• Title/Summary/Keyword: Low-temperature-firing property

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The application of Nano-paste for high efficiency back contact Solar cell (고효율 후면 전극형 태양전지를 위한 나노 Paste의 적용에 대한 연구)

  • Nam, Donghun;Lee, Kyuil;Park, Yonghwan
    • 한국신재생에너지학회:학술대회논문집
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    • 2010.11a
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    • pp.53.2-53.2
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    • 2010
  • In this study, we focused on our specialized electrode process for Si back-contact crystalline solar cell. It is different from other well-known back-contact cell process for thermal aspect and specialized process. In general, aluminum makes ohmic contact to the Si wafer and acts as a back surface reflector. And, silver is used for low series resistance metal grid lines. Aluminum was sputtered onto back side of wafer. Next, silver is directly patterned on the wafer by screen printing. The sputtered aluminum was removed by wet etching process after rear silver electrode was formed. In this process, the silver paste must have good printability, electrical property and adhesion strength, before and after the aluminum etching process. Silver paste also needs low temperature firing characteristics to reduce the thermal budget. So it was seriously collected by the products of several company of regarding low temperature firing (below $250^{\circ}C$) and aluminum etching endurance. First of all, silver pastes for etching selectivity were selected to evaluate as low temperature firing condition, electrical properties and adhesive strength. Using the nano- and micron-sized silver paste, so called hybrid type, made low temperature firing. So we could minimize the thermal budget in metallization process. Also the adhesion property greatly depended on the composition of paste, especially added resin and inorganic additives. In this paper, we will show that the metallization process of back-contact solar cell was realized as optimized nano-paste characteristics.

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An Experimental Study on the Firing Performance and Property of Lime Mortar for Building in Joseon Dynasty (조선시대 조적용 석회의 소성 성능과 모르타르의 물성에 대한 실험 연구)

  • Lee, Sang-Ok;Chung, Kwang-Yong
    • Journal of architectural history
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    • v.25 no.3
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    • pp.37-45
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    • 2016
  • This study was to investigate the firing method of limestone in Joseon Dynasty, and analyze the physical chemical properties of lime mortars in Joseon Dynasty. This study was to manufacture and evaluate the firing experiment and mortar of Limestone by each sort in order to reproduce the traditional lime mortars in Joseon Dynasty, and investigate the behavior to improve physical properties according to the firing method of Limestone. This study has found out that there were screening criteria and standard of appropriate firing temperature about the Limestone in Joseon Dynasty. Accordingly, this study was to improve its strength through various additives and mixture. In particular, in case of Limestone, the black and blue Limestone were preferred, and most of domestic Limestones were low grade Limestone including the clay and took ivory white or blue with low whiteness. This study has shown that the low grade Limestone was mined by the surface mining compared with the high grade Limestone as underground mining method, and could be used because it was easy to mine relatively and there was possibility that Natural Hydraulic Lime(NHL) was used with the traditional lime mortars in Joseon Dynasty.

Humidity Properties of Sintered MnWO4 with a Low Temperature Firing Frit (저온소성 프릿이 첨가된 MnWO4의 소결체의 습도특성)

  • Jung, Byung-hae;So, Ji-young;Kim, Hyung-sun
    • Korean Journal of Materials Research
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    • v.13 no.2
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    • pp.120-125
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    • 2003
  • A low melting borosilicate glass frit was used as an adhesion promoter, which enables $MnWO_4$to be sintered with in a reasonable sintering temperature range ($800∼1000^{\circ}C$). The glass was evaluated for glass transition temperature ($Τ_{g}$ X) and thermal expansion coefficient($\alpha$). Mechanical property (Vickers hardness), grain growth, the comparison of lattice parameter and pore distribution of sintered $MnWO_4$ with the frit were methodically discussed. As sintering temperature increased, a typical liquid phase sintering showed the rapid grain growth and high densification of X$MnWO_4$grain, improvement of hardness (until $920^{\circ}C$) and different pore size distribution. Resistance of sintered $MnWO_4$varied from 450k$\Omega$ to 8.8M$\Omega$ under the measuring humidify ranging from 30 to 90%. Thus, the results will contribute to the application of glass frit containing sensor materials and their future use.

