• 제목/요약/키워드: Low-temperature combustion

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New technology for doped Fe alloys production

  • Ksandopoulo, G.;Korobova, N.;Baydeldinova, A.;Isaykina, O.;Soh, Deawha
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2000년도 하계학술대회 논문집
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    • pp.274-277
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    • 2000
  • SHS is recognized as an attractive process for producing high-temperature, hard materials that difficult and/or expensive to produce by conventional fabrication methods. The goal of this work is to investigate new express technology of doped Fe alloys materials. The high density, homogeneity of the components, and the low processing temperatures achieved and minimum synthesis time are all of paramount importance in fabricating Fe alloys as functional materials.

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0.5 MWth 급 케미컬루핑 연소시스템에서 대량생산 산소전달입자의 환원반응 특성에 미치는 온도, 압력, 유속 및 용량의 영향 (Effects of Temperature, Pressure, Gas Velocity, and Capacity on Reduction Characteristics of Mass Produced Particle in a 0.5 MWth Chemical Looping Combustion System)

  • 류호정;이도연;남형석;황병욱;김하나;원유섭;백점인
    • 한국수소및신에너지학회논문집
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    • 제32권1호
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    • pp.53-62
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    • 2021
  • Batch type reduction-oxidation tests were performed to check effects of temperature, pressure, gas velocity, and capacity on reduction characteristics of mass produced particle in a 0.5 MWth chemical looping combustion system. The fuel conversion and the CO2 selectivity increased as the temperature increased and as the gas velocity decreased. However the CO2 selectivity showed the maximum and decreased as the capacity increased because the CO emission increased. The results show that high temperature, low gas velocity and low inert gas concentration are preferable to ensure high reactivity of oxygen carrier in the fuel reactor.

미분탄 화력발전소 연료로서 고수분 인도네시아탄의 연소특성 (Combustion Characteristics of High Moisture Indonesia Coal as a Pulverized Fuel at Thermal Power Plant)

  • 김재관;이현동
    • 한국연소학회지
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    • 제14권3호
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    • pp.16-23
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    • 2009
  • It is strongly desired for coal-fired power plants to utilize not only low-rank coals with high moisture contents, but also lowering cost with diversifying fuel sources. In this study, combustion characteristics of low rank coal with high moisture, and standard pulverized coals are experimentally investigated using TGA (Thermogravimetric Analysis) and DTF (drop tube furnace). The coals tested are three kinds of coal with moisture content ranging from 8.32 to 26.82%. The results show that under the air combustion condition, the burn-out time at TGA rises as moisture content increases, and standard pulverized coal with 8.32% moisture content showed the lowest activation energy of 55.73 kJ/mol. In case of the high amount of moisture, the combustion efficiency decreases due to evaporation heat loss, and unburned carbon in ash produced at combustion process in DTF increased. Aslo, initial deformation temperature of slag attached in alumina tube of DTF decreased with lowering the crytallinity of anorthite and augite. To improve the combustion reactivity and efficiency, it is effective to upgrade through drying the high moisture coal to moisture level (less than 10%) of standard pulverized coal.

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발전용 희박예혼합 가스터빈에서 연소모드변환 시기의 연소특성 해석 (Numerical Analysis of Combustion Characteristics during Mode Transfer Period in a Lean Premixed Gas Turbine for Power Generation)

  • 정재화;서석빈;김종진;차동진;안달홍
    • 대한기계학회:학술대회논문집
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    • 대한기계학회 2002년도 학술대회지
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    • pp.279-282
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    • 2002
  • Recently, gas turbines for power generation adopt multistage DLN(Dry Low NOx) type combustion, where diffusion combustion is applied at low load and, with increase in load, the combustion mode is changed to lean premixed combustion to reduce NOx emissive concentration. However, during the mode changeover from diffusion to premixed flame, unfavorable phenomena, such as flashback, high amplitude combustion oscillations, or thermal damage of combustor parts could frequently occur. In the present study, to apply for the analysis of such unfavorable phenomena, three-dimensional CFD investigations are carried out to compare the detailed flow characteristics and temperature distribution inside the gas turbine combustor before and after combustion mode changeover. The fuel considered here is pure methane gas. A standard $k-{\varepsilon}$ turbulence model with wall function and a P-N type radiation heat transfer model, have been utilized. To analyze the complex geometric effects of combustor parts on combustion characteristics, fuel nozzles, a swirl vane f3r fuel-air mixing, and cooling air holes on the combustor liner wall, are included in this simulation.

