• Title/Summary/Keyword: Low-dye

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Fabrication and characteristics of the flexible DSSC

  • Choe, Eun-Chang;Choe, Won-Chang;Wi, Jin-Uk;Hong, Byeong-Yu
    • Proceedings of the Korean Vacuum Society Conference
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    • 2016.02a
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    • pp.400.2-400.2
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    • 2016
  • Dye-sensitized solar cells (DSSCs) have been widely investigated as a next generation solar cell because of their simple structure and low manufacturing cost. To realize a commercially competitive technology of DSSCs, it is imperative to employ a technique to prepare nanocrystlline thin film on the flexible organic substrate, aiming at increasing the flexibility and reducing the weight as well as the overall device thickness of DSSCs. The key operation of glass-to-plastic substrates conversion is to prepare mesoporous TiO2 thin film at low temperature with a high surface area for dye adsorption and a high degree of crystallinity for fast transport of electrons. However, the electron transport in the TiO2 film synthesized at low temperature is very poor. So, in this study, TiO2 films synthesized at high temperature were transferred on the selective substrate. We fabricated DSSCs at low temperature using this method. So, we confirmed that the performance of DSSCs using TiO2 films synthesized at high temperature was improved.

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Characteristics and Dyeing Properties of Green Tea Colorants (Part III) -Dyeing Properties of Cotton with Green Tea Colorants- (녹차색소의 특성과 염색성 (제 3보) -면섬유에 대한 녹차색소의 염색성-)

  • Shin, Youn-sook;Choi, Hee
    • Journal of the Korean Society of Clothing and Textiles
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    • v.23 no.4
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    • pp.510-516
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    • 1999
  • Dyeing properties of cotton fabrics with green tea colorants were studied by investigating the effects of dyeing conditions such as colorants concentration. pH dyeing temperature and time on dye uptakes effects of mordats on dye uptakes and color change and effects of cationizing agent on dye uptakes. And various colorfastnesses of dyed fabrics were evaluated for practical use. Green tea colorants showed low affinity to cotton and produced yellowish red color. Freundlich adsorption isotherm was obtained thus it is considered that hydrogen bondings are formed between colorants and cotton. Dye uptake was maximum at pH 5 and decreased as pH increased. Mordants especially Cu and Sn were effective for increasing dye uptake. Dye uptakes were improved remarkably by cationizing. Cationized cotton showed Langumuir adsorption isotherm indicating that ionic bondings were formed between colorants and cationized cotton. While mordanting did not affect lightfastness cationizing affected adversely. Colorfastness of cationized sample was generally inferior to that of mordanted samples.

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A Study on The Photoelectric Characteristics of Dye-sensitized Solar Cell according to Expanding Photo-electrode (염료감응형 태양전지의 광전극 확장에 따른 광전특성 연구)

  • Seo, Hyun-Woong;Kim, Mi-Jeong;Park, Je-Wook;Kim, Ho-Sung;Kim, Hee-Je
    • 한국신재생에너지학회:학술대회논문집
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    • 2007.06a
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    • pp.305-308
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    • 2007
  • The field of dye-sensitized solar cell (DSC) is being researched actively at present. Because DSC has several advantages to pass the limits of Si solar cells such as a low manufacturing expense, a simple manufacturing process and its transparency. A lot of researches are underway about materials and processes in the field of dye-sensitized solar cell but its structure has been fixed up as the sandwich structure that both edges are used as positive and negative terminals. But the structure as of present is a factor of decreasing efficiency because the more electrons are recombined the further distance from terminal, considering about the characteristic of dye-sensitized solar cell that electrons generated inside cell are moved by diffusion. In this study, we made experiment on expanding the terminal to shorten internal moving distance of electron and compared the results according to the variation of active area to find out the effect of this trial. As a result, we achieved about 15.5% improvement of maximum power and 0.5% improvement of efficiency from terminal-expanded dye-sensitized solar cell of $2cm^{2}$ active area and concluded that the increasing rate of efficiency is raised as the active area becomes wider.

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Cost-effective polyvinylchloride-based adsorbing membrane for cationic dye removal

