• The Korean Journal of Ceramics
• /
• v.5 no.4
• /
• pp.375-378
• /
• 1999

In tho XRD study of $56ZrF_4 \cdot34BaF_2 \cdot4AIF_3 \cdot(6-x)LaF_3 \cdotxLnF_3$ glassdLn=Ce, Nd, Gd, Th), halo pattern charactarktic fo an amorphous sample appeared. When the halo peak angle ($\theta_p$) was converted into a wavenumber with $Qp=4\pi sinG\pi/\lambda(\lambda$ is the wavolongth of the radialion used), it was found that the Qp values varied almost liuearly with the concentration 01 $LnF_3$. The emissiou spect1.a of $Ce^{3-}$-containing fluoride glasses nnder 273 nm excitation had a peak maximum at ea. 300 nm $(Ce^{3+}$ 5d-4f- transition). The maximal intensity of the fluorescence was observed when the $CeF_3$, content was extremely low (ca. 1 mol%j. DTA measurement revealed tbat these fluoride glasses had two crystallization temperatures. In $56ZrF_4. 34BaF_2. 4NF_3. (6-x)LaF_3 .xNdF_3$ glasses, the actmation energies of crystallization obtained from a Kssinger plot were 1.7 and 5.0 eV for the glass with x=2, and 1.9 and 5.6 eV for the glass with x=4.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
• /
• v.23 no.10
• /
• pp.776-781
• /
• 2010

CdSe films were deposited on glass substrates (CdSe/glass) by thermal evaporation. Substrate temperature was lowered by cooling substrate holder with liquid nitrogen. Substrate temperatures were $200^{\circ}C$, $0^{\circ}C$ and $-40^{\circ}C$. The crystallographic properties and surface morphologies of the CdSe/glass films were studied by X-ray diffraction (XRD) and scanning electron microscopy (SEM). The optical and electrical properties of the films were investigated by dependence of energy gap, photosensitivity and resistivity on the substrate temperature. CdSe/glass showed energy gap of ~1.72 eV regardless of substrate temperature. The resistivity of the films decreased to $0.5{\Omega}cm$ by lowering the substrate temperature to $-40^{\circ}C$. The CdSe/glass films prepared at $0^{\circ}C$ showed the highest photosensitivity among the films in this study.

• Proceedings of the Korean Society of Precision Engineering Conference
• /
• 2006.05a
• /
• pp.209-210
• /
• 2006

We have successfully termed brown colored patterns inside of a transparent borosilicate glass generally known as BK7, laying the focus of near infrared Ti: sapphire femtosecond laser beam in the bulk BK7 glass. It is important to keep the laser power well below the damage threshold of BK7 in forming the color center. Thanks to the low laser power, there was no laser induced mechanical damage such as cracks or threads in the color formed area. From the absorbance spectrum and its gaussian fitting, we found the band gap of BK7, 4.21eV, and three absorption edges.

• KIEAE Journal
• /
• v.15 no.1
• /
• pp.77-82
• /
• 2015

The purpose of this study is to compare the thermal insulation performance of windows according to the formation of air layer and to evaluate its energy efficiency on a selected standard house. A thermal insulation test, KS F 2278 was used to measure U-values (Heat transmission coefficients) for the following three cases: the first case (Case 1) is a Low-E pair glass (Argon injected), the second case (Case 2) is a Low-E pair glass with the air cap attached on the glass surface, and the third case (Case 3) is a Low-E pair glass, on the frame of which the air cap is attached. The evaluation of the energy efficiency was conducted according to a building energy calculation method from ISO 13790, calculation of energy use for space heating and cooling, using the U-values obtained from the thermal insulation tests. As results of the tests, the U-values of Case 1, Case 2, and Case 3 were $1.668W/m^2{\cdot}K$, $1.568W/m^2{\cdot}K$, and $1.319W/m^2{\cdot}K$ respectively. The Case 2 had about 5.9% lower value than the Case 1, and the Case 3 had about 20.9% lower value than the Case 1. It seems that the thermal performance of the windows is attributed to an increase of the heat resistance and the thickness of air layer. An evaluation of the energy efficiency of the three cases on the selected standard house showed that the amount of heating energy demand per unit area was $7.776kWh/m^2{\cdot}yr$ for the Case $1,6.856kWh/m^2{\cdot}yr$ for the Case 2, and $4.856kWh/m^2{\cdot}yr$ for the Case 3. This study suggests that the formation of air layer (by using air cap) and its thickness should reduce the heat energy demand and thus improve the energy saving efficiency

• Journal of Adhesion and Interface
• /
• v.10 no.4
• /
• pp.162-168
• /
• 2009

As a preliminary study of optimum composite properties under cryogenic temperature, the comparison of interfacial properties of carbon or glass fibers reinforced epoxy composites was evaluated at ambient and intermediate low temperature, i.e., 25 and $-10^{\circ}C$ by using micromechanical techniques. Under tensile and compressive loading conditions, their mechanical modulus at low temperature was higher than that atambient temperature. Interfacial shear strength (IFSS) at ambient and low temperatures was compared to each other, depending on epoxy matrix toughness and apparent modulus at the interface. The IFSS was much higher at low temperature than that at room temperature because of the increased epoxy matrix modulus. Statistical distributions of tensile strengths of glass and carbon fibers were evaluated for different temperature ranges, which is dependent upon fiber's inherent flaws and rigidity.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
• /
• v.13 no.11
• /
• pp.926-931
• /
• 2000