Properties of Cu-Contained Spinel Ferrites with Various Cu Contents (Cu계 스피넬 페라이트의 Cu 함량에 따른 특성 변화)

  • 남중희;오재희
    • Journal of the Korean Ceramic Society
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    • v.33 no.11
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    • pp.1245-1252
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    • 1996
  • The charcteristics for the copper-contained spinel ferrites such as NiCu-and ZnCu ferrites with various copper content are investigated in this study which can provide a explanation for the behavior of copper in sintering at a low temperatuer. The bulk density and the grain size for these sintered ferrites were increased with the larger amount of copper in compositions. In microstructure of copper-contained spinel ferrites copper exists in the grain boundary which is sintering process. Electrical resistivity and frequency range with maximum Q-facor of NiCu-or ZnCu ferrites were decreased as increasing of copper content in ferrite composition.

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Microwave Dielectric Properties of Low Temperature Fired (${Pb_{0.45}}{Ca_{0.55}}$) [(${Fe _{0.5}}{Nb_{0.5}}$)$_{0.9}{Sn_{0.1}}$]$O_3$Ceramics with Various Additives

  • Ha, Jong-Yoon;Park, Ji-Won;Yoon, Seok-Jin;Kim, Hyun-Jai;Yoon, Ki-Hyun
    • Journal of the Korean Ceramic Society
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    • v.38 no.7
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    • pp.597-601
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    • 2001
  • The effect of CuO, $B_2$ $O_3$, $V_2$ $O_{5}$ and CuO-B $i_2$ $O_3$additives on microwave dielectric properties of (P $b_{0.45}$C $a_{0.55}$) [(F $e_{0.5}$N $b_{0.5}$)$_{0.9}$S $n_{0.1}$] $O_3$(PCFNS) were investigated. The PCFNS ceramics were sintered at 11$65^{\circ}C$. To decrease the sintering temperature for using as a low-temperature co-firing ceramics (LTCC), CuO, $B_2$ $O_3$, $V_2$ $O_{5}$ and CuO-B $i_2$ $O_3$were added to the PCFNS. As the content of CuO increased, the sintered density and dielectric constant increased and the temperature coefficient of resonance frequency ($\tau$$_{f}$) shifted to the positive value. When the CuO-B $i_2$ $O_3$were added, dielectric properties were $\varepsilon$$_{r}$ of 83, Q. $f_{0}$ of 6085 GHz, and $\tau$$_{f}$ of 8ppm/$^{\circ}C$ at a sintering temperature of 100$0^{\circ}C$. The relationship between the microstructure and properties of ceramics was studied by X-ray diffraction and scanning electron microscopy.icroscopy.y.icroscopy.y.

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Thermal Property of Phosphate Glasses for Low Firing Temperature in PDP

  • Park, Jun-Hyun;Jung, Byung-Hae;Kim, Hyung-Sun
    • 한국정보디스플레이학회:학술대회논문집
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    • 2002.08a
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    • pp.795-798
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    • 2002
  • Replacing Pb-free glass composition for the dielectric materials is expected in PDP industry. In this study, phosphate glasses, $P_2O_5$- ZnO- SnO (PZS), $P_2O_5$-ZnO-BaO (PZB) were selected for a new transparent dielectric. Thermal properties (Tg, CTE) were measured with differential thermal analyzer and thermal mechanical analyzer. The glass transition of the glasses was ranged at $365{\sim}405^{\circ}C$ for the PZS system and $5.9{\sim}9.5{\times}\;10^{-6}$ of thermal expansion were found. The PZB system showed $445{\sim}470^{\circ}C$ of glass transition. Thus, the glass compositions would be a potential candidate for a transparent dielectric layer in plasma display panel.

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Low Temperature Co-firing of Camber-free Ceramic-metal Based LED Array Package (세라믹-금속 기반 LED 어레이 패키지의 저온동시소성시 휨발생 억제 연구)

  • Heo, Yu Jin;Kim, Hyo Tae
    • Journal of the Microelectronics and Packaging Society
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    • v.23 no.4
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    • pp.35-41
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    • 2016
  • Ceramic-metal based high power LED array package was developed via thick film LTCC technology using a glass-ceramic insulation layer and a silver conductor patterns directly printed on the aluminum heat sink substrate. The thermal resistance measurement using thermal transient tester revealed that ceramic-metal base LED package exhibited a superior heat dissipation property to compare with the previously known packaging method such as FR-4 based MCPCB. A prototype LED package sub-module with 50 watts power rating was fabricated using a ceramic-metal base chip-on-a board technology with minimized camber deformation during heat treatment by using partially covered glass-ceramic insulation layer design onto the aluminum heat spread substrate. This modified circuit design resulted in a camber-free packaging substrate and an enhanced heat transfer property compared with conventional MCPCB package. In addition, the partially covered design provided a material cost reduction compared with the fully covered one.

