• Journal of Energy Engineering
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• v.23 no.4
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• pp.169-175
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• 2014

For the safe handling of ethylbenzene, this study was investigated the explosion limits of ethylbenzene in the reference data. And the lower flash points, upper flash points and AITs(auto-ignition temperatures) by ignition delay time were experimented. The lower flash points of ethylbenzene by using Setaflash closed-cup and Pensky-Martens closed-cup testers were experimented $20^{\circ}C$ and $22^{\circ}C$, respectively. The lower flash points ethylbenzene by using Tag and Cleveland open cup testers were experimented $25^{\circ}C$ and $28^{\circ}C$, respectively. Also, this study measured relationship between the AITs and the ignition delay times by using ASTM E659 tester for ethylbnezene. The experimental AIT of ethylbenzene was $430^{\circ}C$. The calculated LEL and UEL by using the measured lower flash point and upper flash point were 0.93 Vol.% and 7.96 Vol.%, respectively.

• Fire Science and Engineering
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• v.15 no.3
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• pp.14-20
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• 2001

The flash points are one of the most important fundamental properties used to determine the potential for fire and explosion hazards of flammable substances. A classification of the flash points is important for the safe handling of flammable liquids which constitute the solvent mixtures. Basic to all flash points behavior are vapor pressure and explosive limits(lower explosive limit and upper explosive limit). The flash points of flammable solvent mixtures can be calculated with the appropriate use of the fundamental laws of Raoult, Dalton, Le Chatelier and activity coefficient models. In this study, the reference values of lower flash points were compared with the calculated values by using Raoult's law and MRSM(modified response surface methodology) model. The lower flash points were in agreement with the predicted by Raoult's law and MRSM model. By means of this methodology, it is possible to evaluate reliability of experimental data of the flash points of the flammable mixtures.

• Journal of the Korean Institute of Gas
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• v.18 no.4
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• pp.44-50
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• 2014

For the safe handling of aniline, this study was investigated the explosion limits of aniline in the reference data. And the lower flash points, upper flash points and AITs(auto-ignition temperatures) by ignition delay time were experimented. The lower flash point of aniline by using Setaflash and Penski-Martens closed-cup testers were experimented $66^{\circ}C$ and $73^{\circ}C$, respectively. The lower flash point aniline by using Tag and Cleveland open cup testers were experimented $72^{\circ}C$ and $78^{\circ}C$, respectively. Also, this study measured relationship between the AITs and the ignition delay times by using ASTM E659 tester for aniline. The experimental AIT of aniline was $590^{\circ}C$. The calculated LEL and UEL by using the measured low flash point and upper flash point were 1.16 Vol.% and 8.36 Vol.%, respectively.

• Proceedings of the Korea Institute of Fire Science and Engineering Conference
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• 2008.04a
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• pp.131-134
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• 2008

In this study, the lower detonation limits(LDL) and the upper detonation limits(UDL) of the flammable substances predicted with the appropriate use of the heat of combustion and the stoichiometric coefficient. The values calculated by the proposed equations were a good agreement with literature data within a few percent. From a given results, It is to be hoped that this methodology will contribute to the estimation of the detonation limits of for other flammable substances.

• Journal of the Korean Institute of Gas
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• v.26 no.6
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• pp.65-75
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• 2022

Recently, the possibility of fire and explosion due to hydrogen leakage and the resulting risk are increasing since the operating pressure of the electrolysis increases. This study performed the hazardous area classification in accordance with KS C IEC 60079-10-1 and KGS GC101 in consideration of the general operating conditions of the electrolysis. In addition, in order to achieve a To Non-hazardous, an appropriate ventilation rate was estimated to maintain a concentration of less than 25 % of the lower explosive limit. As a result, it was reviewed that the electrolysis is classified as an hazardous area when only natural ventilation is applied, and a huge amount of ventilation is required to classify it as a non-hazardous area.

