• Title/Summary/Keyword: Low carbon steels

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Area Effect on Galvanic Corrosion of Condenser Materials with Titanium Tubes in Nuclear Power Plants (Titanium 전열관을 사용하는 원전 복수기 재료의 Galvanic Corrosion에 미치는 면적의 영향)

  • Hwang, Seong-Sik;Kim, Joung-Soo;Kim, Uh-Chul
    • Nuclear Engineering and Technology
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    • v.25 no.4
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    • pp.507-514
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    • 1993
  • Titanium tubes have recently been used in condensers of nuclear power plants since titanium has very good corrosion resistance to seawater. However, when it is connected to Cu alloys as tube sheet materials and these Cu alloys are connected to carbon steels as water box materials, it makes significant galvanic corrosion on connected materials. It is expected from electrochemical tests that the corrosion rate of carbon steel will increase when it is galvanically coupled with Ti or Cu in sea water and the corrosion rate of Cu will increase when it is coupled with Ti, if this couple is exposed to sea water for a long time. It is also expected that the surface area ratios, R$_1$(surface area of carbon steel/surface area of Ti) and R$_2$(surface area of carbon steel/surface area of Cu) are very important for the galvanic corrosion of carbon steel and that these should not be kept to low values in order to minimize the galvanic corrosion on the carbon steel of the water box. Immersed galvanic corrosion tests show that the corrosion rate of carbon steel is 4.4 mpy when the ratio of surface area of Fe/ surface area of Al Brass is 1 while it is 570 mpy when this ratio is 10$^{-2}$ . The galvanic corrosion rate of this carbon steel is increased from 4.4 mpy to 13 mpy at this area ratio, 1, when this connected galvanic specimen is galvanically coupled with a Ti tube. This can be rationalized by the combined effects of R$_1$ and R$_2$ on the polarization curve.

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A Study on Repeat Heat Treating and Controlled Rolling of Mo-alloyed Plate Steels (Mo첨가 열연강판의 반복 열처리 제어압연에 관한 연구)

  • Lee, Jeong-Hun;Hong, Seung-Chan;Lee, Gyeong-Seop
    • Korean Journal of Materials Research
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    • v.9 no.7
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    • pp.740-747
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    • 1999
  • Grain refinement is the only strengthening mechanism that improves both strength and toughness. Controlled rolling and accelerated cooling techniques have been known to be effective method to improve the mechanical properties by controlling the recrystallization and/or grain coarsening during processing. Repeat phase transformation $(\gamma/\alpha)$ by repeat heat treating is another way of grain refinement. In this study, a combined effect of controlled rolling and repeat heat treating was investigated. To study the effects of Mo addition and process parameters, Mo alloyed low carbon steels were prepared and thermomechanical controlled processes were simulated in the Gleeble system. The Mo addition resulted in an increasement of the grain coarsening temperature and suppress austenite recrystallization. The optimum condition for the refinement of austenite was obtained when the controlled rolling was performed twice with the same heat treatment condition, and reduction ratio of second pass was higher than that of first pass.

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The influence of treatment time on the microstructure of plasma nitrocarburised compound layer (플라즈마 침질탄화처리시 처리시간이 화합물층의 특성에 미치는 영향)

  • 박율민;신평우;조효석;남기석;이구현
    • Journal of the Korean Vacuum Society
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    • v.9 no.4
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    • pp.436-441
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    • 2000
  • Plasma nitrocarburising is a thermochemical heat treatment, and can be used for plain carbon steels and low alloy steels to improve wear, corrosion and fatigue resistance. The process is performed on automotive parts, machinery parts and engineering tools. However, it is still facing problems in obtaining a mono $\varepsilon$ phased compound layer. Therefore, the aim of this research is to investigate the possibility of forming a mono $\varepsilon$ phased compound layer using a gas mixture of nitrogen and methane. It was found that high nitrogen contents were essential for the production of $\varepsilon$ phase compound layer and with increasing methane content in the gas mixture, $\varepsilon$ phase compound layer was favoured. In addition, when the methane content was further increased, cementite was observed in the compound layer. $\gamma$' phase was produced after 10 minutes treatment time and cementite was formed in the compound layer resulting in decreasing the thickness of the compound layer.

