• Journal of the Mineralogical Society of Korea
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• v.19 no.3 s.49
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• pp.197-207
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• 2006

In the coal-bearing formations of the Janggi Group, which are reported as typical clastic sediments, several beds of volcaniclastic rocks are actually found in the Yeongil area. The coal-bearing formations generally exhibit alternating lithologic characteristics of pyroclastic and epiclastic sedimentary facies. Tuff and tuffaceous sandstone rich in pumice fragments are characteristic in the coal-bearing fermations. Diagenetic minerals found in the pyroclastic rocks of the upper and lower coal-bearing formations are montmorillonite, clinoptilolite, opal-CT, and quartz. Several tuffaceous beds correspond to the low-grade ores of zeolites and bentonite, and moreover, these ores mostly occur as thin beds less than 1 m in thickness. Thus, the potential of altered tuffaceous rocks as the resources typical of zeolite and bentonite seems to be low. However, based on mineral composition and CEC determinations, it can be evaluated that these tuffaceous rocks mostly have the promising potential for utilization as the absorbent-functional mineral resources such as acid clays, if these low-grade ores plus adjacent tuffaceous rocks are collectively exploited.

• Journal of the Korea Organic Resources Recycling Association
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• v.23 no.4
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• pp.11-20
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• 2015

In the present work, a basic study on the in-situ biogenic methane generation from low grade coal bed was conducted. Lignite from Indonesia was used as a sample feedstock. A series of BMP (Biochemical Methane Potential) tests were carried out under the different experimental conditions. Although nutrients and anaerobic digester sludge were added to the coal, the produced amount of methane was limited. Both temperature control and particle size reduction showed little effect on the increase of methane potential. When rice straw was added to lignite as an external carbon source, methane yield of 94.4~110.4 mL/g VS was obtained after 60 days of BMP test. The calorific value of lignite after BMP test decreased (4.5~12.1 %) as increasing the content of rice straw (12.5~50 wt % of lignite), implying that anaerobic digestion of rice straw led to partial degradation of lignite. Therefore, rice straw could be used as an external carbon source for the start-up of in-situ biogas generation from low grade coal bed.

• Journal of the Korean Society of Combustion
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• v.18 no.4
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• pp.53-58
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• 2013

Lots of Coal power plants (about 30) using bituminous coals are being run in Korea. The use of high volatile low grade sub-bituminous coal is increasingly extended because of imbalance between the worldwide coal supply and demand. Mill-fire has been an important issue since the use of such sub-bituminous coal. In existing coal plants of Korea, shutdown of coal and air supplies could be only a way, and an alternative has not been found in suppressing the mill fire. The inside fowfield in the mills has a highly fuel-rich, low temperature, and high velocity and non-reactive such that it could be a nonreactive system essentially. Nevertheless, occasional fire-occurrence could be attributed to the existence of an ignition source. However it has not been so far investigated in detail. The current work has a focus on suppressing the mile fire via some parametric experimental study such as effects of temperature, residence time, ignition source, and inert gas mixing. The results show that an small amount of $CO_2$- or $N_2$-mixing with air is very effective in suppressing fire formation even at high temperatures or flying sparks. The results suggest that exhaust gas recirculation into the mill should be an alternative to suppress mill fire.

• Journal of the Korean Applied Science and Technology
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• v.39 no.2
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• pp.368-376
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• 2022

Spontaneous ignition occurs in industrial sites or anywhere in our lives, and is a phenomenon in which a substance ignites itself without an ignition source in the atmosphere. As the rate of chemical reaction increases, the heat generated increases, and the risk of spontaneous ignition increases. In this study, safe raw materials used for food and cosmetics were mixed to prepare coal spontaneous ignition prevention agents specifically among various spontaneous ignition phenomena. The effect of suppressing spontaneous combustion of coal was confirmed through lab and field tests with low-calorie, low-grade coal from Indonesia. As a result of the outdoor field test, the ignition prevention agent manufactured in this study compared with the control group(Fire after 90 days) showed excellent ignition inhibitors for more than 120 days. In addition, CO concentration control was confirmed by comparing the concentration of carbon monoxide for 50 days at the indoor coal yard. It was confirmed that the results were better than the comparative group coal and the existing anti-firing method. In addition, the possibility of coal fire prevention agents for indoor coal farms will be applied from 2024 was confirmed by studying the environment and safety of workers' working environments through official test such as soil and water quality test, MSDS of coal fire prevention agents in consideration of working workers, water quality, and eye irritation tests.

• Journal of Energy Engineering
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• v.24 no.4
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• pp.89-96
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• 2015

Recently, much research has been put into finding the causes and solutions of slagging/fouling problems that occur at the end of the boiler. This slagging/fouling, caused by low-rank coal's ash, disturbs the thermal power and greatly reduces efficiency. In environmental aspects, such as NOx pollution, governments have been implementing restrictions on the quantity of emission gases that can be released into the atmosphere. To solve these problems, research on Ash Free Coal (AFC), which eliminates ash from low-rank coal, is in progress. AFC has advantages over similar high-rank coals because it increases the heating value of the low grade coal, reduces the contaminants that are emitted, and decreases slagging/fouling problems. In this study, using a DTF, the changes of NOx emissions, unburned carbon, and the characteristics of ash deposition were identified. KCH raw coal, AFC extracted from KCH, residue coal, Glencore, and Mixed Coal (Glencore 85wt% and residue coal 15wt%) were studied. Results showed that AFC had a significantly lower emission of NOx compared to that of the raw coal and residue coal. Also, the residue coal showed a higher reactivity compared to raw coal. And finally, In the case of the residue coal and mixed coal, they showed a lower ash deposition than that of low-rank coal.

