a pair (M, C) where a) M is a Hausdorff topological space such that every point $\chi$$\in$M has a neighborhood homeomorphic to an open subset of R$^n$. b) C is a collection of these homeomorphisms whose domains cover M. If ø, $\psi$ $\in$ C then ø o $\psi$$\^$-1/ is C$\^$$\infty$/. c) C is maximal with respect to (b).(omitted)

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Melt-Spun Fe-Pr-C 합금의 자기적 특성 조사 (An Investigation on the Magnetic Properties of Melt-Spun Fe-Pr-C Alloys)

  • 장태석;조대형
    • 한국자기학회지
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    • 제7권4호
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    • pp.173-179
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    • 1997
  • 급속응고(melt spinning)법이 Fe-Nd-C의 경우와 마찬가지로 보자력이 높은 Fe-Pr-C 합금을 얻는데에 효과적인지 알아보기 위하여, 급속응고된 Fe-Pr-C 리본에 대하여 냉각속도 및 열처리의 변화에 따른 상, 미세조직 및 자기특성의 변화를 조사하였다. 냉각속도(wheel speed)가 증가할수록 as-spun 리본의 비정질화가 증가하여 40m/s에서 제조된 리본합금은 거의 비정질화하였다. 10m/s에서 제조된 결정질 리본의 상분포는 주소상태의 상분포와 유사하여 .alpha. -Fe가 일차상, Fe$_{17}$Pr$_{2}$C$_{x}$가 이차상으로 존재하였다. 20m/s에서도 결정질이 우세하게 나타나나, 이때에는 .alpha. -Fe의 정출이 약간 억제되는 반면 Fe$_{17}$Pr$_{2}$C$_{x}$의 정출이 현저하였으며, 30m/s에서는 비정질이 우세하여 소량의 결정질만이 존재하였다. 따라서 강자성 Fe$_{14}$Pr$_{2}$C 상은 as-spun 상태에서는 존재하지 않거나 미량이었으며, 주조합금의 경우와 마찬가지로 고상변태를 통해서 얻을 수 있었다. 일반적으로 as-spun리본이 비정질화할수록 비교적 낮은 온도에서 수분의 열처리만으로 완전한 Fe$_{14}$Pr$_{2}$C 상을 얻을 수 있었으며, 결정화가 완벽할수록 Fe$_{14}$Pr$_{2}$C를 얻기 위한 열처리 시간은 증가하였다. 이와 같이 얻은 Fe$_{14}$Pr$_{2}$C는 대부분 1 .mu. m 이하의 미세한 결정립을 가지고 있었으며, as-spun 리본의 비정질화가 완벽한 경우보다 덜 완벽한 경우(30m/s) 또는 결정질과 약간의 비정질이 혼합된 경우 (20m/s)에 열처리에 의한 보자력의 향상이 뚜렷하였다. 일반적으로 변태온도 구역안에서 열처리 온도가 높을수록 10분 이하의 짧은 열처리가 보자력의 향상에 효과적이었다.이었다.

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돼지 수정란의 완만 및 초급속 동결 융해후의 생존성에 관한 연구 (Studies on the survival Rate after Slow and Ultrarapid Frozen-Thawing of Porcine Embryos)

  • 이봉구;김상근;이규승
    • 한국가축번식학회지
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    • 제16권2호
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    • pp.117-123
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    • 1992
  • This Study was carried out ot investigate the effects of concentration and equilibration time of cryoprotective aagents on survival rate of slowly and ultrarapidly frozen porcine embryos. The porcine embryos following dehydration by cryoprotective agents and 0.25M sucrose were slowly freezed(from 2$0^{\circ}C$ to -7$^{\circ}C$/-1$^{\circ}C$/min., from -7$^{\circ}C$ to -35$^{\circ}C$/-0.2$^{\circ}C$/min., from -35$^{\circ}C$ to -38$^{\circ}C$/-0.3$^{\circ}C$/min.) by Cell Freezer and directly plunged into liquid nitrogen and thawed in 38$^{\circ}C$ water bath. Survival rate was defined as development rate to the morula and blastocyst stage after in vitro culture or by FDA test. The results are summarized as follows : 1. The survival rates of porcine embryos after slow frozen-thawing in the freezing medium of 0.25M sucrose added 2.0M glycerol, 3.0M DMSO, 2.0M propanediol or 2.0M glycerol+2.0M propanediol was 80.6, 84.7, 75.0 or 78.8%, respectively. 2. The survival rates of porcine embryos after slow frozen-thawing in the freezing medium of 0.50M sucrose added 2.0M glycerol, 3.0M DMSO, 2.0M propanediol or 2.0M glycerol+2.0M propanediol was 80.9, 82.4, 73.1 or 77.1%, respectively. 3. The survival rates of porcine embryos after ultrarapid frozen-thawing in the freezing medium of 0.25M sucroese added 2.0M glycerol, 3.0M DMSO, 2.0M propanediol or 2.0M glycerol+2.0M propanediol was 65.3, 68.6, 63.2 or 59.9%, respectively. 4. The survival rates of porcine embryos after ultrapid frozen-thawing in the freezing medium of 0.50M sucrose added 2.0M glycerol, 3.0M DMSO, 2.0 propanediol or 2.0M glycerol+2.0M propanediol was 67.5, 62.9, 56.9, or 62.8%, respectively. 5. The higher survival rate of porcine embryos was attained at the short period ofequilibration time(5min.) in the freezing medium added 0.25M sucrose and 3.0 DMSO compared to those of 10 or 20min. equilibration time in the same condition.

