• Title/Summary/Keyword: Low O/F Ratio

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Autogenous Shrinkage of High-Performance Concrete Containing Mineral Admixture (광물질 혼화재를 함유한 고성능 콘크리트의 자기수축)

  • Lee, Chang-Soo;Park, Jong-Hyok;Kim, Yong-Hyok;Kim, Young-Ook
    • Journal of the Korean Society of Hazard Mitigation
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    • v.7 no.3
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    • pp.19-31
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    • 2007
  • Humidity and strain were estimated for understanding the relation between humidity change by self-desiccation and shrinkage in high-performance concrete with low water binder ratio and containing fly ash and blast furnace slag. Internal humidity change and shrinkage strain were about 10%, 10%, 7%, 11%, 11% and $320{\times}10^{-6}$, $270{\times}10^{-6}$, $231{\times}10^{-6}$, $371{\times}10^{-6}$, $350{\times}10^{-6}$ respectively on OPC30, O30F10, O30F20, O30G40, O30G50 and from the results, fly ash made humidity change and strain decrease but slag increase comparing with ordinary portland cement. Considering only relation internal humidity and shrinkage by self-desiccation, humidity change and shrinkage represented the strong linear relation regardless of mineral admixture. For specifying the relation on internal humidity change and autogenous shrinkage strain, shrinkage model was established which is driven by capillary pressure in pore water and surface energy in hydrates on the assumption of a single network and extended meniscus in pore system of concrete. This model and experimental results had a similar tendency so it would be concluded that the internal humidity change by self-desiccation in HPC originated in small pores less than 20nm, therefore controlling plan on autogenous shrinkage might be focused on surface tension of water and degree of saturation in small pore.

UY Ursae Majoris: An A-Subtype W UMa System with a Very Large Fill-Out Factor and an Extreme Mass Ratio

  • Kim, Chun-Hwey;Song, Mi-Hwa;Park, Jang-Ho;Jeong, Min-Ji;Kim, Hye-Young;Han, Cheongho
    • Journal of Astronomy and Space Sciences
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    • v.36 no.4
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    • pp.265-281
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    • 2019
  • We present new BVRI light curves of UY UMa with no O'Connell effect and a flat bottom secondary eclipse. Light curve synthesis with the Wilson-Devinney code gives a new solution, which is quite different from the previous study: UY UMa is an A-subtype over-contact binary with a small mass ratio of q = 0.21, a high inclination of 81°.4, a small temperature difference of ΔT=18°, a large fill-out factor of f = 0.61, and a third light of approximately 10% of the total systemic light. The absolute dimensions were newly determined. Seventeen new times of minimum light have been calculated from our observations. The period study indicates that the orbital period has intricately varied in a secular period increase in which two cyclical terms with periods of 12y.0 and 46y.3 are superposed. The secular period increase was interpreted to be due to a conservative mass transfer of 2.68 × 10-8 M/yr from the less massive to the more massive star. The cyclical components are discussed in terms of double-light time contributions from two additional bound stars. The statistical relations of Yang & Qian (2015) among the physical parameters of 45 deep, low mass ratio contact binaries were revisited by using the physical parameters of UY UMa and 25 Kepler contact binaries provided by Şenavci et al. (2016).

A Study on Distribution Behavior of Ni and Sb in Reduction products of Cu Matte Converting (동 매트제련의 반응생성물중 Ni와 Sb의 분배거동에 관한 연구)

  • 김영진;이광막;김영홍
    • Resources Recycling
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    • v.8 no.5
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    • pp.44-50
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    • 1999
  • The sbdy iwestlgaled ihc propa-ties of Lhe dust\ulcorner rrom fe~~oallomya ~~ufacturTeh. e chemical composition, cornpasitlon material, p d c l e sire md shapes of the bulk dust, sired dust and magnetically separated durl were mvesligaled. As the re\ulcornerulL, we suppose that the dust from &gh Carbon Fenama~~gunesMc anuiact~vingP rocess is not sufiicient as solulce material of Mn because of ale low Mn canlenl (13.5%) and complicaled composition mate~ial. The dust from Bug F!lter or AOD Proccss is mi~inlym ade up of 0.2-2 pm Mn30, (Hausmam~iu)p iutlde in spherical shape and thc Mn content is 63.190.The dust from Cooler of AOD Process is inninly made up of coarse Ca(O1-Or)zM. n,FeyO,, SiO, and fine Mn30d.

