• 한국진공학회:학술대회논문집
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• 한국진공학회 2014년도 제46회 동계 정기학술대회 초록집
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• pp.281-281
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• 2014

The field emission properties of GaN are reported in the present study. To be a good field emitter, it requires a low work function, high aspect ratio, and strong mechanical stability. In the case of GaN, it has a quite low work function (4.1eV) and strong chemical/mechanical/thermal stabilities. However, so far, it was difficult to fabricate vertical GaN nanostructures with a high aspect ratio. In this study, we successfully achieved vertically well aligned GaN nanostructures with chemical vapor-phase etching methods [1] (Fig. 1). In this method, we chemically etched the GaN film using hydrogen chloride and ammonia gases at high temperature around $900^{\circ}C$. This process effectively forms vertical nanostructures without patterning procedure. This favorable shape of GaN nanostructures for electron emitting results in excellent field emission properties such as a low turn-on field and long term stability. In addition, we observed a uniform fluorescence image from a phosphor film attached at the anode part. The turn-on field for the GaN nanostructures is found to be about $0.8V/{\mu}m$ at current density of $20{\mu}A$/cm^2. This value is even lower than that of typical carbon nanotubes ($1V/{\mu}m$). Moreover, threshold field is $1.8V/{\mu}m$ at current density of $1mA$/cm^2. The GaN nanostructures achieved a high current density within a small applied field range. We believe that our chemically etched vertical nanostructures are the promising structures for various field emitting devices.

• 한국산학기술학회논문지
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• 제14권3호
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• pp.1495-1501
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• 2013

본 연구는 탄소저감과 관련하여 그 동안 진행되어온 도시 단위의 저탄소형 신도시 개발 혹은 기성 시가지에서의 전면철거형 정비방식에서 탈피하여 현지개량방식에 의한 주거지 재생의 탄소저감 효과를 분석하기 위한 것이다. 이를 위해 기존 문헌조사 및 국내 외 사례연구를 통해 탄소저감을 위한 기술적 계획요소들을 도출한 후, 사례 대상지인 청주시 탑2정비구역을 대상으로 관련자료를 수집하여 에너지 소비량 기반의 탄소배출량을 산출하였다. 이 후 탄소배출량 산출기준을 이용하여 기존 대상지역의 탄소발생량과 기 계획된 전면철거방식의 공동주택개발에 따른 탄소발생량을 산출하고, 새롭게 제안된 현지개량방식의 저탄소 지향형 개발에 따른 탄소발생량을 산출하여 상호 비교분석을 실시하였다. 이를 통해 현지개량방식의 저탄소 지향형 주거지 재생이 기존의 전면철거방식의 공동주택 재개발에 비해 탄소를 저감시킬 수 있는 효과적인 방안임을 확인하였다.

• Bulletin of the Korean Chemical Society
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• 제32권3호
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• pp.894-898
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• 2011

The first example of lead compound from $Pb(NO_3)_2$ and $H_3L$ N-heterocyclic ligand $(H_3L\;=\;(HO_2C)_2(C_3N_2)(C_3H_7)CH_2(C_6H_4)(C_6H_3)CO_2H)$, $[Pb_4(L')_4]{\cdot}5H_2O$ 1 (L' = OOC$(C_3H_7)(C_3N_2)CH_2(C_6H_4)(C_6H_3)COO)$, has been obtained under hydrothermal condition by decarboxylation, and characterized by elemental analysis, IR, TGDTA, and single-crystal X-ray diffraction. Compound 1 possesses a rare two-dimensional upper-lower offset terrace-like layer structure. In 1, crystallographic distinct Pb(II) ion adopts five-coordination geometry, and two lattice water molecules occupy the voids between 2-D layers. Results of solid state fluorescence measurement indicate that the emission band 458 nm may be assigned to $\pi^*-n$ and $\pi^*-\pi$ electronic transitions within the aromatic systems of the ligand L', however, the emission bands centred at 555 nm, 600 nm and 719 nm may be derived from phosphorescent emission ($\lambda_{excitation}$ = 390 nm).