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Submanifolds of Codimension 3 in a Complex Space Form with Commuting Structure Jacobi Operator

  • Ki, U-Hang;Song, Hyunjung
    • Kyungpook Mathematical Journal
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    • 제62권1호
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    • pp.133-166
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    • 2022
  • Let M be a semi-invariant submanifold with almost contact metric structure (𝜙, 𝜉, 𝜂, g) of codimension 3 in a complex space form Mn+1(c) for c ≠ 0. We denote by S and R𝜉 be the Ricci tensor of M and the structure Jacobi operator in the direction of the structure vector 𝜉, respectively. Suppose that the third fundamental form t satisfies dt(X, Y) = 2𝜃g(𝜙X, Y) for a certain scalar 𝜃 ≠ 2c and any vector fields X and Y on M. In this paper, we prove that if it satisfies R𝜉𝜙 = 𝜙R𝜉 and at the same time S𝜉 = g(S𝜉, 𝜉)𝜉, then M is a real hypersurface in Mn(c) (⊂ Mn+1(c)) provided that $\bar{r}-2(n-1)c{\leq}0$, where $\bar{r}$ denotes the scalar curvature of M.

NONEXISTENCE OF A CREPANT RESOLUTION OF SOME MODULI SPACES OF SHEAVES ON A K3 SURFACE

  • Choy, Jae-Yoo;Kiem, Young-Hoon
    • 대한수학회지
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    • 제44권1호
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    • pp.35-54
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    • 2007
  • Let $M_c$ = M(2, 0, c) be the moduli space of O(l)-semistable rank 2 torsion-free sheaves with Chern classes $c_1=0\;and\;c_2=c$ on a K3 surface X, where O(1) is a generic ample line bundle on X. When $c=2n\geq4$ is even, $M_c$ is a singular projective variety equipped with a holomorphic symplectic structure on the smooth locus. In particular, $M_c$ has trivial canonical divisor. In [22], O'Grady asks if there is any symplectic desingularization of $M_{2n}$ for $n\geq3$. In this paper, we show that there is no crepant resolution of $M_{2n}$ for $n\geq3$. This obviously implies that there is no symplectic desingularization.

터빈 로터강의 피로크랙전파속도의 확률특성 연구( I ) (A Study on the Statistical Characterisics of Fatigue Crack Propagation Rate in Turbine Rotor Steel(I))

  • 오세욱;이치우;정순호
    • 한국해양공학회지
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    • 제1권2호
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    • pp.83-92
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    • 1987
  • Inorder ot estimate the running life of turbine rotors, fatigue crack propagation low, da/dN = C(${\DELTA}K)^m$, proposed by paris et al. has been widely applied. In this study, fatigue crack propagation rates for 16 samples of 1% Cr-Mo-V rotor steel were measured and statistical characteristics of m and C values in above equation were reviewed. The results are summarized as follows. 1. C and m follow a log-normal distribution and normal distribution, respectively. And the relation of C and shows a strong negative correlation. 2. Fatigue crack propagation equation can be expressed as da/dN=$4.11{\times}10^{-4}({\Delta}K/153.8)^m$, introducing the ralationship C=$C_oK_o^{-m}$. In this case, contribution of $C_o$ distribution to the distribution of log C shows very small compared to degrees of contribution by m.

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고려인삼 사포닌류의 생합성에 관한 연구 (Biosynthesis of Saponins in Panax ginseng)

  • 홍석주;이용우;주충노
    • Journal of Ginseng Research
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    • 제11권2호
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    • pp.136-144
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    • 1987
  • 고려인삼(Panax ginseng C.A. Meyer) 뿌리의 주요 성분중의 하나인 saponin류(ginsenosides)의 생합성 경로를 규명하기 위하여 인삼 뿌리 절편(2g)을 20mM sodium acetate ($500\mu$Ci [U-$^{l4}C$]-acetate), 10 mM mevalonate ($25\mu$Ci [2-$^{l4}C$]-mevalonate), 10 mM squalene ($10\mu$Ci [4,8,12,13,17,21-$^3H$]-squalene)을 각각 포함한 반응액에 가하고 $30^{\circ}C$에서 72시간 가온처리하여 얻은 생성물을 분석한 결과 다음과 같은 결과를 얻었다. 1. [U-$^{l4}C$]-acetate, [2-$^{l4}C$]-mevalonate, [4,8,12,13,17,21-$^3H$]-squalene으로부터 각각 방사성 인삼 saponin이 합성됨을 autoradiography로 확인하였다. 2. [U-$^{l4}C$]-acetate로부터의 생성물을 T.L.C.로 분리 분석한 결과 panaxadiol, panaxatriol, squalene, mevalonate에서 회수된 방사능이 각각 가해준 총 방사능의 2.1%, 2.7%, 2.6%, 0.2% 였으며 당에서도 상당량의 방사능이 탐지되었다. 3. 2-$^{l4}C$]-mevalonate로부터의 생성물을 T.L.C.로 분리 분석한 결과 squalene에서 많은 방사능이 회수되었고 [4,8,12,13,17,21-$^3H$]-squalene으로부터의 생성물을 T.L.C.로 분리 분석한 결과 panaxadiol, panaxatriol, sterol에서 많은 방사능이 회수되었다. 이상과 같은 실험결과로부터, 인삼뿌리에서의 saponin류 합성이 acetate로부터 mevalonate, squalene등의 중간 물질을 거치는 경로가 있음을 확인할 수 있었다.

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