• Title/Summary/Keyword: Low $CO_2$

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Ambient Levels of CO and PM10 at Low- and High-floor Apartments in Industrial Complexes (산업단지 내 저층과 고층 아파트의 외기 중 호흡성분진과 일산화탄소 수준)

  • Jo, Wan-Kuen;Lee, Joon-Yeob
    • Journal of Environmental Science International
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    • v.15 no.8
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    • pp.719-725
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    • 2006
  • Since low-floor apartments ate vertically closer to patting lots and roadways, it is hypothesized that residents in low-floor apartments may be exposed to elevated ambient levels of motet vehicle emissions compared to residents in high-floor apartments. The present study examined this hypothesis by measuring two motor vehicle source-related pollutants(CO and PM10) in ambient air of high-rise apartment buildings within the boundary of industrial complexes according to atmospheric stability The ambient air concentrations of CO and PM10 were higher for low-floor apartments than for high-floor apartments, regardless of atmospheric stability, The median concentration ratio of the low-floor air to high-floor alt ranged from 1.3 to 2.0, depending upon atmospheric stabilities, seasons and compounds. Moreover, the CO and PM10 concentrations were significantly higher in the winter and in the summer, regardless of the Hoot height. Atmospheric stability also was suggested to be important for the residents' exposure of high-rise apartment buildings to both CO and PM10. The median ratios of surface inversion air to non-surface inversion air ranged from 1.2 to 1.7 and from 1.0 to 1.6 lot PM10 and CO, respectively, depending upon seasons. Conclusively, these parameters(apartment floor height, season, and atmospheric stability) should be considered when evaluating the exposure of residents, living in high-rise apartment buildings, to CO and PM10. Meanwhile, the median PMl0 outdoor concentrations were close to or higher than the Korean annual standards for PM10, and the maximum PM10 concentrations substantially exceeded the Korean PM10 standard, thus suggesting the need for a management strategy for ambient PM 10. Neither the median nor the maximum outdoor CO concentrations, however, were higher than the Korean CO standard.

Low Temperature Plasma-Enhanced Atomic Layer Deposition Cobalt

  • Kim, Jae-Min;Kim, Hyeong-Jun
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2009.11a
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    • pp.28.2-28.2
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    • 2009
  • Cobalt thin film was fabricated by a novel NH3-based plasma-enhanced atomic layer deposition(PE-ALD) using Co(CpAMD) precursor and $NH_3$ plasma. The PE-ALD Co thin films were produced well on both thermally grown oxide (100 nm) $SiO_2$ and Si(001) substrates. Chemical bonding states and compositions of PE-ALD Co films were analyzed by XPS and discussed in terms of resistivity and impurity level. Especially, we successfully developed PE-ALD Code position at very low growth temperature condition as low as $T_s=100^{\circ}C$, which enabled the fabrication of Co patterns through lift-off method after the deposition on PR patterned substrate without any thermal degradation.

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Influences of Various Electrolytes on the Low-Temperature Characteristics of Ni-MH Secondary Battery (Ni-MH 2차 전지의 저온특성에 미치는 전해액의 영향)

  • Park, Chae-Gyu;Shim, Jong-Su;Jang, Min-Ho;Park, Choong-Nyeon;Choi, Jeon
    • Journal of Hydrogen and New Energy
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    • v.18 no.3
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    • pp.284-291
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    • 2007
  • The Ni-MH batteries for HEV and industry are normally placed in outdoor, consequently causing an too weak discharge power problem due to a cold weather specially in winter time. In order to improve the low temperature performances of the Ni-MH battery for HEV and industrial uses, it has been investigated the low temperature discharge characteristics of Ni-MH battery with various electrolytes at $-18^{\circ}C$. The summary of experimental results are as follows. The low temperature characteristics depended strongly on the characteristics of electrolytes. When the concentration of the electrolytes were too high or too low the low temperature performance was poor. The best electrolyte was composed of KOH 6.2M+LiOH 1.2M. An addition of RbOH or CsOH to electrolyte improved the low temperature performance. The best total concentration of electrolyte composed of KOH, NaOH and LiOH was about 7M.

De-soda Process Using Silica for Fabrication of Low Soda Alumina Powder

  • Park, Sang-Chun;Kim, Dae-Woong;Heo, In-Woong;Lee, Sang-Jin
    • Journal of the Korean Ceramic Society
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    • v.52 no.3
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    • pp.192-196
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    • 2015
  • Low soda alumina powder was fabricated using silica (${\alpha}$-quartz) as an agent for removing soda components in the alumina. Quartz powder 2 mm in size was added to aluminum hydroxide obtained through the Bayer process, and then the mixture was heated at various temperatures. Finally, the heat-treated powders were sieved for classification. In this study, the effects of the quartz amount and heating temperature on the mechanism of removing soda were examined. A minimum soda content of 0.005 wt% was observed at the conditions of 15 wt% quartz (based on $Al(OH)_3$ amount) heat-treated at $1600^{\circ}C$ for 8 h. The soda components, such as $Na_2O$, NaOH, and $Na_2CO_3$, in alumina were ionized and activated at high temperature, and this facilitated the reaction with quartz silica and alumina producing nepheline. The advantages of using quartz include low iron content and low cost in comparison with the conventional de-soda process using chamotte, another silicate mineral.