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Correlation between Microstructure and Mechanical Properties of Base Metal and HAZ of 500 MPa Steel Plates for Offshore Platforms (해양플랜트용 500 MPa급 후판강의 모재 및 HAZ의 미세조직과 기계적 특성의 상관관계)

  • Park, Jiwon;Cho, Sung Kyu;Cho, Young Wook;Shin, Gunchul;Kwon, Yongjai;Lee, Jung Gu;Shin, Sang Yong
    • Korean Journal of Materials Research
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    • v.30 no.3
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    • pp.123-130
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    • 2020
  • In this study, two types of thick steel plates are prepared by controlling carbon equivalent and nickel content, and their microstructures are analyzed. Tensile tests, Vickers hardness tests, and Charpy impact tests are conducted to investigate the correlation between microstructure and mechanical properties of the steels. The H steel, which has high carbon equivalent and nickel content, has lower volume fraction of granular bainite (GB) and smaller GB packet size than those of L steel, which has low carbon equivalent and nickel content. However, the volume fraction of secondary phases is higher in the H steel than in the L steel. As a result, the strength of the L steel is higher than that of the H steel, while the Charpy absorbed energy at -40 ℃ is higher than that of the L steel. The heat affected zone (HAZ) simulated H-H specimen has higher volume fraction of acicular ferrite (AF) and lower volume fraction of GB than the HAZ simulated L-H specimen. In addition, the grain size of AF and the packet sizes of GB and BF are smaller in the H-H specimen than in the L-H specimen. For this reason, the Charpy absorbed energy at -20 ℃ is higher for the H-H specimen than for the L-H specimen.

Effects of the Precipitation of Carbides and Nitrides on the Texture Structures in Extra Low Carbon Steel Sheets containing B, Nb and Ti(ll) (B, Nb및 Ti를 함유한 극저탄소강에서 탄화물 및 질화물의 석출이 집합조직에 미치는 영향(ll))

  • Lee, Jong-Mu;Yun, Guk-Han;Lee, Do-Hyeong
    • Korean Journal of Materials Research
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    • v.3 no.2
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    • pp.131-139
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    • 1993
  • Abstract Alloying elements such as AI, Ti, Nb and B in the extra low carbon AI-killed steel precipitate as nitrides or carbides and change the recrystallization texture structure of the steel during heattreatment with the result of strong effects on the deep drawability of the steel sheet. In this study the effects of fine precipitates such as nitrides and carbides on the texture of extra low carbon steels into which Ti, Nb, B, P, Si and Mn were added as alloying elements were investigated by means of TEM, SEM and optical microscopic analyses. Fine N$b_2$C and T$i_2$AIN precipitates are mainly observed in the steel containing both Nb and Ti, while fine AIN and coarse BN precipitates are observed in the Nb~containing steel and coarse T${i_4}{N_3}$ and ${N_10}{N_22}$/T$i_68$ precipitates are observed in the Ti-containing steel. The grain size of the Ti containing steel is larger than that of the Nb containing steel and that of the one containing both Nb and Ti.

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A Study on the Material Characteristics and the Welding Properties of 600MPa Grade Steel (SM 570 TMC) (600MPa급(SM 570 TMC) 강재의 소재 및 용접특성에 관한 연구)

  • Kim, Jong Rak;Kim, Sang Seup;Lee, Chul Ho;Lee, Eun Taik;Beak, Ki Youl
    • Journal of Korean Society of Steel Construction
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    • v.20 no.6
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    • pp.773-781
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    • 2008
  • As buildings are becoming taller and longer-spanned, the requirements of high-strength and reliable steels are becoming increasingly stringent. Structural steels, however, acquire significantly different mechanical properties when their strength becomes higher. In this study, the mechanical properties, welding characteristics, and conformities of the 600MPa-grade high-strength steel were tested. The 600MPa-grade steel plates exhibited stable criterion strengthvalues and showed low carbon equivalents (${\mathcal{Ceq}}$) and composition (${\mathcal{Pcm}}$) as well as excellent welding hardness. In the tensile strength test, all the specimens were found to have strengths of over 600MPa. In the Sharphy impact test, the impact-absorbed energy of the V-notch specimens was shown to be 47J at the KS limit. Moreover, the maximum hardness of the specimens in the weld-heat-affected zone at a normal temperature was the same as that before welding. Their weld metal properties, however, were found not to be as good as those of high-strength steel. As such, the details of high-strength steel must be determined.

Microstructural Changes during Tempering Treatment of Nitrogen-permeated STS 410 and 410L Martensitic Stainless Steels (질소침투 열처리한 STS 410 및 410L 마르텐사이트계 스테인리스강의 템퍼링에 의한 조직변화)