Application Study of Recoil Mechanism using Friction Springs (마찰스프링의 주퇴복좌장치 적용성 연구)

  • Cha, Ki-Up;Gimm, Hak-In;Cho, Chang-Ki
    • Journal of the Korean Society for Precision Engineering
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    • v.29 no.3
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    • pp.324-333
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    • 2012
  • The conventional medium and large caliber gun, in general, utilize the hydro-pneumatic recoil mechanism to control the firing impulse and to return to the battery position. However, this kind of mechanism may cause the problems like the leakages and the property changes in oil and gas due to the temperature variations between low and high temperatures. Accordingly, the friction spring mechanism has recently been researched as an alternative system. The friction spring mechanism consists of a set of closed inner and outer rings with the concentric tapered contact surfaces assembled in the columnar form, and can only be used under the compression load. When the spring column is axially loaded, the tapered surfaces become overlapped, causing the outer rings to expand while the inner rings are being contracted in diameter allowing an axial displacement. Because of friction between tapered contact surfaces, much higher spring stiffness is obtained on the stroke at the increase in load than the stroke at the decrease. In this paper, the dynamic equations regarding the friction spring system and the design approach have been investigated. It is also tried for a dynamic model representing the recoil motion and the friction spring forces. And the model has been proved from firing test using a gun system with friction springs. All the results show that the recoil mechanism using friction springs can substitute for the classic hydro-pneumatic recoil system.

The Property Change of ITO Prepared by Reactive R.F. Sputtering in POP manufacturing Process (반응성 스퍼트링으로 형성된 ITO의 유전채 소성에 따른 특성변화)

  • Nam, Sang-Ok;Chi, Sung-Won;Sohn, Je-Bong;Huh, Keun-Do;Cho, Jung-Soo;Park, Chung-Hoo
    • Proceedings of the KIEE Conference
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    • 1997.07d
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    • pp.1411-1413
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    • 1997
  • The thin film that is electrically conductive and optically transparent is called conductive transparent thin film. ITO(Indium-Tin Oxide) which is a kind of conductive transparent thin film has been widely used in solar cell, transparent electrical heater, selective optical filter, FDP(Flat Display Panel) such as LCD (Liquid Crystal Display), PDP(Plasma Display Panel) and so on. Especially in PDP, ITO films is used as a transparent electrode in order to maintain discharge and decrease consumption power through the improvement of cell structure. In this study, we prepared ITO by reactive r.f. sputtering with indium-tin(Sn wt 10%) alloy target instead of indium-tin oxide target. The ITO films deposited at low temperature $150^{\circ}C$ and 8% $O_2$ partial pressure showed about $3.6{\Omega}/{\square}$. At the end of firing, the resistance of ITO was decreased, the optical transparence was improved above 90%.

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Synthesis and dielectric properties of the $ZnAl_2O_4$ ceramics for low-firing (저온소결용 $ZnAl_2O_4$ 세라믹스의 합성 및 유전 특성)

  • Kim, Kwan-Soo;Yoon, Sang-Ok;Kim, Shin;Kim, Nam-Hyup;Kim, Yun-Han;Shim, Sang-Heung
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2007.06a
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    • pp.279-279
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    • 2007
  • Synthesis and dielectric properties of glass-ceramic composites with zinc borosilicate glass(here after ZBS glass) were investigated as functions of $ZnAl_2O_4$ phase synthesis method, glass addition (50~60 vol%) and sintering temperature ($600{\sim}950^{\circ}C$ for 2 hrs). The 50 vol% ZBS glass-$Al_2O_3$ and 60 vol% ZBS glass-$ZnAl_2O_4$ ensured successful sintering below $900^{\circ}C$. But the composition of 100-x-y vol% ZBS glass-x vol% $Al_2O_3-y$ vol% ZnO exhibited poor sinterability below $900^{\circ}C$ and the swelling phenomenon occurred in this composite with the large amount of ZBS glass. The sintering behavior of Glass-ceramic composites was affected by the crystallization of $ZnAl_2O_4$ which was formed by the reaction between ZBS glass and $Al_2O_3$. Dielectric constant (${\varepsilon}_r$), $Q{\times}f$ value and temperature coefficient of resonant frequency (${\tau}_f$) of the composite with 50 and 60 vol% ZBS glass contents demonstrated $ZBS-Al_2O_3({\varepsilon}_r=5.7)$, $ZBS-ZnAl_2O_4({\varepsilon}_r=5.8)$ which is applicable to substrate requiring an low dielectric properties.

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