Evaluation for adsorption of low concentration of indoor $CO_2$ adsorption using zeolite and alkali metal (제올라이트 및 알칼리금속을 이용한 실내용 저농도 $CO_2$ 흡착제의 성능 평가)

  • Lim, Yun-Hui;Lee, Ju-Yeol;Cha, Yu-Joung;Park, Byung-Hyun
    • Journal of the Korean Applied Science and Technology
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    • v.30 no.3
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    • pp.494-503
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    • 2013
  • In this study, $CO_2$ adsorbent was produced for minimizing energy loss due to ventilation within the building. For improved selectivity about low concentration of $CO_2$ in multiple-use facilities, the ball type adsorbent was modified from a commercial zeolite, alumina, alkali metals and activated carbon with mixing LiOH, binder, and $H_2O$. We measured specific surface area, pore characteristic, and crystal structure of the modified adsorbent. Effects of alkalization on the absorptive properties of the adsorbents were investigated. Continuous column tests (2,000 ppm) and batch chamber tests ($4m^3$, 5,000ppm) showed that the modified adsorbent indicated about the selectivity of $CO_2$ more than 9.7% (0.613 mmol/g) compared with ordinary adsorbents and $CO_2$ removal efficiency of 88.8% within l hour, respectively. It was estimated that the modified adsorbent was applicable to indoor environments.

Highly Conformal Deposition of Pure Co Films by MOCVD Using Co2(CO)8 as a Precursor (Co2(CO)8 (Dicobalt Octacarbonyl) 전구체를 이용한 MOCVD Co 박막의 균일한 증착 특성 및 높은 순도에 관한 연구)

  • Lee, Jeong-Gil;Lee, Jae-Gab
    • Korean Journal of Materials Research
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    • v.16 no.2
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    • pp.106-110
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    • 2006
  • We have investigated the effect of the experimental variables such as temperature and pressure on conformality of Co films deposited over high aspect ratio trenches using $Co_2(CO)_8$ as a precursor. The results show that the conformality of Co films is a strong function of temperature and process pressure. Lowering the pressure and temperature significantly improves the conformality. As the pressure decreases from 0.6 Torr to 0.2 Torr at $50^{\circ}C$, the bottom coverage of Co films over $0.2{\mu}m$ width trenches with an aspect ratio of 13 to 1 significantly increases to 85%. However, further increasing the temperature from 50 to $60^{\circ}C$ at the pressure of 0.2 Torr degrades the bottom coverage to 14%. In contrast, the extremely low pressure of 0.03 Torr allows the excellent conformal deposition of Co films up to $70^{\circ}C$. This can be attributed to the suppression of homogeneous reaction in the gas phase, which can create the intermediate products with high sticking coefficient. In addition, the Co films deposited at $50^{\circ}C$ show the low resistivity with negligible contamination. As a result, the newly developed Co process using MOCVD can be implemented into the next generation devices with complex shapes.

CHANGES IN BODY AND ORGAN WEIGHTS, HEMATOLOGICAL PARAMETERS, AND FREQUENCY OF MICRONUCLEI IN THE PERIPHERAL BLOOD ERYTHROCYTES OF ICR MICE EXPOSED TO LOW-DOSE-RATE $\gamma$-RADIATION

  • Kang, Yu-Mi;Shin, Suk-Chul;Jin, Young-Woo;Kim, Hee-Sun
    • Journal of Radiation Protection and Research
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    • v.34 no.3
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    • pp.102-106
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    • 2009
  • We exposed ICR mice to low-dose (0.2 Gy) and low-dose-rate (0.7 mGy/h) $\gamma$-radiation ($^{137}Cs$) in the Low-dose-rate Irradiation Facility at the Radiation Health Research Institute to evaluate systemic effects of low-dose radiation. We compared the body and organ weights, number of blood cells (white and red blood cells and platelets), levels of biochemical markers in serum, and frequency of micronuclei in polychromatic erythrocytes between low-dose irradiated and non-irradiated control mice. The ICR mice irradiated with total doses of 0.2 and 2 Gy showed no changes in body and organ weights, number of blood cells (white and red blood cells), or frequency of micronuclei in the polychromatic erythrocytes of peripheral blood. However, the number of platelets (P = 0.002) and the liver weight (P < 0.01) were significantly increased in mice exposed to 0.2 and 2 Gy, respectively. These results suggest that a low-dose-rate of 0.7 mGy/h does not induce systemic damage. This dose promotes hematopoiesis in the bone marrow microenvironment and the proliferation of liver cells. In the future, the molecular biological effects of lower doses and dose rates need to be evaluated.

