• 제목/요약/키워드: Low Surface Tension

검색결과 201건 처리시간 0.023초

전조 나선핀 튜브의 외부핀 형상 변화에 의한 열전달 향상에 관한 연구 (A Study on the Heat Transfer Improvement of Integral-Fin Tubes by External Fin Effect)

  • 한규일;조동현
    • 수산해양기술연구
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    • 제30권1호
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    • pp.33-44
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    • 1994
  • This work studies for boiling and condensation heat transfer performance of trapezoidally shaped integral-fin tubes having fin densities from 748fpm to 1654fpm. For comparison, tests are made using a plain tube having the same inside and outside diameter as that of the root of fins of finned tubes. Hahne's theoretical model and Webb's theoretical model are used to predict the R-11 boiling heat transfer coefficient and condensing heat transfer coefficient respectively for plain tube and all integral-fin tubes. Experiments are carried out using R-11 as working fluid. This work is limited to film-wise condensation and pool boiling on the outside surface of plain tube and 4 low integral-fin tubes. In case of condensation, the refrigerant condenses at saturation state of 32$^{\circ}C$ on the outside tube surface cooled by coolant and in case of boiling. the refrigerant evaporates at saturation state of 1bar on the outside tube surface. The amount of non-con-densable gases in the test loop is reduced to a negligible value by repeated purging. The actual boiling and condensing processes occur on the outside tube surfaces. Hence the nature of this surface geometry affects the heat transfer performances of condenser and evaporator in refrigerating system. The condensation heat transfer coefficient of integral-fin tube is enhanced by both extended tube surface area and surface tension. The ratio of the condensation heat transfer coefficients of finned to plain tubes is greater than that of surface area of finned to plain tubes, while ratio of the boiling heat transfer coefficient of finned to plain tubes shows reverse result. As a result, low integral-fin tube can be used in condenser more effectively than used in evaporator.

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미분무수 첨가제의 소화효과 비교 (Comparison of Fire Extinguishing Effects for Water Mist Additives)

  • 김승일;신창섭
    • 한국안전학회지
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    • 제28권6호
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    • pp.23-28
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    • 2013
  • In order to improve extinguishing performance of water mist, many studies of additives have been conducted. In this study, viscosity agent which has the ability to improve extinguishing performance by adhering to the surface on fire was used and fluorine-free surfactant was also added to water to enhance water's wetting ability. This study aimed to verify optimal concentration of extinguishing of additives according to fire source and extinguishing performance by comparison with pure water. In case of wood crib fire, the results show that flame suppression and extinguishing time of sodium alginate 0.4 wt.% are 3.4 times and 2.2 times shorter than those of pure water in 0.2 MPa respectively. It seems that large amount of water adhere to surface on fire, thus cooling effect on surface was enhanced. Also water consumption of sodium alginate 0.4wt.% is up to 65% lower than that of pure water. In case of heptane fire, extinguishing time of cocobetaine 0.1 wt.% is 9.7 times shorter than that of pure water in 0.2 MPa. It is thought that because cocobetaine can block oxygen and suppress oil mist by making emulsion film on fire surface due to a low surface tension. On the other hand, water consumption of cocobetaine 0.1 wt.% is 92% lower than that of pure water.

저분자 유기실리콘 계면활성제의 개발 동향 (제2보) (Trend on Development of Low Molecular Weight Organosilicone Surfactants (Part II))

  • 랑문정
    • 한국응용과학기술학회지
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    • 제34권3호
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    • pp.461-477
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    • 2017
  • 소수성 유기실리콘 그룹에 친수성 극성 그룹이 결합되어 있는 유기실리콘 계면활성제는 유기실리콘의 독특한 특성으로 인하여 낮은 계면장력, 윤활성, 퍼짐성, 발수성, 열 안정성, 화학적 안정성 때문에 폴리우레탄 폼, 건설재료, 화장품, 페인트잉크, 농약 등 많은 산업분야에 사용되고 있다. 특히 소수기로 저분자 실록산을 가지고 있는 유기실리콘 계면활성제는 낮은 표면장력과 우수한 습윤/퍼짐성 때문에 super wetter/super spreader로서 활용되고 있으나 가수분해가 되는 취약한 단점도 가지고 있다. 저분자 실록산 계면활성제의 기능향상과 단점개선 등 응용분야에서의 요구사항을 반영하기 위하여 다양한 화학구조를 가진 저분자 실록산 계면활성제들이 개발되고 있다. 본 총설에서는 반응성 테트라실록산과 다이실록산의 합성방법, 반응성 테트라실록산 또는 다이실록산을 친수성 그룹과 결합시키는 규소수소화반응 같은 주요 합성방법, 그리고 폴리에테르, 카보하이드레이트, 제미니, 볼라 타입 등 구조를 가지는 테트라실록산 계면활성제와 다이실록산 계면활성제들의 합성방법을 논의한다.

