• Journal of Power System Engineering
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• v.13 no.6
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• pp.76-81
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• 2009

Thermal desorption systems are designed to remove organic compounds from solid matrices such as soils, sludges and filter cakes without thermally destroying them. It is a separation technology, not a destruction technology. Since it is a thermal process, there is a common belief that temperature is the only significant parameter to be monitored. While it is true that better removal efficiencies are usually achieved at higher temperatures, other factors must be considered. Since the process is governed by mass transfer, heating time and the amount of mixing are also key parameters in optimizing removal efficiency. Thermal desorption have been successfully used for just about every organic contaminant found to date. It has also been used to remove mercury. In the present study, the numerical simulation has been performed to investigate the characteristics of heat transfer of LTTD(low temperature thermal desorption). The commercial software, AMESIM was applied for analyzing the heat transfer process in the LTTD.

• Journal of Korean Society of Environmental Engineers
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• v.29 no.8
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• pp.956-960
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• 2007

The objective of this study is to remove BTEX(Benzene, Toluene, Ethylene, Xylene) and TPH(Total Petroleum Hydrocarbon) effectively by using method low thermal desorption. The thermal desorption is frequently selected because it can treat various contaminants effectively. The temperature and heating time are determined by TGA(Thermogravimetric analysis) curve. The experiment result from this research, removal rate of BTEX was up to 100% within 5 minutes and removal rates of TPH were more than 65% at $300^{\circ}C$ and 70% at $500^{\circ}C$ respectively. It was observed that there was a little change of removal rates of TPH.

• Journal of Soil and Groundwater Environment
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• v.20 no.5
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• pp.11-15
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• 2015

The three processes of 1) high- & low-temperature microwave heatings, 2) the soil washing, and 3) the thermal desorption processes in soil remediation are analysed on the treatment cost data for 2003-2012 years. The cost of microwave heating method with at temperature 500-700℃, for 30 minutes, and at 4-6 kW is approximately 10 $/ton (13,000 ₩) due to the deep through heating of micro-wave, the soil washing with chemicals is about 80 $/ton (85,000 ₩) due to the chemicals & duration, and the thermal desorption process is around 40 $/ton (41,000 ₩) from the less efficiency. Furthermore the sustainability has been assessed, and suggestions are made. 1) Green; the minimal environmental footprint, 2) Growth; the least cost, 3) Shared; the social & environmental justice, 4) Smart; the microwave characteristics of deep through irradiation & heating, and 5) Mutuality; the flexibility of the technology. More additives including water, the government support, and public relation are suggested realizing the microwave in this condition is not harmful to human beings.

• Transactions of the Korean hydrogen and new energy society
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• v.9 no.3
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• pp.111-118
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• 1998

The intrinsic degradation behavior of $(V_{0.53}Ti_{0.47})_{0.925}Fe_{0.075}$ alloy with BCC structure and the two plateau regions (the low and high plateau region) has been investigate during the temperature-induced hydrogen absorption-desorption cycling (thermal cycling). After 400 thermal cycles between room temperature and $600^{\circ}C$ under 10atm $H_2$, the total reversible hydrogen absorption capacity decreased by about 40%. From thermal desorption analysis it was found that the degradation behavior at each plateau region was different. In addition, XRD analysis showed that the crystal structure of the sample in de-hydrided state was changed from BCC to BCT after degradation, and that of the sample in hydrided state it was maintained as FCC although peaks were broadened after degradation. From the result of static isothermal hydrogenation treatment it were found that crystal structure change from BCC to BCT was caused by the thermal energy. TEM analysis showed that the peak broadening was due to the formation of an amorphous phase in FCC matrix.

• Journal of Korean Society for Atmospheric Environment
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• v.27 no.2
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• pp.191-200
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• 2011

A way to adsorptively remove indoor carbon dioxide at relatively lower concentration under ambient temperature was studied. A small lab-scale carbon dioxide adsorption and desorption reactors were prepared, and 5A and 13X zeolites were packed in this reactors to investigate their adsorption and desorption characteristics. The inflow carbon dioxide concentration was controlled to 5,000 ppm, relatively higher concentration found in indoor spaces with air quality problems, by diluting carbon dioxide with nitrogen gas. The flow rate was varied as 1~5 L/min, and the carbon dioxide concentration after this reactor was constantly monitored to examine the adsorption characteristics. It was found that 5A adsorbed more carbon dioxide than 13X. A lab-scale carbon dioxide desorption reactor was also prepared to investigate the desorption characteristics of zeolites, which is essential for the regeneration of used zeolites. The desorption temperature was varied as $25{\sim}200^{\circ}C$, and the desorption pressure was varied as 0.1~1.0 bar. Carbon dioxide desorbed better at higher temperature, and lower pressure. 5A could be regenerated more than three times by thermal desorption at $180^{\circ}C$. It is required to modify zeolites for higher adsorption and better regeneration performances.