The microwave dielectric properties and the microstructures as a mole fraction of (1-x)ZnNb$_2$O$_{6}$-xPb$_{5}$Nb$_4$O$_{15}$ ceramics with CuV$_2$O$_{6}$, Sb$_2$O$_3$ and glass(ZNPN ceramics) was investigated. 0.98ZN-0.02PN ceramics containing 1.5 wt% CuV$_2$O$_{6}$ 1.0 wt% Sb$_2$O$_3$ and 1.0 wt% glass had a dielectric constant($\varepsilon$$_{r}$) of 23, Qxf$_{o}$ value of 15000 and TCF(Temperature Coefficient of resonance Frequency) of -25 ppm/$^{\circ}C$ and it is possible to be co-fired with Ag electrode at 90$0^{\circ}C$. As sintered temperature increases over 90$0^{\circ}C$ the grain size of ZNPN ceramics was increasing for growth and it has poor co-fired properties with Ag electrode.e.ctrode.e.e.

• The Korean Journal of Ceramics
• /
• v.5 no.2
• /
• pp.178-182
• /
• 1999

Simple binary $Na_2S-SiO_2$ oxysulfide glasses were prepared by a conventional melt-quench method in order to investigate the role of sulfur in glass structure and the electronic state. By X-ray photoelectron spectroscopy(XPS) measurement, S2p binding energy of the glass was observed at approximately 161eV which was close to that of ionic $S^{2-}$. The coordinating state around silicon atoms were investigated by ${29}^Si$ MAS-NMR measurement. The chemical shift observed from NMR supported that sulfur atom was joined to a silicon atom by substituting for an oxygen atom and was present as a non-bridging sulfide ion in low alkali content. On the other hand, it could be presumed that a portion of sulfur anions existed in an isolated state from the glass-network frame at high alkali content. The state of these sulfurs was also studied by Raman spectroscopy in detail.

• Tribology and Lubricants
• /
• v.35 no.2
• /
• pp.106-113
• /
• 2019

We investigated the application of tetrahedral amorphous carbon (ta-C) coatings to fabricate a glass lens manufactured using a glass molding process (GMP). In this work, ta-C coatings with different thickness (50, 100, 150 and 200 nm) were deposited on a tungsten carbide (WC-Co) mold using the X-bend filter of a filtered cathode vacuum arc. The effects of thickness on mechanical and tribological properties of the coating were studied. These ta-C coatings were characterized by atomic force microscopy, scanning electron microscopy, nano-indentation measurements, Raman spectrometry, Rockwell-C tests, scratch tests and ball on disc tribometer tests. The nano-indentation measurements showed that hardness increased with an increase in coating thickness. In addition, the G-peak position in the Raman spectra analysis was right shifted from 1520 to $1586cm^{-1}$, indicating that the $sp^3$ content increased with increasing thickness of ta-C coatings. The scratch test showed that, compared to other coatings, the 100-nm-thick ta-C coating displayed excellent adhesion strength without delamination. The friction test was carried out in a nitrogen environment using a ball-on-disk tribometer. The 100-nm-thick ta-C coating showed a low friction coefficient of 0.078. When this coating was applied to a GMP, the life time, i.e., shot counts, dramatically increased up to 2,500 counts, in comparison with Ir-Re coating.

• 한국태양에너지학회:학술대회논문집
• /
• 2011.04a
• /
• pp.156-161
• /
• 2011

In case of newly constructed buildings, the construction type is almost Curtain-wall system or large window in building skin. However, these kind of buildings have problems with regulations on building energy efficiency. And national regulations on building energy efficiency limit only the V-factor of window(except infiltration), it is hard to predict energy consumption of Curtain-wall buildings which gain large solar energy in summer. In this study, the influence of LSG(Light to Solar Gain) on energy performance was theoretically analyzed with simulation. LSG is the value of VLT divide SHGC and represents the optical performance of the glass or glazing. The Window & Therm program developed in LBNL was used to analyze window systems and EnergyPlus was used to building energy. Cases of glazing are three types; single coated Low-e clear glazing, tripple coated Low-e clear glazing, tripple coated Low-e tinted glazing. The results of this study are follows; 1) The building energy consumption of Alt-l, 2, 3 were about 300, 253, $259kWh/m^2{\cdot}yr$ respectively. Therefore, improvement of LSG could save the energy up to 16%. 2) The saved energy could be converted 1 billion won as annual benefit of total energy costs 3) SHGC and LSG more influence on cooling energy than heating energy in office buildings.

• Journal of the Korean Ceramic Society
• /
• v.45 no.7
• /
• pp.401-404
• /
• 2008

Willemite ($Zn_2SiO_4$) are a wide range of applications such as a phosphor host and an important crystalline phase in glass ceramics, electrical insulators, glazes, and pigments. In this study, Willemite precursors were synthesized with zinc silicate gels from mixture of zinc nitrate solution and various sodium silicate solution by the geopolymer technique. To examine the crystallization behavior, precursors were have been monitored by the XRD. A pure willemite phase was obtained at $900^{\circ}C$. TEM investigations revealed that the sample with 50 nm particle size was obtained via heat-treated at $900^{\circ}C$ for W-3.