• 한국재료학회:학술대회논문집
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• 한국재료학회 2011년도 추계학술발표대회
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• pp.18.1-18.1
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• 2011

Some applications of carbon nanotubes (CNTs) as field emitters, such as x-ray tubes and microwave amplifiers, require high current emission from a small emitter area. To emit the high current density, CNT emitters should be optimally fabricated in terms of material properties and morphological aspects including high crystallinity, aspect ratio, distribution density, height uniformity, adhesion on a substrate, low outgassing rate during electron emission in vacuum, etc. In particular, adhesion of emitters on the substrate is one of the most important parameters to be secured for high current field emission from CNTs. So, we attempted a novel approach to improve the adhesion of CNT emitters by incorporating metal oxide layers between CNT emitters. In our previous study, CNT emitters were fabricated on a metal mesh by filtrating the aqueous suspensions containing both highly crystalline thin multiwalled CNTs and thick entangled multiwalled CNTs. However, the adhesion of CNT film was not enough to produce a high emission current for an extended period of time even after adopting the metal mesh as a fixing substrate of the CNT film. While a high current was emitted, some part of the film was shown to delaminate. In order to strengthen the CNT networks, cobalt-nickel oxides were incorporated into the film. After coating the oxide layer, the CNT tips seemed to be more strongly adhered on the CNT bush. Without the oxide layer, the field emission voltage-current curve moved fast to a high voltage side as increasing the number of voltage sweeps. With the cobalt-nickel oxide incorporated, however, the curve does not move after the second voltage sweep. Such improvement of emission properties seemed to be attributed to stronger adhesion of the CNT film which was imparted by the cobalt-nickel oxide layer between CNT networks. Observed after field emission for an extended period of time, the CNT film with the oxide layer showed less damage on the surface caused by high current emission.

• 대한화학회지
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• 제43권3호
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• pp.315-320
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• 1999

고성능 전계발광(electroluminescent, EL) 소자에 사용되는 발광물질의 개발을 위하여 설계된 발광기능기의 분자구조는 비스스틸렌구조의 발광기능기에 전자주입과 수송을 위한 시안기와 정공주입과 수송을 위한 페닐아민기를 가진 구조이다. 위의 발광기능기로 구성 된 고분자물질, PU-BCN과 저분자물질, D-BCN을 합성하였다. PU-BCN과 D-BCN을 발광층으로 사용하여 만들어진 단층형 소자(SL)의 구조는 Indium-tin oxide(ITO)/발광층/MgAg이고, 적층형소자의 구조는 ITO/발광층/oxadiazole dehvative/MgAg, (DL-E)와 ITO/tri-phenylamine derivative/발광층/MgAg,(DL-H)의 두 종류이다. 동일한 발광기능기를 가진 고분자 발광물질, PU-BCN과 저분자발광물질, D-BCN은 전하주입과 수송성이 띄어난 물질로 평가되었으며, 두 발광물질들은 높은 전류밀도하에서 거의 동일한 발광특성을 보였다. 발광물질들의 최대 발광 피이크는 약 640 nm의 적색 발광영역에서 측정되었다.

• 한국분무공학회지
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• 제21권3호
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• pp.130-136
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• 2016

NOx and PM are important air pollutants as vehicle management policy aspect. Medium-duty truck is the main source of the pollutants although the vehicle market share is only 3.5%. National emission portion of NOx and PM form the mobile sourece are 14% and 16% respectively. In this study it was investigated that characteristics of air pollutants emission on medium duty truck equipped with EGR and SCR system. Vehicle's test reflected driving cycle on the chassis dynamometer, and applied test cycle was WHVC(World Harmonized Vehicle Cycle) mode. The test cycle include three segments, represent urban, rural and motorway driving. Based on the test results NOx, PM, HC were less emitted form SCR vehicle than EGR vehicle. And CO was less emitted form EGR vehicle than SCR vehicle due to CO oxidation reaction on DPF surface. And most air pollutants reduced as average vehicle speed increased. Pollutants were less emitted on motorway section than urban and rural sections. But highly NOx emission on motorway section was verified according to increased EGR ratio on fast vehicle speed. HC and CO additional emission was identified as 68%, 58% respectively during SCR vehicle's cold engine start emission test. NOx additional emission was detected by 24% on SCR vehicle's condition of engine cold start while not detected on vehicle equipped with EGR. SCR vehicle's additional NOx emission was derived from low reaction temperature during engine cold start condition. medium-duty truck emission characteristics were investigated in this study and expected to used to improve air pollutants management policy of medium-duty truck equipped with SCR & EGR.