  • Lee, Hea Joeng;Kong, Jung Hyun;Lee, Hae Woo;Yu, Dea Kyung;Kang, Chang Yong;Sung, Jang Hyun
    • Journal of the Korean Society for Heat Treatment
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    • v.20 no.2
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    • pp.84-93
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    • 2007
  • Microstructural changes during tempering at the temperature range of $300^{\circ}C{\sim}700^{\circ}C$ for the nitrogen-permeated STS 410 and 410L martensitic stainless steels has been investigated. After nitrogen permeation at temperature between 1050 and $1150^{\circ}C$, the surface layer appeared fine $Cr_2N$ of square and rod types in the martensite matrices. Hardness of the nitrogen-permeated surface layer represented 680Hv and 625Hv, respectively, for 410 and 410L steels. It is considered that the fine homogeneously dispersive effect of precipitates by nitrogen caused the increased hardness. Due to the counter current effect of carbon from interior to surface during nitrogen diffusion from surface to interior, the 0.1%C alloyed 410 steel showed the low nitrogen content of 0.025% compared with 0.045% of 410L steel at the distance of $100{\mu}m$ from the surface. Tempering of nitrogen-alloyed 410 and 410L showed the maximum hardness at $450^{\circ}C$. This maximum hardness was considered to be the secondary hardening effect of very fine carbide and nitride. The decrease in hardness at $700^{\circ}C$ was the softening effect of the matrix due to the precipitation of many needle-shaped $Cr_2N$ for 410 steel and the precipitation of coarse nitride of $Cr_2N$ in line with the spherical precipitates with directionality for 410L steel. For 410 steel, the corrosion resistance of nitrogen permeated surface in the solution of 1 N $H_2SO_4$ were nearly unchanged, however the superior corrosion resistance was obtained for nitrogen permeated 410L steel compared to the solution annealed condition.

Influence of Graphite Epoxy Composite Material on the Electrochemical Galvanic Corrosion of Metals (금속재료의 전기화학적 갈바닉 부식에 미치는 GECM의 영향)

  • Yoo, Y.R.;Son, Y.I.;Shim, G.T.;Kwon, Y.H.;Kim, Y.S.
    • Corrosion Science and Technology
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    • v.8 no.1
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    • pp.27-39
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    • 2009
  • Non metallic composite materials, for example, GECM(graphite epoxy composite material) show high specific strength because of low density. These kinds of non metallic composite materials improved the structural effectiveness and operation economics. However, if these materials contacted several metals, corrosion can be arisen since non metallic composite materials have electrical conductivity. This paper dealt with galvanic corrosion between graphite epoxy composite material and several metals. Base on the electrochemical galvanic corrosion test between GECM and metals, corrosion current of carbon steel and aluminium increased with time but corrosion current of stainless steels and titanium decreased and galvanic potential increased. This behavior shows the galvanic corrosion depends upon the presence of passive film. Also, galvanic effect of GECM coupled with ferrous alloys and non-ferrous alloys was lower than that of 100% graphite, which is attributed to lower exposed area of graphite fiber in the GECM than apparent area of the GECM specimen used for the calculation of galvanic current in this work.

The Effects of Nb, V on the High Temperature Wear and Corrosion of the Overlaying Materials for Continuous Casting Rolls (연주롤용 육성용접 재료의 고온마모 및 부식특성에 미치는 Nb, V의 영향)

  • Kim, C.G.;Whang, D.S.;Yoon, J.H.;Kang, C.Y.;Kwak, H.H.
    • Journal of Power System Engineering
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    • v.8 no.3
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    • pp.30-35
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    • 2004
  • In the steel making industries, the continuous casting process has been applied to the number of company because of its economical benefit. Casting rolls are utilized for frictional drive and transport of solidifying slap. Dimensional tolerances, mechanical stability and surface condition of the cast roll can affect both the surface and internal quality of the product being cast. To overcome these problems, the industry is accelerating on the rate of technology improvements. Samples were overlaid on the S45C steel by submerged arc welding process. And the hardness, wear, electrochemical corrosion and oxidation tests were carried out. Test results were that all these materials were satisfying basic requirements of caster rolls. By these results, the addition of 0.1%Nb and 0.15%V increase mechanical properties and tempering resistance by its superior carbide forming characteristics in low carbon $12{\sim}13%Cr$ martensitic stainless steels.

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Behavior of Initiation and Propagation of Fatigue Crack under Periodic Overstressing (In the case of Fatigue Limit Stresses) (과대, 과소 응력하에서의 피로크랙 발생거동 (피로한도 응력을 중심으로))

  • 송남홍;원시태
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.15 no.6
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    • pp.1839-1851
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    • 1991
  • Fatigue crack behavior is studied through the two-level rotary bending test with the deep non-through radial holed notch specimens of low carbon steels(SM22C). The main factors investigated are the effects of the damage zone size around crack tip and phenomena of closing or opening of the crack tip. Obtained results are summarized as follows. Fatigue crack behavior in second level stressing slightly lower than fatigue limit is closely related to the size of damage zone produced by the first level stress higher than fatigue limit and to the phenomena of crack closing and opening for the second level stress. The non-propagating crack limit condition depends upon the crack length l$_{1}$ propagated under the first level stress and the magnitude of second level stress .sigma.$_{2}$ lower than the fatigue limit. The non-propagating crack limit condition is expressed by following eq. $\sigma_2^{6.1}{\times}l_{1}=7.35{\times}10^{6}[(kg_{f}mm^{6.1}(mm)]$