• Title/Summary/Keyword: Low-carbon alloy

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A Brief Review of κ-Carbide in Fe-Mn-Al-C Model Alloys

  • Seol, Jae Bok
    • Applied Microscopy
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    • v.48 no.4
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    • pp.117-121
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    • 2018
  • The multiple length scale analysis of previously designed Fe-Mn-Al-C based low-density model alloys reveals the difference in ordered ${\kappa}-carbide$, $(Fe,Mn)_3AlC_x$, between Fe-25Mn-16Al-5.2C (at%) alloy and Fe-3Mn-10Al-1.2C (at%) alloy. For the former alloy composition consisting of fully austenite grains, ${\kappa}-carbide$ showed majorly cuboidal and minorly pancake morphology and its chemical composition was not changed through aging for 24 h and 168 h at $600^{\circ}C$. Meanwhile, for the isothermally annealed ferritic alloy system for 1 hr at 500 and $600^{\circ}C$, the dramatic change in the chemical composition of needle-shape ${\kappa}-carbide$, $(Fe,Mn)_3(Fe,Al)C_x$, was found. Here we address that the compositional fluctuations in the vicinity of the carbides are significantly controlled by abutting phase, either austenite or ferrite. Namely, the cooperative ordering of carbon and Al is an important factor contributing to carbide formation in the high-Mn and high-Al alloyed austenitic steel, while the carbon and Mn for the low-Mn and high Al alloyed ferritic steel.

Influence of Carbon Content on the Mechanical Properties of the Ni-Co Alloy (Ni-Co 합금강의 기계적 특성에 대한 탄소함량의 영향)

  • 장경천;국중민;정장만;권택용;최병기
    • Proceedings of the Korean Society of Machine Tool Engineers Conference
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    • 2004.04a
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    • pp.129-135
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    • 2004
  • This study was to evaluate the effect of carbon content on metallic change and fatigue characteristics with Fe-29% Ni-17% Co, low heat expansion alloy, widely using electronic components, precision machines, and sealing with glass and metal etc. The steels were fabricated with variation of carbon content, 0, 0.03, 0.06, 0.1, and 0.20% with VIM and tensile test and fatigue test were performed to achieve the above purpose. The more carbon content, the higher hardness value and yield strength. But elongation of 0.03%C, 0.06%C, and 0.10%C specimen decreased about 2.2%, 1.5% and 0.8% respectively mote than that of the base metal. Especially the strength and elongation of 0.20%C specimen increased simultaneously about 14.4% and 7.5%. Fatigue life of 0.03%C specimen decreased but the more carbon content, the higher fatigue life over 0.06% carbon content more than that of base metal.

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Effect of Hot Forging on the Hardness and Toughness of Ultra High Carbon Low Alloy Steel (초 고 탄소 저합금강의 경도와 인성에 미치는 열간단조의 영향)

  • Kim, Jong-Beak;Kang, Chang-Yong
    • Journal of Power System Engineering
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    • v.17 no.6
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    • pp.115-121
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    • 2013
  • This study was carried out to investigate the effect of hot forging on the hardness and impact value of ultra high carbon low alloy steel. With increasing hot forging ratio, thickness of the network and acicular proeutectoid cementite decreased, and than were broken up into particle shapes, when the forging ratio was 80%, the network and acicular shape of the as-cast state disappeared. Interlamellar spacing and the thickness of eutectoid cementite decreased with increasing forging ratio, and were broken up into particle shapes, which then became spheroidized. With increasing hot forging ratio, hardness, tensile strength, elongation and impact value were not changed up 50%, and then hardness rapidly decreased, while impact value rapidly increased. Hardness and impact value was greatly affected by the disappeared of network and acicular shape of proeutectoid cementite, and became particle shape than thickness reduction of proeutectoid and eutectoid cementite.

A Study on the Diffusion Behaviors in Weld Interface of Cr-Mo Steel/Austenitic Stainless Steel (Cr-Mo강/오스테나이트계 스테인리스강 용접재의 용접계면에서의 확산거동에 관한 연구)

  • 김동배;이상율;이종훈;이상용;양성철
    • Journal of Welding and Joining
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    • v.17 no.4
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    • pp.46-52
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    • 1999
  • Some of the pressurized reactor pressure vessels used in many chemical plants are made of low alloy carbon steel plates internally clad with an austenitic stainless steel for improved anti-corrosion properties. In this study, metallurgic structure of the weld interface of A 387 Grade12Class1 low alloy carbon steel claded with A182-F321 austenitic stainless steel after thermal exposure simulation heat treatment was investigated to display a characteristic behavior of dissimilar metal weld interface with thermal exposure during service at high temperature and pressure. EPMA, STEM, vickers-hardness test were performed and the results were correlated with the microstructure. To estimate the depth of the carburized/decarburized bands quantitatively, a model for carbon diffusion was proposed. The validity of the proposed theoretical relationships was confirmed by the directly measured data from the welded parts failed during service.