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Properities of Plastic film house soils and Physiological Disorder of Eggplant (시설가지 연작재배토양 이화학성이 생리장해과 발생에 미치는 영향)

  • Uhm, Mi-Jeong;Han, Soo-Gon;Kim, Kab-Cheol;Moon, Young-Hoon;Choi, Jeong-Sik
    • Korean Journal of Soil Science and Fertilizer
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    • v.34 no.3
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    • pp.192-198
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    • 2001
  • This study was carried out to investigate the change of chemical properities and, microorganism due to continual cropping and to find the influences to physiological disordered eggplant fruits. Accumulation of soil nutrients seemed to be increased with the plastic film house duration and decreased with soil depth. The longer the period of eggplant cultivation duration, the lower the ratio of bacteria to fungi(B/F) and actinomycetes to the fungi(A/F) in rhizosphere soils. The soil EC and available $P_2O_5$ were significally correlated with the population densities of fungi($r=0.423^{**}$) and actinomycetes($r=0.438^{**}$), respectively. The ratio of split or drupaceous fruit showed tendency to increase with low soil moisture, and that of hypertrophy fruit showed tendency to increase in fields with longer cultivation years and high soil EC. The soil EC significally correlated with the ratio of hypertrophy fruit ($r=0.719^{**}$, Y=0.210X+0.578)and total physiological disordered fruits ($r=0.656^{**}$, Y=0.769X+7.097). And value of soil (Ca+Mg)/K was correlated with the ratio of physiologically disordered fruits($R^2=0.356^{*}$, Y=-1.333Ln(X)+12.26).

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Evaluation of Chloride Behavior and Service Life in Long-Term Aged FA Concrete through Probabilistic Analysis (장기재령 FA 콘크리트에 대한 염화물 거동 및 확률론적 염해 내구수명 평가)

  • Yoon, Yong-Sik;Kwon, Seung-Jun
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.8 no.3
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    • pp.276-285
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    • 2020
  • In this study, accelerated chloride diffusion tests were performed on OPC(Ordinary Portland Cement) and FA(Fly Ash) concrete considering three levels o f W/B(Water to Binder) ratio o n 1,095 curing days. The accelerated chloride diffusion coefficient and the passed charge were evaluated in accordance with Tang's method and ASTM C 1202, and the resistance performance to chloride attack improved over time. FA concrete showed excellent resistance performance against chloride penetration with help of pozzolanic reaction. As the result of the passed charge, FA concrete showed durability improvement, "low" grade to "very low" grade, but OPC concrete changed "moderate" grade to "low" grade at 1,095 curing days. After assuming the design variables used for durability design as normal distribution functions, the service life of each case was evaluated by the probabilistic analysis method based on MCS(Monte Carlo Simulation). In FA concrete, the increase of probability of durability failure was lower than that of OPC concrete with increasing time, because the time-dependent coefficient of FA concrete was up to 3.2 times higher than OPC concrete. In addition, the service life by probabilistic analysis was evaluated lower than the service life by deterministic analysis, since the target probability of durability failure was set to 10%. It is considered that more economical durability design will be possible if the mo re suitable target probability of durability failure is set for various structures through researches on actual conditions and indoor tests under various circumstances.

DNA Mediated Energy Transfer from 4',6-Diamidino-2-phenylindole to tetra- and bis-cationic Porphyrins at Low Binding Densities

  • Gong, Lindan;Ryu, Jae-Ki;Kim, Bok-Jo;Jang, Yoon-Jung
    • Bulletin of the Korean Chemical Society
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    • v.33 no.2
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    • pp.529-534
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    • 2012
  • The fluorescence of 4',6-diamidino-2-phenylindole (DAPI) bound to DNA at a [DAPI]/[DNA base] ratio of 0.005 was quenched by meso-tetrakis(N-methylpyridinium-4-yl)porphyrin (TMPyP) or cis-bis(N-methylpyridinium-4-yl)porphyrin (BMPyP) when both DAPI and either porphyrin spontaneously bound to the same DNA strand. The quenching was investigated using the "one-dimensional inner sphere" and the "F$\ddot{o}$rster resonance energy transfer" (FRET) models. Total quenching occurred when DAPI and TMPyP were up to 19.3 base pairs or $66\AA$ apart. BMPyP could quench the fluorescence up to 13.9 base pairs or $47\AA$. TMPyP, which intercalated between the DNA base-pairs, appeared to be a better acceptor than BMPyP, which stacked along the DNA stem. The higher quenching and higher resonance energy transfer efficiency of TMPyP was due to the larger overlap integral between its absorption spectrum and the emission spectrum of DNA-bound DAPI.

Predicting the moment capacity of RC slabs with insulation materials exposed to fire by ANN

  • Erdem, Hakan
    • Structural Engineering and Mechanics
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    • v.64 no.3
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    • pp.339-346
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    • 2017
  • Slabs prevent harmful effects of fire that may occur in any floor. However, it is necessary to protect the slabs from fire. Insulation materials may be appropriate to protect reinforced concrete (RC) slab from elevated temperature. In the present study, a model has been developed in artificial neural network (ANN) to predict the moment capacity ($M_r$) of RC slabs exposed to fire with insulation material. 672 data were obtained for ANN model through author's prepared program. Input layer in model consisted of seven input parameters; such as effective depth (d), ratio of d'/d, thermal conductivity coefficient ($k_{insulation}$), insulation materials thickness ($L_{insulation}$), reinforcement area ($A_{st}$), fire exposure time ($t_{\exp}$), and concrete compressive strength ($f_c$). The predicted $M_r$ by ANN was consistent with the obtained $M_r$ by author. It is proposed to ease computational complexity in determining $M_r$ using ANN. The effects of using insulation material on the moment capacity in RC slabs were also investigated. Insulating material with low thermal conductivity has been found to be more effective for durability to high temperature.