• Journal of Information Display
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• 제2권3호
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• pp.72-77
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• 2001

Amorphous silicon thin-film transistors (a-Si TFTs) were incorporated into Mo-tip-based triode-type field emitters and diode-type ones of carbon nanotubes for an active-matrix cathode (AMC) plate of field emission displays. Also, we developed a novel surface-treatment process for the Mo-tip fabrication, which gleatly enhanced in the stability of field emission. The field emission currents of AMC plates on glass substrate were well controlled by the gate bias of a-Si TFTs. Active-matrix field emission displays (AMFEDs) with these AMC plates were demonstrated in a vacuum chamber, showing low-voltage matrix addressing, good stability and reliability of field emission, and highly uniform light emissions from the anode plate with phosphors. The optimum design of AMFEDs including a-Si TFTs and a new light shield/focusing grid is discussed.

• 한국연소학회:학술대회논문집
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• 한국연소학회 2006년도 제33회 KOSCO SYMPOSIUM 논문집
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• pp.128-133
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• 2006

Influence of changing combustor pressure on flame stabilization and nitrogen oxide (NOx) emission in the swirl-stabilized flame with secondary fuel injection was investigated. The combustor pressure was controlled by suction at combustor exit. Pressure index ($P{\ast}=P_{abs}/P_{atm}$), where $P_{abs}$ and $P_{atm}$ indicated the absolute pressure and atmosphere pressure, was controlled in the range of $0.7{\sim}1.3$ for each equivalence ratio conditions. The flammable limits of swirl flames were largely influenced by changing combustor pressure and they showed different tendency compared with laminar flames. Emission index showed maximum value near atmospheric condition and decreased with decreasing pressure index for overall equivalence ratio conditions. R.m.s of pressure fluctuations also showed similar tendency with nitric oxide emission. By injecting secondary fuel into flame zone, the flammable limits were extended significantly. Emission index of nitric oxide and r.m.s. of pressure fluctuations were also controlled by injecting secondary fuel. The swirl flames were somewhat lifted by secondary fuel with high momentum, hence low nitric oxide emission. This NOx reduction technology is applicable to industrial furnaces and air conditioning system by adopting secondary fuel injection.

• 한국염색가공학회지
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• 제29권4호
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• pp.223-230
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• 2017

Three super hydrophobic fluorescence dyes were selected to dye high molecular weight polyethylene fiber and their molar absorptivity, emission spectrum, and quantum yield were measured. From the results of color strength on the fiber, all the three dyes exhibited linear increase according to the dye concentration and Fluoro3 dye showed the highest color strength among them. Emission strength of the fluorescence dyes on the fiber was investigated according to the dye concentrations. The emission was increased with the increase of the dye concentration at relatively low dye concentration and then after showing the maximum emission strength the emission was decreased at higher dye concentrations. The highest emission was obtained in Fluoro2 dye. Color fastness to washing and rubbing was generally good enough, however, especially to light, only Fluoro3 dye exhibited rating 3 acceptable practically and Fluoro1 and 2 was ratings 1 which is unacceptable level.

• Asian Journal of Atmospheric Environment
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• 제11권3호
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• pp.153-164
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• 2017

Odor dispersion around a cubic building from rooftop odor emissions was investigated using computational fluid dynamics (CFD). The Shear Stress Transport (here after SST) $k-{\omega}$ model in FLUENT CFD code was used to simulate the flow and odor dispersion around a cubic building. The CFD simulations were performed for three different configurations of cubic buildings comprised of one building, two buildings or three buildings. Five test emission rates were assumed as 1000 OU/s, 2000 OU/s, 3000 OU/s, 4000 OU/s and 5000 OU/s, respectively. Experimental data from wind tunnels obtained by previous studies are used to validate the numerical result of an isolated cubic building. The simulated flow and concentration results of neutral stability condition were compared with the wind tunnel experiments. The profile of streamline velocity and concentration simulation results show a reasonable level of agreement with wind tunnel data. In case of a two-building configuration, the result of emission rate 1000 OU/s illustrates the same plume behavior as a one-building configuration. However, the plume tends to the cover rooftop surface and windward facet of a downstream building as the emission rate increases. In case of a three-building configuration, low emission rates (<4000 OU/s) form a similar plume zone to that of a two-building configuration. However, the addition of a third building, with an emission rate of 5000 OU/s, creates a much greater odorous plume zone on the surface of second building in comparison with a two-building configuration.