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http://dx.doi.org/10.7842/kigas.2014.18.4.44

The Study on Measurement and Prediction of Combustible Properties for Aniline  

Ha, Dong-Myeong (Dept. of Occupational Health and Safety Engineering., Semyung University)
Publication Information
Journal of the Korean Institute of Gas / v.18, no.4, 2014 , pp. 44-50 More about this Journal
Abstract
For the safe handling of aniline, this study was investigated the explosion limits of aniline in the reference data. And the lower flash points, upper flash points and AITs(auto-ignition temperatures) by ignition delay time were experimented. The lower flash point of aniline by using Setaflash and Penski-Martens closed-cup testers were experimented $66^{\circ}C$ and $73^{\circ}C$, respectively. The lower flash point aniline by using Tag and Cleveland open cup testers were experimented $72^{\circ}C$ and $78^{\circ}C$, respectively. Also, this study measured relationship between the AITs and the ignition delay times by using ASTM E659 tester for aniline. The experimental AIT of aniline was $590^{\circ}C$. The calculated LEL and UEL by using the measured low flash point and upper flash point were 1.16 Vol.% and 8.36 Vol.%, respectively.
Keywords
Safe handling; Aniline; Flash point; Explosion limit; ASTM E659; Autoignition temperature(AIT);
Citations & Related Records
Times Cited By KSCI : 2  (Citation Analysis)
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1 Hilado, C.J. and S.W. Clark, "Autoignition Temperature of Organic Chemicals", Chemical Engineering, 4, 75-80, (1972)
2 Scott, G.S., G.W. Jones and F.E. Scott, "Determination of Ignition Temperature of Combustible Liquids and Gases", Analytical Chemistry, 20(3), 238-241, (1948).   DOI
3 Lees, F.P., Loss Prevention in the Process Industries, Vol. 2, 2nd ed., Butterworth-Heinemann, (1996)
4 Bjerketvedt, D., J.R. Bakke and K. van Wingerden, "Gas Explosion Handbook", J. of Hazardous Materials, 52, 1-150, (1997)   DOI   ScienceOn
5 Stephson, R.M. Flash Points of Organic and Orgarnometallic Compounds, Elsevier Science Publishing Co. Inc., (1987)
6 Zabetakis, M.G., A.L. Furno and G.W. Jones," Minimum Spontaneous Ignition Temperature of Combustibles in Air", Industrial and Engineering Chemistry, 46(10), 2173-2178, (1954)   DOI
7 Semenov, N. N., Some Problems in Chemical Kinetics and Reactivity, Vol. 2, Princeton University Press, Princeton, N.J., (1959)
8 Ha, D.M.,"The Evaluation of Hazard by Measurement of Combustible Characteristics of n-Tetradecane", J. of the Korean Society of Safety, 27(5), 70-76, (2012)   과학기술학회마을
9 Gmehing, J., Onken, U., and Arlt, W., Vapor-Liquid Equilibrium Data Collection, Deutsche Gesellschaft fur Chemisches Apparatewesen, (1980)
10 Ha, D.M., "The Measurement of Combustible Characteristics of n-Undecane", J. of the Korean Institute of Fire Sci. & Eng., 27(2), 11-17, (2013)   과학기술학회마을   DOI
11 Lide, D.R., Handbook Chemistry and Physics, 76th ed., CRC Press, (1996)
12 Montemayor, R.E., J.E. Rogerson, J.C. Colbert and S.B. Schiller, "Reference Verification Fluids for Flash point Determination", J. of Testing and Evaluation, 27(6), 423-427, (1999)   DOI   ScienceOn
13 Britton, L.G., "Two Hundred Years of Flammable Limits", Process Safety Progress, 21(1), 1-11, (2002)   DOI   ScienceOn
14 Hilado, C.J. and S.W. Clark, "Discrepancies and Correlations of Reported Autoignition Temperatures", Fire Technology, 8, 218-227, (1972)   DOI
15 NFPA, Fire Hazard Properties of Flammable Liquid, Gases, and Volatile Solids, NFPA 325M, National Fire Protection Association, (1991)
16 SFPE, SFPE Handbook of Fire Protection Engineering, 2nd ed., Society of Fire Protection Engineers, (1995)
17 Lenga, R.E and Votoupal, K.L., The Sigma Aldrich Library of Regulatory and Safety Data, Volume I-III, Sigma Chemical Company and Aldrich Chemical Company Inc., (1993)
18 Babrauskas, V., Ignition Handbook, Fire Science Publishers, Society of Fire Protection Engineers, (2003)
19 Dean, J.A., Lange's Handbook of Chemistry, 14th ed. McGraw-Hill, (1992)
20 Lewis, R.J., SAX's dangerous Properties of Industrial Materials, 11th ed., John Wiley & Son, Inc., New Jersey, (2004)
21 KOSHA, /www.kosha.or.kr/msds/msdsMain.do?menuId=69
22 Fluka Chemie AG., Catalog 1986-87, CH-9470, Bucks/Switzerland.