미생물(微生物) 계면활성제(界面活性劑)에 관한 연구(硏究)(제(第)2보(報));지방분해(脂肪分解) 효소(酵素)에 의하여 합성(合成)된 당지질(糖脂質) 계면활성(界面活性) (Studies on the Biosurfactant(2);Surface Activity of glicolipid Synthesized by Porcine Pancreatic Lipase)

  • 남기대;최재효;이선주;김상춘
    • 한국응용과학기술학회지
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    • 제8권1호
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    • pp.55-58
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    • 1991
  • Biosurfactant have a low toxicity, good biodegradable, various structure. It can be used for a broad range of purposes in a large variety of different applications. Sorbitol mono alkyl ester synthesized by the Porcine Pancreatic lipase catalyzes transesterification reaction between a sugar alcohol and plant oils. We are examined the surface tension, emusion stability and critical micelle concentration were evaluated. Consequently It has a good properties of biosurfactant.

Microfluidic Components and Bio-reactors for Miniaturized Bio-chip Applications

  • Euisik Yoon;Yun, Kwang-Seok
    • Biotechnology and Bioprocess Engineering:BBE
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    • 제9권2호
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    • pp.86-92
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    • 2004
  • In this paper miniaturized disposable micro/nanofluidic components applicable to bio chip, chemical analyzer and biomedical monitoring system, such as blood analysis, micro dosing system and cell experiment, etc are reported. This system includes various microfluidic components including a micropump, micromixer, DNA purification chip and single-cell assay chip. For low voltage and low power operation, a surface tension-driven micropump is presented, as well as a micromixer, which was implemented using MEMS technology, for efficient liquid mixing is also introduced. As bio-reactors, DNA purification and single-cell assay devices, for the extraction of pure DNA from liquid mixture or blood and for cellular engineering or high-throughput screening, respectively, are presented.

미세버블 디젤 연료의 분사율과 미시적 분무특성에 대한 연구 (Investigation on Injection Rate and Microscopic Spray Characteristics of Fine Bubble Diesel Fuel)

  • 진해론;이승우;김기현
    • 한국분무공학회지
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    • 제25권1호
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    • pp.15-20
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    • 2020
  • This study aims to investigate injection rate and microscopic spray characteristics of diesel fuel containing fine air bubble (FBD). fine bubble was generated by cavitation theory using bubble generator. Fuel spray was injected into constant volume chamber and visualized by high speed camera. The injection rate data was acquired with bosch tube method. Injection rate of finebubble diesel was very similar with that of diesel. It showed slightly faster injection start by 5 ㎲ attributed to the low viscosity characteristics. In microscopic spray visualization, fine bubble diesel spray showed unsymmetric spray shape compared with diesel spray. It also showed very vigorous spray atomization performance during initial spray development. Improved atomization was also attributed to the low viscosity and surface tension of finebubble diesel fuel.

Manufacturing Polymer/clay Nanocomposites Using a Supercritical Fluid Process

  • Jung, Hyun-Taek;Yoon, Ho-Gyu;Lim, Soon-Ho
    • International Journal of Precision Engineering and Manufacturing
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    • 제9권4호
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    • pp.63-65
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    • 2008
  • The increased interest in reducing the environmental effects caused by releasing organic compounds and aqueous waste has motivated the development of polymeric materials in supercritical fluids. Recently, supercritical fluids have been used in material synthesis and processing because of their special properties, such as high diffusivity, low viscosity, and low surface tension. Supercritical carbon dioxide is the most attractive because it is non-toxic, non-flammable, and has moderate critical temperature and critical pressure values. Supercritical carbon dioxide can also swell most polymers. In this study, we prepared polymer/clay nanocomposites using supercritical fluids. Cloisites 10A, 15A, 25A, and 30B used in this study are montmorillonites modified with a quaternary ammonium salt. The nanocomposites of polymer/clay were characterized by X-ray diffraction, thermogravimetric analysis, and differential scanning calorimetry.

아미노 변성 폴리실록산의 유화 특성 (Characterization of Emulsion Properties for Modified Amino Polysiloxanes)

  • 하윤식;서무룡;이정경;박경일;장윤호
    • 한국환경과학회지
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    • 제8권1호
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    • pp.61-67
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    • 1999
  • Silicone oil has organic and inorganic properties, and its skeleton is polysiloxane bonding that silicon is bonded hydrogen or organic group. Silicone compounds are very smooth and lubricant properties by low surface tension, low temperature dependence, and nonadhesive properties. Because of these properties, silicone compounds are used as many parts of chemicals, softener, smooth and libricant agents, water-repellent agent, and defoaming agent, etc. Emulsion was prepared with the inversion emulsification method which adopted the agent-in-oil method dissolving the polyoxyethylene(7) tridecyl ether(HLB 12.2) into methoxy terminated poly(dimethyl-co-methyl amino) siloxane and hydroxy terminated poly(dimethyl-co-methyl amino) siloxane in water. At this time, processed emulsion was almost microemulsion. When ratio of emulsifier increases, emulsion is stable bacuause microemulsion is solubilized by emulsion drop size and zeta-potential are decreased. But, when amount of electrolyte is increase, emulsion became unstable because emulsion drop size is increased.