  • Namvar-Mahboub, Mahdieh;Jafari, Zahra;Khojasteh, Yasaman
    • Membrane and Water Treatment
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    • v.11 no.2
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    • pp.131-139
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    • 2020
  • The current study focused on the preparation of low-cost PVC-based adsorbing membrane. Metakaolin, as available adsorbent, was embedded into the PVC matrix via solution blending method. The as-prepared PVC/metakaolin mixed matrix membranes were characterized using scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy (EDS), attenuated total reflectance-Fourier transform infrared (ATR-FTIR) spectroscopy, atomic force microscopy (AFM), pure water permeability and contact angle measurements. The results confirmed the improvement of PWP and hydrophilicity due to the presence of metakaolin in the PVC matrix. Additionally the structure of PVC membrane was changed due to the incorporation of metakaolin in the polymer matrix. The static adsorption capacity of all samples was determined through dye removal. The effect of metakaolin dosage (0-7%) and pH (4, 8, 12) on dye adsorption capacity was investigated. The results depicted that the highest adsorption capacity was achieved at pH of 4 for all samples. Additionally, adsorption data were fitted on Langmuir, Freundlich, and Temkin models to determine the appropriate governing isotherm model. Finally, the dynamic adsorption capacity of the optimum PVC/metakaolin membrane was studied using dead-end filtration cell. The dye removal efficiency was determined for pure PVC and PVC/metakaolin membrane. The results demonstrated that PVC/metakaolin mixed matrix membrane had a high adsorption capacity for dye removal from aqueous solution.

A Study on Dosimetric Characterization of Direct Yellow 12 Dye at High Radiation γ-Dose

  • Batool, Javaria;Shahid, Shaukat Ali;Ramiza, Ramiza;Akhtar, Nasim;Naz, Afshan;Yaseen, Maria;Ullah, Inam;Nadeem, Muhammad;Shakir, Imran
    • Bulletin of the Korean Chemical Society
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    • v.33 no.7
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    • pp.2265-2268
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    • 2012
  • Aqueous solution of oxygenated Direct yellow 12 dye has been evaluated spectrophotometrically as a possible gamma rays dosimeter. The neutral (pH-7), alkaline (pH-12.5) and acidic (pH-5.5) aqueous solution of the dye were prepared and exposed to various gamma doses. Absorption spectra of unirradiated and irradiated solutions were recorded at 400 nm peak. The increase in absorbance with the increase in irradiation dose was observed from 1 to 6 kGy. The stability response of the dye solution for different environmental conditions such as temperature (low & high), light and darkness were investigated during post irradiation storage for ten days. The dye solution showed high stability in darkness for the studied period. The optical density of the dye solution was found to be decreased at high temperature storage.

Study on the Natural Dye Program in Gyeongsang Region (경상도 지역 천연염색 프로그램에 관한 연구)

  • Lee, Je Nam;Lee, Eun Jin
    • Fashion & Textile Research Journal
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    • v.19 no.2
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    • pp.140-151
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    • 2017
  • This study researched the status and prospect of the natural dye program in the Gyeongsang region, with a focus on private centers with sufficient infrastructure and abundant human resources available for natural dyes. Metropolitan cities do not own the drying house and the agricultural land for natural dyes as well as have difficulty securing the land; therefore, entire sites are limited and smaller as they are closer to the city. The one-time program of all centers has been researched to help promote and maintain centers rather than generate profit. It is shown that June-August (summer) is preferred over December-February (winter). Natural dye programs for hobby and education are operated as needed because the number of participants are low. This program uses natural indigo and Persimmon Juice for the dyeing raw materials. Programs are often outsourced by other institutes with a private certification registration system the starting of a business after obtaining certification are often found in institutes operating programs directly. Future plans do not include investments in facilities (like the enlargement of experience centers) the prospect of programs and business value is bright for business strategies that include an exhibition shop for natural dye products and program development.

Natural Indigo Dyeing of Cotton Fabric - One-step reduction/dyeing process - (면직물에의 천연 인디고 염색 - 일단계 환원/염색 공정 -)

  • Shin, Youn-Sook;Cho, A-Rang;Yoo, Dong-Il
    • Textile Coloration and Finishing
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    • v.22 no.2
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    • pp.101-109
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    • 2010
  • The objective of this study is to investigate the characteristics of natural indigo dyeing of cotton fabric. Reduction and dyeing were carried out by one-step process using an infrared dyeing machine at the liquor ratio of 1:100, and subsequently oxidation and washing in water were followed. Dye uptake was increased with the increase of indigo concentration. Over the full range of dyeing tests, the dyeing condition was optimized to $40^{\circ}C$ for 40min. For most of dye concentrations, the cotton fabrics showed mainly PB color. Maximum K/S value was shown at 4g/L of sodium hydrosulfite concentration and the color strength increased with the increase of dye concentration. Value(lightness) decreased with the increase of dye uptake irrespective of mercerization or reduction method, while the mercerized cotton showed two times higher dye uptake than the untreated cotton. Whereas hue of the untreated cotton showed large decrease of P character(5.6~3.5 PB) with the increase of dye uptake, that of the mercerized cotton increased P character(4.7~5.5 PB). Irrespective of mercerization, value and chroma decreased with the increased of dye uptake. In addition, the untreated showed lower chroma than the mercerized cotton. In the case of traditional reduction, hue of the untreated cotton was changed very little with the increase of dye uptake. For hydrosulfite reduction, P character decreased with the increase of dye uptake. The difference of hue value was small with the change of reduction method(hydrosulfite reduction or traditional fermentation). Color character was not influenced by the changed maximum absorption wavelength. Washing fastness showed 4~4/5 shade change rating without any staining. And dry rubbing fastness was good at low color strength. The bacterial reduction ratios of dyed cotton fabric were also increased.