• Applied Chemistry for Engineering
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• v.28 no.3
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• pp.332-338
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• 2017

The objective of this work was to study the low temperature vacuum adsorption technology applicable to small and medium scale painting plants, which is the main emission source of volatile organic compounds. The low-temperature vacuum swing adsorption (VSA) technology is the way that the adsorbates are removed by reducing pressure at low temperature ($60{\sim}90^{\circ}C$) to compensate disadvantages of the existing thermal swing adsorption (TSA) technology. Commercial activated carbon was used and the absorption and desorption characteristics of toluene, a representative VOCs, were tested on a lab scale. Also based on the lab scale experimental results, a $30m^3min^{-1}$ VSA system was designed and applied to the actual painting factory to assess the applicability of the VSA system in the field. As a result of lab scale experiments, a 2 mm pellet type activated carbon showed higher toluene adsorption capacity than that of using 4 mm pellet type, and was used in a practical scale VSA system. Optimum conditions for desorption experiments were $80{\sim}90^{\circ}C$ and 100 torr. In the practical scale system, the adsorption/desorption cycles were repeated 95 times. As a result, VOCs discharged from the painting factory can be effectively removed upto 98% or more even after repeated adsorption/desorption cycles when using VSA technology indicating potential field applicabilities.

• The Bulletin of The Korean Astronomical Society
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• v.44 no.1
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• pp.70.4-70.4
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• 2019

Complex organic molecules (COMs) are increasingly observed in the environs of young stellar objects (YSOs), including hot cores/corinos around high-mass/low-mass protostars and protoplanetary disks. It is widely believed that COMs are first formed in the ice mantle of dust grains and subsequently released to the gas by thermal sublimation at high temperatures (T>100 K) in strong stellar radiation fields. In this paper, we report a new mechanism that can desorb COMs from icy grain mantles at low temperatures (T<100K), which is termed rotational desorption. The rotational desorption process of COMs comprises two stages: (1) ice mantles on suprathermally rotating grains spun-up by radiative torques (RATs) are first disrupted into small fragments by centrifugal stress, and (2) COMs and water ice then evaporate rapidly from the tiny fragments (i.e., radius a <1nm) due to thermal spikes or enhanced thermal sublimation due to increased grain temperature for larger fragments (a>1 nm). We discuss the implications of rotational desorption for releasing COMs and water ice in the inner region of protostellar envelopes (hot cores and corinos), photodissociation regions, and protoplanetary disks (PPDs). In shocked regions of stellar outflows, we find that nanoparticles can be spun-up to suprathermal rotation due to supersonic drift of neutral gas, such that centrifugal force can be sufficient to directly eject some molecules from the grain surface, provided that nanoparticles are made of strong material. Finally, we find that large aggregates (a~ 1-100 micron) exposed to strong stellar radiations can be disrupted into individual icy grains via RAdiative Torque Disruption (RATD) mechanism, which is followed by rotational desorption of ice mantles and evaporation of COMs. In the RATD picture, we expect some correlation between the enhancement of COMs and the depletion of large dust grains in not very dense regions of YSOs.