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Biosurfactant as a microbial pesticide

  • Lee, Baek-Seok;Choi, Sung-Won;Choi, Ki-Hyun;Lee, Jae-Ho;Kim, Eun-Ki
    • 한국생물공학회:학술대회논문집
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    • 한국생물공학회 2003년도 생물공학의 동향(XII)
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    • pp.40-44
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    • 2003
  • Soil-borne infectious disease including Pythium aphanidermatum and Rhizoctonia solani causes severe damage to plants, such as cucumber. This soil-borne infectious disease was not controlled effectively by chemical pesticide. Since these diseases spread through the soil, chemical agents are usually ineffective. Instead, biological control, including antagonistic microbe can be used as a preferred control method. An efficient method was developed to select an antagonistic strain to be used as a biological control agent strain. In this new method, surface tension reduction potential of an isolate was included in the ‘decision factor’ in addition to the other factors, such as growth rate, and pathogen inhibition rate. Considering these 3 decision factors by a statistical method, an isolate from soil was selected and was identified as Bacillus sp. GB16. In the pot test, this strain showed the best performance among the isolated strains. The lowest disease incidence rate and fastest seed growth was observed when Bacillus sp. GB16 was used. Therefore this strain was considered as plant growth promoting rhizobacteria (PGPR). The action of surface tension reducing component was deduced as the enhancement of wetting, spreading, and residing of antagonistic strain in the rhizosphere. This result showed that new selection method was significantly effective in selecting the best antagonistic strain for biological control of soil-borne infectious plant pathogen. The antifungal substances against P. aphanidermatum and R. solani were partially purified from the culture filtrates of Bacillus sp. GB16. In this study, lipopeptide possessing antifungal activity was isolated from Bacillus sp. GB16 cultures by various purification procedures and was identified as a surfactin-like lipopeptide based on the Fourier transform infrared spectroscopy (FT-IR), nuclear magnetic resonance (NMR), high performance liquid chromatography mass spectroscopy (HPLC-MS), and quadrupole time-of-flight (Q-TOF) ESI-MS/MS data. The lipopeptide, named GB16-BS, completely inhibited the growth of Pythium aphanidermatum, Rhizoctonia solani, Penicillium sp., and Botrytis cineria at concentrations of 10 and 50 mg/L, respectively. A novel method to prevent the foaming and to provide oxygen was developed. During the production of surface active agent, such as lipopeptide (surfactin), large amount of foam was produced by aeration. This resulted in the carryover of cells to the outside of the fermentor, which leads to the significant loss of cells. Instead of using cell-toxic antifoaming agents, low amount of hydrogen peroxide was added. Catalase produced by cells converted hydrogen peroxide into oxygen and water. Also addition of corn oil as an oxygen vector as well as antifoaming agent was attempted. In addition, Ca-stearate, a metal soap, was added to enhance the antifoam activity of com oil. These methods could prevent the foaming significantly and maintained high dissolved oxygen in spite of lower aeration and agitation. Using these methods, high cell density, could be achieved with increased lipopeptide productivity. In conclusion to produce an effective biological control agent for soil-borne infectious disease, following strategies were attempted i) effective screening of antagonist by including surface tension as an important decision factor ii) identification of antifungal compound produced from the isolated strain iii) novel oxygenation by $H_2O_2-catalase$ with vegetable oil for antifungal lipopeptide production.

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Simulations of fiber spinning and film blowing based on a molecular/continuum model for flow-induced crystallization

  • McHugh, Anthony J.;Doufas, A.K.
    • Korea-Australia Rheology Journal
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    • 제13권1호
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    • pp.1-12
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    • 2001
  • This paper describes the application of our recently developed two-phase model for flow-induced crystallization (FIC) to the simulation of fiber spinning and film blowing. 1-D and 2-D simulations of fiber spinning include the combined effects of (FIC), viscoelasticity, filament cooling, air drag, inertia, surface tension and gravity and the process dynamics are modeled from the spinneret to the take-up roll device (below the freeze point). 1-D model fits and predictions are in very good quantitative agreement with high- and low-speed spinline data for both nylon and PET systems. Necking and the associated extensional softening are also predicted. Consistent with experimental observations, the 2-D model also predicts a skin-core structure at low and intermediate spin speeds, with the stress, chain extension and crystallinity being highest at the surface. Film blowing is simulated using a "quasi-cylindrical" approximation for the momentum equations, and simulations include the combined effects of flow-induced crystallization, viscoelasticity, and bubble cooling. The effects of inflation pressure, melt extrusion temperature and take-up ratio on the bubble shape are predicted to be in agreement with experimental observations, and the location of the frost line is predicted naturally as a consequence of flow-induced crystallization. An important feature of our FIC model is the ability to predict stresses at the freeze point in fiber spinning and the frost line in film blowing, both of which are related to the physical and mechanical properties of the final product.l product.

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