• Journal of the Korean Society of Safety
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• v.14 no.3
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• pp.84-92
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• 1999

The effects of air velocity and excess air on combustion characteristics were studied in a fluidized bed combustor. The domestic low-grade anthracite coal with heating value of 2010 kcal/kg and the imported bituminous coal from Australia with heating value of 6520 kcal/kg were used as coal samples. The combustion characteristics of mixed fuels in a fluidized bed combustor could be interpreted by pressure fluctuation properties, ash distribution and gas emission. The properties of the pressure fluctuations, such as the standard deviation, cross-correlation function, dominant frequency and the power spectral density function, were obtained from the statistical analysis. From this study, the combustion region increased with increasing air velocity but decreased with excess air due to combustion characteristics of anthracite and bituminous coal.

• Journal of Energy Engineering
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• v.21 no.1
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• pp.68-74
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• 2012

Sub-bituminous coals have been used increasingly in coal-fired power plants with a proportion of over 50% in the blend with bituminous coals. As a result, the unburned material in fly ash has increased and is causing problems in utilizing the fly ash as an additive for concrete production. In this study, analysis of fly ash obtained from a 500 MWe power plant was carried out and unburned material in the fly ash found to be soot. The coals used in the plant were analyzed with CPD model to investigate the sooting potential depending on the coal type and blending ratio.

• Korean Chemical Engineering Research
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• v.59 no.2
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• pp.174-179
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• 2021

Recently, hybrid coal research is underway to upgrade low-grade coal. The hybrid coal is made by mixing low-grade coal with bioliquids such as molasses, sugar cane, and lignin. In the case of lignin used here, a large amount of lignin is included in the wastewater of the papermaking process, and thus, research on hybrid coal production using the same is attracting attention. However, since a large amount of metal ions are contained in the lignin wastewater from the papermaking process, substances that corrode the generator are generated during combustion, and the amount of fly ash is increased. To solve this problem, it is essential to remove metal ions in the lignin wastewater. In this study, metal ions were removed by ion exchange with a alumina hollow fiber membrane coated with K-Phillipsite (K-PHI) zeolite. The alumina hollow fiber membrane used as the support was prepared by the nonsolvent induced phase separation (NIPS) method, and K-PHI seeds were prepared by hydrothermal synthesis. The prepared K-PHI seed was seeded on the surface of the support and coated by secondary growth hydrothermal synthesis. The characteristic of prepared coating membrane was analyzed by Scanning Electron Microscope (SEM), X-Ray Diffraction (XRD), Energy Dispersive Spectroscopy (EDX), and the concentration of metal ions before and after ion exchange was measured by Inductively Coupled Plasma Optical Emission Spectrometer (ICP-OES). The extraction amount of K+ is 86 mg/kg, and the extraction amount of Na+ is 54.9 mg/kg. Therefore, K-PHI zeolite membrane has the potential to remove potassium and sodium ions from the solution and can be used in acidic lignin wastewater.

• Journal of the Korean Society of Combustion
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• v.12 no.4
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• pp.47-56
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• 2007

Utilization of sewage sludge for industrial fuel should be considered in appropriate calory with low emission of environmental pollutants and the amount of sewage sludge for continuously long-time operation. For the low grade fuel(<4,000kcal/kg), one of proper processes is that coal and oil are added into sewage sludge to remove impurities and increase calory(>7,000kcal/kg) and the amount of fuel having sewage sludge. Recently, 2-step agglomeration has been attempted by secondarily agglomerate sewage sludge onto the primary nuclei formed by agglomeration of coal and oil. Furthermore, sawdust and waste oil can substitute about 1/3 each for coal and mineral oil consumed in this process, which will lead to securing alternative energy resources from environmental pollutants as well as cost reduction.

• Transactions of the Korean hydrogen and new energy society
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• v.27 no.6
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• pp.621-627
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• 2016

Low-priced hydrogen is required in petrochemical industry for producing low-sulfur oil, and upgrading low-grade crude oil since environmental regulations have been reinforced. Steel industry can produce hydrogen from by-product gases such as Blast Furnace Gas (BFG), Coke Oven Gas (COG), and Linze Donawitz Gas (LDG) with water gas shift (WGS) reaction by catalysis. In this study, we optimized conditions for WGS reaction with commercial catalysts by BFG and LDG. In particular, the influence on activity of gas-hourly-space-velocity, and $H_2O/CO$ ratios at different temperatures were investigated. As a result, 99.9%, and 97% CO conversion were showed with BFG, and LDG respectively under $350^{\circ}C$ High Temperature Shift (HTS), $200^{\circ}C$ Low Temperature Shift (LTS), 3.0 of $H_2O/CO$, and $1500h^{-1}$ of GHSV. Furthermore, 99.9% CO conversion lasted for 250 hours with BFG as feed gas.