• Transactions of the Korean Society of Mechanical Engineers B
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• v.35 no.2
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• pp.137-143
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• 2011

This paper describes the effects of biodiesel blended fuel on the engine combustion and emission characteristics in a four cylinder CRDI(Common-rail direct injection) diesel engine. In this work, the biodiesel-diesel blended fuel(20% of biodiesel and 80% of ULSD(ultra low sulfur diesel) by volume ratio, BD20) and ULSD fuel are used under the various injection pressures and engine speeds. The experimental results of BD20 and ULSD fuel show that NOx emissions were increased and soot emissions were decreased with the increase of injection pressure. In particular, NOx emissions were slightly increased for the BD20 fuel, however, soot emissions were significantly reduced compared to the ULSD fuel. When the engine speed is increased from 1000rpm to 2000rpm, NOx emissions are decreased at all tested conditions, and soot emissions are largely increased at lower injection pressure.

• Applied Chemistry for Engineering
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• v.19 no.6
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• pp.617-623
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• 2008

GTL (gas-to-liquid) fuel produced by the Fischer-Tropsch reaction of carbon monoxide (CO) and hydrogen ($H_2$) is expected to be one of the environmental friendly biomass based alternatives and blended to petrodiesel. In this study, the characteristic of the fuel was analyzed by its concentration differences after blending petrodiesel in domestic market with different amounts of GTL fuel which produced from Shell. Gas chromatography shows that GTL fuel consists of longer paraffin chain than common diesel. GTL fuel showed a high flash point, distillation, kinematic viscosity, and derived cetane number. In addition, GTL fuel showed lower lubricity due to low sulfur content.

• Journal of Soil and Groundwater Environment
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• v.20 no.3
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• pp.1-6
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• 2015

The rapid industrial development is facing problem due to energy depletion in Korea. So that, it can be necessary to develop alternative energy sources. Alternative energy like biofuels can be produced by using waste fuel, which is ecofriendly. As we know, the organic waste was banned to dump in landfill and ocean dumping. The most practicable method usually used to reduce organic waste is getting feedstuff or composting, considering the discharge characteristics of agricultural by-products waste treatment were selected. In this study, bio-coal was made using agriculture by product. Biocoal was prepared by adding 50 g of uniformly mixture into reactor and was carbonized at low temperatures 210, 220, and 230℃. The time of reaction was 1, 2 and 3 hours. Bio-coal approximately was similar to the standard of solid fuels. Other characteristics of fuel were also studied. The experiments which were analyzed were moisture content and calorific value, ash, chlorine, sulfur and heavy metals analysis as mercury, cadmium, lead, arsenic, and chromium. As a result, bio-coal 220℃, 2 hours was the optimal conditions while heating.

• Journal of Hydrogen and New Energy
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• v.35 no.4
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• pp.401-409
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• 2024

The maritime industry, responsible for 80% of global freight transport, heavily pollutes the environment through traditional fossil fuels. The International Maritime Organization aims to reduce sulfur and greenhouse gas emissions, but faces technical and financial challenges. Hydrogen fuel cells present a promising alternative with high efficiency and low emissions. This study examines the legal and regulatory frameworks needed for hydrogen bunkering across land, port, and sea. Key legislation includes the High-pressure Gas Safety Control Act, Hydrogen Economy Promotion and Hydrogen Safety Management Act, Harbor Act, Harbor Authority Act, Marine Transportation Act, and Harbor Transport Business Act. The study identifies overlapping regulations and proposes integrated solutions. The findings underscore the necessity of strict safety standards and legislative amendments to recognize hydrogen as a ship fuel. Establishing a comprehensive legal framework is essential for safe and efficient hydrogen bunkering. Continuous updates through international cooperation and standardized regulations are crucial for adopting hydrogen fuel cells, ensuring a sustainable and environmentally friendly maritime industry.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.15 no.6
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• pp.3383-3388
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• 2014

An experimental study was performed to compare the characteristics of the combustion pressure and exhaust emissions in the case of using pure diesel when the EGR rate was changed in a CRDI 4-cylinder diesel engine with those using biodiesel blended and pure diesel fuel. In this study, the EGR rate variation were conducted at an engine speed of 2000rpm with fuel with a biodiesel blended rate of 20%. The combustion pressure of the biodiesel blended rate 20% and pure diesel fuels decreased with increasing EGR rate. The IMEP of biodiesel was higher than that of ULSD (Ultra low sulfur diesel). The emission results showed that the NOx emission of biodiesel blended fuel with increasing EGR rate was higher than that of ULSD. In addition, the NOx emission of biodiesel blended and diesel fuel decreased with increasing EGR rate. The CO and soot, $CO_2$ emissions increased with increasing EGR rate, and the CO and soot emissions from the biodiesel blended fuel were lower than that of ULSD but the $CO_2$ emissions were higher.

• Proceedings of the Korea Society for Energy Engineering kosee Conference
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• 2002.11a
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• pp.171-184
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• 2002

Approx. 200,000 bpd vacuum residue oil is produced from oil refineries in Korea. These are supplying to use asphalt, high sulfur fuel oil, and upgrading at the residue hydro-desulfurization unit. Vacuum residue oil has high energy content, however high sulfur content and high concentration of heavy metals represent improper low grade fuel. To meet growing demand for effective utilization of vacuum residue oil from refineries, recently some of the oil refinery industries in Korea, such as SK oil refinery and LG Caltex refinery, have already proceeded feasibility study to construct 435-500 MWe IGCC power plant and hydrogen production facilities. Recently, KIER(Korea Institute of Energy Research) are studing on the Vacuum Residue gasification process using an oxygen-blown entrained-flow gasifier. The experiment runs were evaluated under the reaction temperature : 1,100~1,25$0^{\circ}C$, reaction pressure : 1~6kg/$\textrm{cm}^2$G, oxygen/V.R ratio : 0.8~0.9 and steam/V.R ratio : 0.4-0.5. Experimental results show the syngas composition(CO+H$_2$) : 85~93%, syngas flow rate : 50~110Mm$^3$/hr, heating value : 2,300~3,000 ㎉/Nm$^3$, carbon conversion : 65~92, cold gas efficiency : 60~70%. Also equilibrium modeling was used to predict the vacuum residue gasification process and the predicted values were compared reasonably well with experimental data.