• Journal of Soil and Groundwater Environment
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• v.17 no.3
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• pp.76-85
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• 2012

Geochemical and ecological properties of remediated soil and gas exhausted from a low-temperature thermal desorption (LTTD) process were analyzed to assess the environmental impact of LTTD treatment. Soil characteristics were examined with regard to the chemical (EC, CEC, and organic matter) and the ecological (dehydrogenase activity, germination rate of Brassica juncea, and growth of Eisenia andrei) properties. The exhaust gases were analyzed based on the Air Quality Act in Korea as well as volatile organic compounds (VOCs) and mixed odor. Level of organic Organic matter of the soil treated by LTTD process was slightly decreased compared to that of the original soil because the heating temperature ($200^{\circ}C$) and retention time (less than 15 minutes) were neither high nor long enough for the oxidation of organic matter. The LTTD process results in reducing TPH of the contaminated soil from $5,133{\pm}508$ mg/kg to $272{\pm}107$ mg/kg while preserving soil properties. Analysis results of the exhaust gases from the LTTD process satisfied discharge standard of Air Quality Law in Korea. Concentration of VOCs including acetaldehyde, propionaldehyde, butyraldehyde and valeraldehyde in circulation gas volatilized from contaminated soil were effectively reduced in the regenerative thermal oxidizer and all satisfied the legal standards. Showing ecologically improved properties of contaminated soil after LTTD process and environmentally tolerable impact of the exhaust gas, LTTD treatment of TPH-contaminated soil is an environmentally acceptable technology.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 2002.09a
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• pp.44-52
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• 2002

Low temperature thermal desorption (LTTD) has become one of the cornerstone technologies used for the treatment of contaminated soils and sediments in the United States. LTTD technology was first used in the mid-1980s for soil treatment on sites managed under the Comprehensive Environmental Respones, Compensation and Liability Act (CERCLA) or Superfund. Implementation was facilitated by CERCLA regulations that require only that spplicable regulations shall be met thus avoiding the need for protracted and expensive permit applications for thermal treatment equipment. The initial equipment designs used typically came from technology transfer sources. Asphalt manufacturing plants were converted to direct-fired LTTD systems, and conventional calciners were adapted for use as indirect-fired LTTD systems. Other innovative designs included hot sand recycle technology (initially developed for synfuels production from tar sand and oil shale), recycle sweep gas, travelling belts and batch-charged vacuum chambers, among others. These systems were used to treat soil contaminated with total petroleum hydrocarbons (TPH), polycyclic aromatic hydrocarbons (PAHs), pesticides, polychlorinated biphenyls (PCBs) and dioxin with varying degrees of success. Ultimately, performance and cost considerations established the suite of systems that are used for LTTD soil treatment applications today. This paper briefly reviews the develpoment of LTTD systems and summarizes the design, performance and cost characteristics of the equipment in use today. Designs reviewed include continuous feed direct-fired and indirect-fired equipment, batch feed systems and in-situ equipment. Performance is compared in terms of before-and-after contaminant levels in the soil and permissible emissions levels in the stack gas vented to the atmosphere. The review of air emissions standards includes a review of regulations in the U.S. and the European Union (EU). Key cost centers for the mobilization and operation of LTTD equipment are identified and compared for the different types of LTTD systems in use today. A work chart is provided for the selection of the optmum LTTD system for site-specific applications. LTTD technology continues to be a cornerstone technology for soil treatment in the U.S. and elsewhere. Examples of leading-edge LTTD technologies developed in the U.S. that are now being delivered locally in global projects are described.

• Journal of Soil and Groundwater Environment
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• v.14 no.5
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• pp.62-70
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• 2009

A field soil highly contaminated with petroleum hydrocarbons (JP-8 and diesel fuels) was employed for its remediation by a lab-scale thermal desorption process. The soil was collected in the vicinity of an underground storage tank in a closed military base and its contamination level was as high as 4,476 ppm as total petroleum hydrocarbon (TPH). A lab scale directly-heated low temperature thermal desorption (LTTD) system of 10-L capacity was developed and operated for the thermal treatment of TPH contaminated soils in this study. The desired operation temperature was found to be approximately $200-300^{\circ}C$ from the thermal gravimetric analysis of the contaminated field soils. The removal efficiencies higher than 90% were achieved by the LTTD treatment at $200^{\circ}C$ for 10 min as well as at $300^{\circ}C$ for 5 min. As the water content in the soils increased and therefore they were likely to be present as lumps, the removal efficiency noticeably decreased, indicating that a pre-treatment such as field drying should be required. The analysis of physical and chemical properties of soils before and after the LTTD treatment demonstrated that no significant changes occurred during the thermal treatment, supporting no needs for additional post-treatments for the soils treated by LTTD. The results presented in this study are expected to provide useful information for the field application and verification of LTTD for the highly contaminated geo-environment.