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Effects of Magnetic Characteristics on Coefficient of Thermal Expansion in Fe-Ni-Co-C Invar Alloy for Transmission Line (송전선 강심용 Fe-Ni-Co-C 합금의 열팽창계수에 미치는 자기적 특석의 영향)

  • Kim, Bong-Seo;Kim, Byung-Geol;Lee, Hee-Woong
    • Proceedings of the KIEE Conference
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    • 2001.07c
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    • pp.1346-1348
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    • 2001
  • Generally, Invar alloy shows very low thermal expansion characteristics, lower than $2{\times}10^{-6}$/K approximately. To apply Fe-Ni-Co-C Invar alloy as a core material for large ampacity transmission line we studied the effects of magnetic properties on coefficient of thermal expansion. The coefficient of thermal expansion(CTE) suddenly decreases with addition of a little carbon(0.08%), increases with the increasing carbon and has a constant value at the composition over than 1.0%C. The trend of Curie temperature change with carbon is similar with that of CTE. Therefore, the CTE has a linear relationship with Curie temperature. However, the CTE linearly decreases with the ratio of saturation magnetization and Curie temperature(${\sigma}_s/T_c$).

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Study on the Effect of Induction Heating with Alloying Elements for the Pre-Heat Treated Steel of 100kgf/$mm^2$ Tensile Strength (100Kgf/$mm^2$급 선조질강의 합금원소에 따른 유도가열효과에 관한 연구)

  • Park, J.T.;Ahn, S.T.;Kwon, D.H.;Seo, J.H.;Kang, N.H.;Youn, D.J.
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 2009.05a
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    • pp.40-43
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    • 2009
  • This study is for investigating the effect of induction heating with various alloy elements to manufacture the pre-heat treated steels of 100kgf/$mm^2$ for cold heading. For four kinds of steels, the condition of induction heating (especially, induction tempering) were observed, and their microstructure and tensile and compressive properties were investigated. The middle carbon steel and the low carbon Cr-Mo steel are needed the higher Grange-Baughman tempering parameter than that of the low carbon Cr steel to obtain 100kgf/$mm^2$ tensile strength. For accomplishing the pre-heat treated steel of 100kgf/$mm^2$ tensile strength having advanced cold heading. It is needed that the pre-heat treated steel is manufactured by induction quenching and tempering with the low carbon alloy steel to have the high ratio of ferrite and the fine globular cementite simultaneously.

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A STUDY ON THE RESISTANCE OF WEAR AND CYTOTOXICITY OF THE TITANIUM SURFACE AFTER FILM DEPOSITIONS (박막증착시 티타늄 표면의 마손저항도와 세포독성에 관한 연구)

  • Kim Hyung-Woo;Kim Chang-Whe;Kim Yung-Soo
    • The Journal of Korean Academy of Prosthodontics
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    • v.39 no.1
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    • pp.84-95
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    • 2001
  • Titanium is widely used in dentistry for its low density, high strength, fatigue resistance, corrosion resistance, and biocompatibility. But it has a tendency of surface damage under circumstance of friction and impact for its low hardness of the surface. Coating is one of methods fir increasing surface hardness. Its effect is to improve surface physical characteristics without change of titanium. Diamond-like carbon and titanium nitride are known for its high hardness of the surface. So that this study was aimed at the wear test and the cytotoxicity test of the commercially pure titanium and Ti-6Al-4V alloy which were deposited by diamond-like carbon film or titanium nitride film to acertain improvement of the surface hardness and the biocompatibility. A disk (25mm diameter, 2mm thickness) was made of commercially pure titanium and Ti-6Al-4V alloy and these substrates were deposited by diamond-like carbon film or titanium nitride film. Diamond-like carbon film was deposited by the method of radiofrequency plasma assisted chemical vapor deposition and titanium nitride film was deposited by the method of reactive arc ion plating. Then these substrates were tested about wear characteristics by the pin-on-disk type wear tester in which ruby ball was used as a wear causer under the load of 32N, The fracture cycles were measured by rotating the substrates until their films were fractured. The wear volume was measured after 150 cycles and 3,000 cycles using surface profiler. The cytotoxicity test was peformed by the method of the MTT assay. The results were as follows : 1. In the results of the wear volume test, commercially pure titanium and titanium alloy which were coated by diamond-like carbon film or titanium nitride aim had higher resistance against wear than the substrates which were not coated by any films (P<0.05). 2. In the results of the fracture cycle test and the wear volume test, diamond-like carbon film had higher resistance against wear than titanium nitride film (P<0.05). 3. In both coatings of diamond-like carbon aim and titanium nitride film, Ti-6Al-4V alloy had higher resistance against wear than commercially pure titanium (P<0.05) 4. In the results of the cytotoxicity test, diamond-like carbon film and titanium nitride film had little cytotoxicity as like commercially pure titanium or Ti-6Al-4V alloy (P>0.05).