• Journal of Energy Engineering
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• v.12 no.1
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• pp.49-57
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• 2003

Approx. 200.000 bpd vacuum residue oil is produced from oil refineries in Korea, and is supplied to use asphalt, high sulfur fuel oil and for upgrading at the residue hydro-desulfurization unit. Vacuum residue oil has high energy content, however its high sulfur content and high concentration of heavy metals represent improper low grade fuel. To meet growing demand for effective utilization of vacuum residue oil from refineries, recently some of the oil refinery industries in Korea, such as SK oil refinery and LG Caltex refinery, have already proceeded feasibility study to construct 435~500 MWe IGCC power plant and hydrogen production facilities. Recently, KIER (Korea Institute of Energy Research) are studying on the Vacuum Residue gasification process using an oxygen-blown entrained-flow gasifier. The experiment runs were evaluated under the reaction temperature: 1.100~l,25$0^{\circ}C$, reaction pressure: 1~6 kg/$\textrm{cm}^2$G, oxygen/V.R ratio: 0.8~0.9 and steam/V.R ratio: 0.4~0.5. Experimental results show the syngas composition (CO+H$_2$): 85~93%, syngas flow rate: 50~l10 Nm$^3$/hr, heating value: 2,300~3,000 k㎈/Nm$^3$, carbon conversion: 65~92, cold gas efficiency: 60~70%. Also equilibrium modeling was used to predict the vacuum residue gasification process and the predicted values were compared reasonably well with experimental data.

• Journal of the Korean Society for Marine Environment & Energy
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• v.11 no.4
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• pp.221-226
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• 2008

Air pollution associated with the SOx emission from the shipboard propulsion and generation engines is becoming one of the major environmental concerns these days. Lead by the international organizations including IMO and European Union, a significantly strengthened air pollution related regulations have been introduced and they are becoming in practice as scheduled. Such rules are basically giving the guidelines for permissible SOx emission which can be only met by using high quality fuel oils with less sulfur content or operating scrubbing systems aiming at reducing SOx at the engine exhaust. Since both countermeasures can lead to the cost increase in ship building and operation, Korean shipbuilding industries, leading the world's market, need to be well aware of the ever changing regulations and be prepared with proper solutions. Here, we briefly summarize such latest rules and regulations on the air pollution at sea, and review some technical issues on the scrubbing systems available with some suggestions.

• Journal of Environmental Science International
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• v.13 no.4
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• pp.339-347
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• 2004

This paper asks the question: what choice of environmental policy instruments is efficient to reduce sulfur dioxide from stationary sources\ulcorner: In Korea, command and control has been a common way of controlling $SO_2-emissions.$ When compared to the non-incentive environmental policy instrument such as command and control, economic incentive environmental policy instrument has been the advantage of making polluter himself flexibly deals with in marginal abatement cost to develop environmental technology in the long view. Therefore, the application possibility of the incentive environmental policy instrument was studied in this research to realize the countermeasure for controlling of $SO_2-emissions.$ As a result, enforcement of the countermeasure such as flue gas desulfurizer by command and control would be suitable because power generation is performed by the public or for the public in source of air pollution and thus, economic principle is not applied to the polluter. In the source of industrial pollution, enforcement of fuel tax is found to be suitable for the countermeasure for the use of low sulfur oil in terms of the flexibility of demand for the price in the long tenn. For the permissible air pollution standards applicable to all air pollutant emitting facilities, enforcement of incentive environmental policy such as bubble, off-set, banking policy or tradeable emission penn its would be ideal in long terms according to the regional characteristics and the number and scale of air pollutant emitting facilities.

• Korean Chemical Engineering Research
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• v.61 no.2
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• pp.226-233
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• 2023

To create an environmentally sustainable fuel with a low sulfur concentration, requires alternative sulfur removal methods. During the course of this study, a high surface gamma alumina-supported ZnO nanocatalyst with a ZnO/-Al₂O₃ ratio of 12% was developed and tested for its ability to improve the activity of the oxidative desulfurization (ODS) process for the desulfurization of kerosene fuel. Scanning electron microscopy (SEM) and Brunauer-Emmett-Teller (BET) were used to characterize the produced nanocatalyst. In a digital batch baffled reactor (20~80 min), the effectiveness of the synthesized nanocatalyst was tested at different initial concentrations of dibenzothiophene (DBT) of 300~600 ppm, oxidation temperatures (25~70 ℃), and oxidation periods (0.5, 1, and 2 hours). The baffles included in the digital baffled batch reactor resist the swirling of the reaction mixture, thus facilitating mixing. The ODS procedure yielded the maximum DBT conversion (95.5%) at 70 ℃ with an 80-minute reaction time and an initial DBT level of 600 ppm. The most precise values of kinetic variables were subsequently determined using a mathematical modelling procedure for the ODS procedure. The average absolute error of the simulation findings was less than 5%, demonstrating a good degree of agreement with the experimental results acquired from all runs. The optimization of the operating conditions revealed that 99.1% of the DBT can be removed in 140 minutes.