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분사각 및 분공 직경이 예혼합 압축착화 엔진 연소에 미치는 영향 (The Effect of Injection Angle and Nozzle Diameter on HCCI Combustion)

  • 국상훈;공장식;박세익;배충식;김장헌
    • 한국자동차공학회논문집
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    • 제15권2호
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    • pp.1-7
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    • 2007
  • The effect of injector geometries including the injection angle and number of nozzle holes on homogeneous charge compression ignition (HCCI) engine combustion has been investigated in an automotive-size single-cylinder diesel engine. The HCCI engine has advantages of simultaneous reduction of PM and NOx emissions by achieving the spatially homogenous distribution of diesel fuel and air mixture, which results in no fuel-rich zones and low combustion temperature. To make homogeneous mixture in a direct-injection diesel engine, the fuel is injected at early timing. The early injection guarantees long ignition delay period resulting in long mixing period to form a homogeneous mixture. The wall-impingement of the diesel spray is a serious problem in this type of application. The impingement occurs due to the low in-cylinder density and temperature as the spray penetrates too deep into the combustion chamber. A hole-type injector (5 holes) with smaller angle ($100^{\circ}$) than the conventional one ($150^{\circ}$) was applied to resolve this problem. The multi-hole injector (14 holes) was also tested to maximize the atomization of diesel fuel. The macroscopic spray structure was visualized in a spray chamber, and the spray penetration was analyzed. Moreover, the effect of injector geometries on the power output and exhaust gases was tested in a single-cylinder diesel engine. Results showed that the small injection angle minimizes the wall-impingement of diesel fuel that results in high power output and low PM emission. The multi-hole injector could not decrease the spray penetration at low in-cylinder pressure and temperature, but still showed the advantages in atomization and premixing.

예혼합 압축착화 디젤엔진의 부하변동에 따른 연소특성 분석 (Analysis of Combustion Characteristics for a Homogeneous Charge Compression Ignition Engine with Load Condition)

  • 장시웅;이기형;이창식
    • 한국자동차공학회논문집
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    • 제10권1호
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    • pp.17-23
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    • 2002
  • In order to reduce exhaust emissions from diesel engine under wide operating range, an experimental study based on a new concept of combustion called HCDC(Homogeneous Charge Diesel Combustion) was conducted. In this concept, most of the fuel is supplied as premixed homogeneous charge and the rest is directly injected into a cylinder to ignite. In this study we compared combustion characteristics of an HCDC engine with those of conventional diesel engines. At high premixed fuel ratio and high load range, it was observed that premixed combustion heat release rate was low and diffusion combustion duration was shorten. from this experiment, it was found that NOx is reduced by the lower maximum temperature and soot is reduced by rapid combustion during diffusion combustion phase.

20kW급 마이크로터빈용 저공해 연소기의 고압고온 성능실험 연구 (An Experimental Study on Low Nox Combustor Performance at High Pressure and Temperature for 20kW Class Microturbines)

  • 윤정중;오종식;이헌석
    • 유체기계공업학회:학술대회논문집
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    • 유체기계공업학회 2002년도 유체기계 연구개발 발표회 논문집
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    • pp.183-190
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    • 2002
  • In order to reduce NOx emissions in the 20kw class microturbines under development, the low NOx characteristics, as being an application to the lean premixed combustion technology, have been investigated. The study has been conducted at the conditions of high temperature and pressure. Air from a compressor with the temperature of 500K to 650K and the pressure of 0.3bar gauge to 0.7bar gauge, was supplied to the combustor through an air preheat-treatment. Sampling exhaust gases were measured at the immediate exit of the combustor. for the effect of temperature on NO and CO emissions. though NOx was increased, CO was decreased with increasing inlet air temperature. With increasing inlet air pressure, NOx and CO were increased also. NOx was decreased, but CO was increased with increasing inlet air mass flow rate. The test has been performed on the equivalent ratios of 0.10 to 0.25 in a lean region. NOx was increased with increasing equivalent ratios, but CO was decreased as an influence of flame temperature. In the very lean region of the equivalent ratio below 0.12, CO was increased suddenly, due to instability. As the results of this study, NOx and CO are found to be reduced to the similar level at the same time when operated at optimal conditions.