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Thermodynamic Interactions Among Carbon, Silicon and Iron in Carbon Saturated Manganese Melts (탄소 포화 Mn 합금 용액내 C, Si 및 Fe 사이의 열역학적 상호작용)

  • Paek, Min-Kyu;Lee, Won-Kyu;Jin, Jinan;Jang, Jung-Mock;Pak, Jong-Jin
    • Korean Journal of Metals and Materials
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    • v.50 no.1
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    • pp.45-51
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    • 2012
  • Thermodynamics of carbon in manganese alloy melts is important in manufacturing low carbon ferromanganese and silico-manganese alloys. In order to predict the carbon solubility in liquid $Mn-Si-Fe-C_{sat}$ alloys as a function of melt composition and temperature, thermodynamic interactions among carbon, silicon and iron in carbon saturated liquid manganese should be known. In the present study, the effects of silicon and iron on the carbon solubility in Mn-Si, Mn-Fe and Mn-Si-Fe melts were measured in the temperature range from 1673 to 1773 K. The carbon solubility decreases significantly as silicon and iron contents increase in liquid manganese alloy. The interaction parameters among carbon, silicon and iron in carbon saturated liquid manganese were determined from the carbon solubility data and the Lupis' relation for the interaction coefficient at constant activity.

Effects of Alloy Additions and Annealing Parameters on Microstructure in Cold-Rolled Ultra Low Carbon Steels (극저탄소 냉연강판에서 합금원소 및 어닐링조건이 미세조직에 미치는 영향)

  • Jeong, Woo Chang
    • Journal of the Korean Society for Heat Treatment
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    • v.17 no.2
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    • pp.78-86
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    • 2004
  • Effects of the annealing parameters on the formation of ferrites transformed at low temperatures were studied in cold-rolled ultra low carbon steels with niobium and/or chromium. Niobium and chromium were found to be effective in the formation of the low temperature transformation ferrites. The low temperature transformation ferrites more easily formed when both higher annealing temperature and longer annealing time, allowing substitutional alloying elements to distribute between phases, are in combination with faster cooling rate. It was found from EBSD study that the additions of niobium or chromium resulted in the increase in the numbers of high angle grain boundaries and the decrease in those of the low angle grain boundaries in the microstructures. Both granular bainitic ferrite and bainitic ferrite were characterized by the not clearly etched grain boundaries in light microscopy because of the low angle grain boundaries.

Microstructure and Hardness of High Cr Wear Resistance Materials Made by Ferro Materials (페로 소재로 만들어진 고크롬계 내마모재의 미세조직과 경도)

  • Kim, Gwang-Soo
    • Korean Journal of Materials Research
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    • v.16 no.1
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    • pp.5-10
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    • 2006
  • This study was performed to investigate the characteristics of the synthesized powder type ferro materials for wear resistant hardfacing. The powder type filler materials were made from ferro Cr and ferro Mn. Those ferro materials are two types, such as high carbon and low carbon contained. The alloy composed of high carbon ferro Cr and high carbon ferro Mn exhibited the best properties in terms of microstructure and hardeness for wear characteristics. Further, the alloys produced by the synthesized powders and wire type filler, were also evaluated in terms of microstructures and microhardness measurements. The results indicated that the synthesized powders displayed reasonable properties compared to commercial grade materials. The hardness value of the alloy produced by the synthesized powders were approached about 90% of the commercial grade's hardness. The hardness values of the alloys closely depended on the amount of the dissolution of the ferro Cr, the hardness and the volume of the eutectic phase.