Effect of Shielding Gases on the Weldability of High Efficient GMAW Process (고능률 GMAW의 용접성에 미치는 보호가스의 영향)

  • 한기형;한종만;이민우;이은배;한용섭
    • Journal of Welding and Joining
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    • v.13 no.1
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    • pp.127-137
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    • 1995
  • The possibility of new GMAW process using economic shielding gases including CO$_{2}$ gas was investigated on the effect of shielding gas on weldabilty. In the optimum welding condition using 600A power source, FCAW process showed low depositions rate, 114 g/min at 300A, but new GMAW using other mixed shielding gases exhibited high deposition rate, 208-224 g/min at 450A. TIME gas, Ar+CO$_{2}$ gas and Ar+CO$_{2}$+O$_{2}$ gas as a shielding gas were able to be used to the very high welding current(450A), moreover TIME gas and Ar+CO$_{2}$ gas showed the highest arc stability among shielding gases studied in this experiments. The weld penetration was performed by axial spray transfer mode of weld droplet. On the basis of workability, weldability and economic point of view, Ar mixture (80%Ar+20%CO$_{2}$) gas was recommended as a shielding gas for the development and application of new GMAW process. This shielding gas showed the low spatter, good weld quality, stable arc and low cost at the region of high welding current.

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문경지역 탄산온천수의 지구화학적 및 동위원소적 특성연구

  • 배대석;최현수;고용권;박맹언;정율필
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2000.11a
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    • pp.87-90
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    • 2000
  • The hydrogeochemical and isotopic studies on deep groundwater in the Munkyeong area, Kyeongbuk province were carried out. $CO_2$-rich groundwater (Ca-HC $O_3$ type) is characterized by low pH (5.8~6.5) and high TDS (up to 2,682 mg/L), while alkali groundwater (Na-HC $O_3$ type) shows a high pH (9.I~10.4) and relatively low TBS (72~116 mg/L). $CO_2$-rich water may have evolved by $CO_2$ added at depth during groundwater circulation. This process leads to the dissolution of surrounding rocks and Ca, Na, Mg, K and HC $O_3$ concentrations are enriched. The low Pc $o_2$ (10$^{-6.4}$atm) of alkali groundwaters seems to result from the dissolution of silicate minerals without a supply of $CO_2$. The $\delta$$^{18}$ O and $\delta$D values and tritium data indicate that two types of deep groundwater were both derived from pre-thermonuclear meteoric water. The carbon Isotope data show that dissolved carbon in the $CO_2$-rich water was possibly derived from deep-seated $CO_2$ gas. The $\delta$$^{18}$ S values of dissolved sulfate show that sulfate reduction occurred at great depths. The application of various chemical geothermometers on $CO_2$-rich groundwater shows that the calculated deep reservoir temperature is about 130~175$^{\circ}C$. Based on the geological setting, water chemistry and environmental isotope data, each of the two types of deep groundwater represent distinct hydrologic and hydrogeochemical evolution at depth and their movement is controlled by the local fracture system.m.

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Bimetallic Zeolitic Imidazolate Framework Derived Co3O4/CoFe2O4 Catalyst Loaded In2O3 Nanofibers for Highly Sensitive and Selective Ethanol Sensing (금속-유기 골격체 열분해를 통해 합성된 Co3O4/CoFe2O4 첨가 In2O3나노섬유를 이용한 고감도 고선택성 에탄올 센서)

  • Lee, Soo-Min;Kim, Tae-Hyun;Jo, Young-Moo;Kim, Ki Beom;Lee, Jong-Heun
    • Journal of Sensor Science and Technology
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    • v.30 no.2
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    • pp.94-98
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    • 2021
  • In this study, pure and Co3O4/CoFe2O4-loaded Indium oxide (In2O3) nanofibers were synthesized by the electrospinning of an Indium/Polyvinylpyrrolidone precursor solution containing cobalt and iron bimetallic zeolitic imidazolate frameworks and subsequent heat treatment. The ethanol, toluene, p-xylene, benzene, carbon monodxide, and hydrogen gas sensing characteristics of the solution were measured at 250-400 ℃. 0.5 at%-Co3O4/CoFe2O4-loaded In2O3 nanofibers exhibited extreme response (resistance ratio - 1) to 5 ppm of ethanol (210.5) at 250 ℃ and excellent selectivity over the interfering gases. In contrast, pure In2O3 nanofibers exhibited relatively low responses to all the analyte gases and low selectivity above 250-400 ℃. The superior response and selectivity toward ethanol is explained by the catalytic roles of Co3O4 and CoFe2O4 in gas sensing reaction and the electronic sensitization induced by the formation of p (Co3O4/CoFe2O4)-n (In2O3) junctions.