Analysis of Process Parameter dependency on the characteristics of high density fluoro carbon plasma using global model (글로벌 모델에 의한 저온 고밀도 플루오로카본 플라즈마 특성의 공정변수 의존성 해석)

  • Lee, Ho-Jun;Tae, Heung-Sik
    • Proceedings of the KIEE Conference
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    • 1999.11d
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    • pp.879-881
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    • 1999
  • Radical and ion densities in a CF4 plasma have been calculated as a function of input power density. 9as pressure and feed gas flow rate using simple 0 dimensional global model. Fluorine atom is found to be the most abundant neutral particle. Highly fragmented species such as CF and CF+ become dominant neutral and ionic radical at the high power condition. As the pressure increases. ion density increases but ionization rate decreases due to the decrease in electron temperature. The fractional dissociation of CF4 feed gas decreases with pressure after increasing at the low pressure range. Electron density and temperature are almost independent of flow rate within calculation conditions studied. The fractional dissociation of CF4 monotonically decreases with flow rate. which results in increase in CF3 and decrease in CF density. The calculation results show that the SiO2 etch selectivity improvement correlates to the increase in the relative density of fluorocarbon ion and neutral radicals which has high C/F ratio.

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Effects of Vacuum Annealing on the Electrical Properties of Sputtered Vanadium Oxide Thin Films (스퍼터된 바나듐 산화막의 전기적 특성에 미치는 진공 어닐링의 효과)

  • Hwang, In-Soo;Lee, Seung-Chul;Choi, Bok-Gil;Choi, Chang-Kyu;Kim, Nam-Chul
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2003.11a
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    • pp.435-438
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    • 2003
  • The effects of oxygen partial pressure and vacuum annealing on the electrical properties of sputtered vanadium oxide($VO_x$) thin films were investigated. The thin films were prepared by r.f. magnetron sputtering from $V_2O_5$ target in a gas mixture of argon and oxygen. The oxygen/(oxygen+argon) partial pressure ratio of 0% and 8% is adopted. Electrical properties of films sputter-deposited under different oxygen gas pressures and in situ annealed in vacuum at $400^{\circ}C$ for 1h and 4h are characterized through electrical conductivity measurements. I-V characteristics were distinguished between linear and nonlinear region. In the low field region the conduction is due to Schottky emission, while at high fields it changes to Fowler-Nordheim tunneling type conduction. The conductivity measurements have shown an Arrhenius dependence of the conductivity on the temperature.

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Electrochemical double layer capacitors with PEO and Sri Lankan natural graphite

  • Jayamaha, Bandara;Dissanayake, Malavi A.K.L.;Vignarooban, Kandasamy;Vidanapathirana, Kamal P.;Perera, Kumudu S.
    • Advances in Energy Research
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    • v.5 no.3
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    • pp.219-226
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    • 2017
  • Electrochemical double layer capacitors (EDLCs) have received a tremendous interest due to their suitability for diverse applications. They have been fabricated using different carbon based electrodes including activated carbons, single walled/multi walled carbon nano tubes. But, graphite which is one of the natural resources in Sri Lanka has not been given a considerable attention towards using for EDLCs though it is a famous carbon material. On the other hand, EDLCs are well reported with various liquid electrolytes which are associated with numerous drawbacks. Gel polymer electrolytes (GPE) are well known alternative for liquid electrolytes. In this paper, it is reported about an EDLC fabricated with a nano composite polyethylene oxide based GPE and two Sri Lankan graphite based electrodes. The composition of the GPE was [{(10PEO: $NaClO_4$) molar ratio}: 75wt.% PC] : 5 wt.% $TiO_2$. GPE was prepared using the solvent casting method. Two graphite electrodes were prepared by mixing 85% graphite and 15% polyvinylidenefluoride (PVdF) in acetone and casting n fluorine doped tin oxide glass plates. GPE film was sandwiched in between the two graphite electrodes. A non faradaic charge discharge mechanism was observed from the Cyclic Voltammetry study. GPE was stable in the potential windows from (-0.8 V-0.8 V) to (-1.5 V-1.5 V). By increasing the width of the potential window, single electrode specific capacity increased. Impedance plots confirmed the capacitive behavior at low frequency region. Galvanostatic charge discharge test yielded an average discharge capacity of $0.60Fg^{-1}$.