Utilization of Metasequoia(Metasequoia glyptostroboides) Cone as a New Natural Dye Resource(2): Dyeing Properties and Antimicrobial Functionality of Silk Fiber (새로운 천연염재로서 메타쉐콰이어 열매의 활용(2) : 견섬유의 염색성과 항균성을 중심으로)

  • Yan, Jun;Yoo, Dong Il;Shin, Younsook
    • Textile Coloration and Finishing
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    • v.27 no.4
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    • pp.281-287
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    • 2015
  • The aim of this study was to investigate the possibility utilizing Metasequoia(Metasequoia glyptostroboides) cone as a new natural dye resource. In previous study, dyeing onto cotton fiber was carried out and Metasequoia cone colorant showed low affinity to cotton fiber and maximum dye uptake was obtained at pH 3.5 showing YR Munsell color. For further evaluation of its efficacy as a new natural dye resource, effects of dyeing conditions and mordanting on dye uptake, color change, and colorfastness were investigated for silk fiber. Metasequoia cone colorant showed good affinity toward silk fiber showing YR Munsell color and maximum dye uptake was shown at pH 3.5. Post-mordanting with Cu and Fe improved dye uptake, especially Fe($C_5H_{10}FeO_6$) mordant was effective as much as 2 times higher dye uptake comparing with un-mordanted sample. The color of dyed fabrics with mordanting showed YR Munsell color. Fe mordanted fabrics appeared dark gray~black color. Colorfastness to washing was relatively good, whereas lightfastness of the dyed fabrics showed grade 2. It was confirmed that Metasequoia cone colorant can be used as a new dye resource for silk fiber getting brownish yellow to dark gray/black color depending on mordant type. In addition, it showed antimicrobial functionality.

Immediate Effects of Low-Dye Taping on the Ankle Motion and Ground Reaction Forces in the Pronated Rear-Foot During Gait

  • Kim, Sung-shin;Chung, Jae-yeop
    • Physical Therapy Korea
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    • v.23 no.1
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    • pp.72-79
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    • 2016
  • Background: Increased foot pronation causes biomedchanical changes at the lower limbs, which may result in musculoskeletal injuries at the proximal joints. Pronation rear-foot leads to plantar fasciitis, Achilles tendonitis, and posterior tibial tendonitis pathologically. According to the recent meta-analysis, They showed that therapeutic adhesive taping is more effective than foot orthoses and motion control footwear, low-Dye (LD) taping has become the most popular method used by physiotherapists. Objects: The purpose of this study was to determine the immediate effects of LD taping results in different ankle motion and ground reaction force (GRF) as before and after applied LD taping on pronated rear-foot during gait. Methods: Twenty-four participants were recruited for this study. The gait data were recorded using an 8-camera motion capture system and two force platforms. At first, the experiments were carried out that participants walked barefoot without LD taping. And then they walked both feet was applied LD taping. Results: The ankle inversion minimum was significantly greater after LD taping than before LD taping (p=.04); however, in the GRF, there were no significant differences in the inversion maximum or total motion of the stance phase (p=.33, p=.07), or in the vertical (p=.33), posterior (p=.22), and lateral (p=.14) peak forces. Conclusion: The application of taping to pronation rear-foot assists in increased ankle inversion.

The Characteristic Analysis of the Dye-sensitized Solar Cells as the Change of Incident Angle (광 입사각에 따른 염료감응형 태양전지의 발전특성 분석)

  • Seo, Hyun-Woong;Son, Min-Kyu;Lee, Kyoung-Jun;Jang, Jin-Ju;Hong, Ji-Tae;Kim, Hee-Je
    • 한국신재생에너지학회:학술대회논문집
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    • 2008.10a
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    • pp.124-127
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    • 2008
  • Dye-sensitized solar cells (DSCs) have been proposed as a substitute for overcoming the limitation of Si solar cells because DSC has the various applications using advantages of DSC such as low cost, transparency and flexibility. Although some people point out low efficiency of DSC as the important problem at present, general views say that actually cumulative power is not insufficient as compared with Si solar cell. Therefore, we analyzed the characteristics of both cells according to the change of incident angle in this study. The insensibility about the incident angle has more developable time. Finally, DSC is able to fill a shortage of power caused from low efficiency of DSC for same time by developing during impossible time to develop in Si solar cell. As a result, DSC has 75% and 210% cumulative power of Si solar cell in summer and winter under the standard sunshine duration.

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