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가스 및 분무화염의 연소소음 특성에 관한 실험연구 (Combustion Noise Characteristics in Gas and Liquid Flames)

  • 김호석;백민수;오상헌
    • Journal of Advanced Marine Engineering and Technology
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    • 제18권1호
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    • pp.81-91
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    • 1994
  • Combustion noise involved with chemical heat release and turbulent process in turbopropulsion systems, gasturbine, industrial furnaces and internal engines is indeed noisy. The experimental study reported in this paper is made to identify a dominant combustion noise in jet flames. Gaseous propane and kerosene fuel have been used with air as the oxidizer in a different jet combustion systems. Combustion and aerodynamic noise are studied through far field sound pressure measurements in an anechoic chamber. And also mean temperature and velocities and turbulent intensities of both isothermal and reacting flow fields were measured. It is shown that axial mean velocity of reacting flow fields is higher about 1 to 3m/sec than that of cold flow in a gaseous combustor. As the gaseous fuel flow rate increases, the acoustic power increases. But the sound pressure level for the spray flame decreases with increasing equivalence ratio. The influence of temperature in the combustion fields due to chemical heat release has been observed to be a dominant noise source in the spray flame. The spectra of combustion noise in gaseous propane and kerosene jet flame show a predominantly low frequency and a broadband nature as compared with the noise characteristics in an isothermal air jet.

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Size Tailored Nanoparticles of ZrN Prepared by Single-Step Exothermic Chemical Route

  • Lee, Sang-Ki;Park, Kyung-Tae;Ryu, Hong-Youl;Nersisyan, Hayk H.;Lee, Kap-Ho;Lee, Jong-Hyeon
    • 한국재료학회지
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    • 제22권5호
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    • pp.243-248
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    • 2012
  • ZrN nanoparticles were prepared by an exothermic reduction of $ZrCl_4$ with $NaN_3$ in the presence of NaCl flux in a nitrogen atmosphere. Using a solid-state combustion approach, we have demonstrated that the zirconium nitride nanoparticles synthesis process can be completed in only several minutes compared with a few hours for previous synthesis approaches. The chemistry of the combustion process is not complex and is based on a metathesis reaction between $ZrCl_4$ and $NaN_3$. Because of the low melting and boiling points of the raw materials it was possible to synthesize the ZrN phase at low combustion temperatures. It was shown that the combustion temperature and the size of the particles can be readily controlled by tuning the concentration of the NaCl flux. The results show that an increase in the NaCl concentration (from 2 to 13 M) results in a temperature decrease from 1280 to $750^{\circ}C$. ZrN nanoparticles have a high surface area (50-70 $m^2/g$), narrow pore size distribution, and nano-particle size between 10 and 30 nm. The activation energy, which can be extracted from the experimental combustion temperature data, is: E = 20 kcal/mol. The method reported here is self-sustaining, rapid, and can be scaled up for a large scale production of a transition metal nitride nanoparticle system (TiN, TaN, HfN, etc.) with suitable halide salts and alkali metal azide.

반 실험적 방법을 통한 고체 램 제트 성능에 대한 흡입 공기 온도의 영향 (Inlet Air Temperature Effect on the Performance Efficiency of the Solid Fuel Ramjet through Semi-empirical Method)

  • 이태호
    • 한국추진공학회:학술대회논문집
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    • 한국추진공학회 2005년도 제25회 추계학술대회논문집
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    • pp.29-33
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    • 2005
  • 고체 램 제트 추진기관에서도 일반 로켓 추진기관에서와 같이 Isp 즉 추력을 증대 시키기 위하여 고체 입자들을 연료에 함유시킨다. 이러한 고체입자가 포함된 연료들은 매우 짧은 연소실 체류시간 때문에 연소 효율의 증대가 필수적이며 흡입공기 온도가 중요한 역할을 한다. 이 흡입공기 온도가 램 제트 성능에 미치는 영향을 조사하였다 성능조사는 실험적 방법에 한계가 있어 연소실험을 통한 연소효율을 이용하여 반-실험적으로 조사하였다. 연소실 흡입공기 온도에 영향을 미치는 인자는 자유 유동장 즉 대기 온도와 비행 마하 수이며 이들에 대한 효과를 조사하였다.

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