• Journal of the Korean Institute of Gas
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• v.16 no.5
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• pp.41-46
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• 2012

The flash point the lowest temperature at which the concentration of vapor of the substance in the air reaches the lower flammability limit(LFL), and is one of the most important physical properties used to determine the potential for fire and explosion hazards of industrial materials. The most published flash point data was for pure components and the flash points of the binary solutions that have flammable components, appear to be scarce in the literature. In the present study, the flash points of tert-pentanol+n-decane system were measured by Tag open-cup tester. The measured data were compared with the values calculated by the Raoult's law and the optimization methods based on the Wilson and NRTL equations. The calculated values by optimization methods were found to be better than those based on the Raoult's law.

• Journal of the Korea Safety Management & Science
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• v.7 no.4
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• pp.85-99
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• 2005

The main objective of this paper is to search whether containment vessel's best pressure may increase until how long when loss of coolant accident (LOCA) happened in containment vessel of Ulchin nuclear power plant 1 and 2. Another goal of this research is to find the influential factors that increase containment vessel pressure. Model for this research is Ulchin nuclear power plant 1 with 10 cycles. Data were collected by simulator of Ulchin nuclear power plant 1 and design of experiment was used for data analysis. For the experiment, seven factors that are going to influence in containment vessel pressure were chosen. It was found that fatter which influences in early rise of containment vessel pressure after LOCA is only explosion size. Also, containment vessel's best pressure (3.74 bar.a) was much lower than limit (4.86 bar.a) of FSAR (Final Safety Analysis Report).

• Journal of the Korea Academia-Industrial cooperation Society
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• v.22 no.6
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• pp.573-582
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• 2021

In this study, a series of processes for evaluating the effective protection against barriers that should be equipped in institutions that perform reliability tests on high-risk ammunition, such as high-explosive ammunition, were introduced. The impact that high-explosive bombs can have on personnel includes damage to the eardrum and lungs caused by explosion overpressure and penetrating wounds that can be received by fragments generated simultaneously with the explosion. Therefore, a high-explosive with COMP B explosives as its contents were set up, and an explosion protection theory investigation to calculate the degree of damage, numerical calculations and simulations were performed to verify the protection power. A numerical calculation revealed the maximum explosion overpressure on the protective wall when the high-explosive exploded and the penetration force of the fragment against a 50 mm-thick protective wall to be 77.74 kPa and 41.34 mm, respectively. In the simulation verification using AUTODYN, the maximum explosion overpressures affecting the firewall and personnel were 56.68 kPa and 18.175 kPa, respectively, and the penetration of fragments was 35.56 mm. This figure is lower than the human damage limit, and it was judged that the protective power of the barrier would be effective.

• Journal of the Korean Society of Safety
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• v.20 no.3 s.71
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• pp.91-97
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• 2005

The research on the explosive limits is one of fundamental fields of combustion process, and information on the explosive limits of mixture of fuel and oxidant, with or without additives, is very important for the prevention in industrial fire and explosion accidents. Explosive limits of all compounds and solvent mixtures can be calculated with the appropriate use of the fundamental laws of Raoult, Batten, Le Chatelier and MRSM(modified response surface methodology) model. In this study, the reference values of lower explosive limits(LEL) of the ethanol+toluene+ethylacetate system were compared with the calculated values by using the solution thermodynamics and the MRSM model, respectively. The values calculated by the proposed equations were a good agreement with literature data within a few percent. By means of this methodology, it is possible to evaluate reliability of experimental data of the lower explosive limits of the flammable mixtures. Also, from given results, it is possible to predict explosive limits of the other flammable liquid mixtures used in the chemical process by the use of the proposed equations.

• Journal of the Korean Institute of Gas
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• v.22 no.4
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• pp.13-26
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• 2018

Currently, local regulations, such as KS Code, do not clearly specify how to calculate the range of hazardous area, so the dispersion modeling program should be used to select dispersion. The purpose of this study is to present a methodology of determining the range of hazardous area which is simpler and more reasonable than modelling by using representative materials and process conditions. Based on domestic and overseas regulations that are currently in effect, variables affecting distance to LFL(Lower Flammable Limit) were selected. A total of 16 flammable substances were modelled for substance variables, process conditions variables, and weather conditions variables, and the statistical analysis selected the variables that affect them. Using the selected variables, a three-step classification method was prepared to select the range of locations subject to explosion hazard.