• Transactions of the Korean Society of Mechanical Engineers A
• /
• v.33 no.5
• /
• pp.489-495
• /
• 2009

A novel technique to measuret of viscoelastic properties of polymers is proposed to investigate complex Poisson's ratio as a function of frequency. The forced vibration responses for the samples under the normal and the shear deformation are to be measured with varying load masses. The measured data were used to obtain the viscoelastic properties of the material based on an accurate 2D numerical deformation model of the sample. The 2D model enabled us to exclude data correction by the empirical form factor used in 1D model. Comprehensive measurements of viscoelastic properties of two slightly varied silicone RTV rubber ($Silastic^{(R)}$ S2) compositions were performed. Standard composition (90% PDMS polymer + 10% catalyst) and modified composition (92.5% polymer + 7.5% catalyst) were tested in temperature range from $30^{\circ}C$ to $70^{\circ}C$. Shear modulus, modulus of elasticity, loss factor, and both the real and the imaginary parts of the Poisson's ratio were determined for frequencies from 50 to 400Hz in the linear deformation regime (at relative deformations $10^{-4}{\sim}10^{-3}$).

• Journal of Pharmaceutical Investigation
• /
• v.36 no.1
• /
• pp.31-38
• /
• 2006

Using a Rheometries Dynamic Analyzer (RDA II), the dynamic viscoelastic properties of a semi-solid ointment base (vaseline) in large amplitude oscillatory shear flow fields were measured over a temperature range of $25{\sim}45^{\circ}C$ and the linear viscoelastic behavior in small amplitude oscillatory shear flow fields was investigated over a wide range of angular frequencies. In this article, the nonlinear viscoelastic behavior was reported from the experimentally obtained data and the effect of temperature on this behavior was discussed in detail. In addition, the angular frequency and temperature dependencies of a linear viscoelastic behavior were explained. Finally, the applicability of a time-temperature superposition principle originally developed for polymeric materials was examined using a shift factor. Main results obtained from this study can be summarized as follows : (1) At very small strain amplitude region, vaseline shows a linear viscoelastic behavior independent of the imposed deformation magnitudes. Above a critical strain amplitude $({\gamma}_{0}=0.1{\sim}0.2%)$, however, vaseline exhibits a nonlinear viscoelastic behavior ; indicating that both the storage modulus and dynamic viscosity are sharply decreased with increasing deformation magnitude. (2) In large amplitude oscillatory shear flow fields, an elastic behavior (storage modulus) has a stronger strain amplitude dependence and begins to show a nonlinear behavior at a smaller strain amplitude region than does a viscous behavior (dynamic viscosity). (3) In small amplitude oscillatory shear flow fields, the storage modulus as well as the loss modulus are continuously increased as an increase in angular frequency and an elastic nature is always superior to a viscous behavior over a wide range of angular frequencies. (4) A time-temperature superposition principle can successfully be applicable to vaseline. This finding allows us to estimate the dynamic viscoelastic behavior of vaseline over an extraordinarily extended range (11 decades) of angular frequencies inaccessible from the experimentally measured range (4 decades).

• Proceedings of the KSR Conference
• /
• 2007.11a
• /
• pp.824-829
• /
• 2007

Mechanical and thermal analysis properties of carbon fiber/epoxy composite for train carbody were evaluated by varying with environmental factors such as ultraviolet, temperature, and moisture. Accelerated environmental aging tester was utilized for this study. Testing temperature was set to $80^{\circ}C$ and ultraviolet was obtained through xenon-arc lamp. To consider moisture, water sprayed on specimen for 18 minutes every 2 hour. All the specimens were made of CF1263/Epoxy composite. Mechanical properties such as tensile, bending, and shear properties were evaluated through a material testing system. Also, thermal analysis properties such as storage shear modulus, loss shear modulus, and tan ${\delta}$ were measured through dynamic mechanical analyzer. Finally surfaces of the composite exposed to environmental factors were examined using a scanning electron microscope. From experimental results, those properties of CF1263/Epoxy composite were shown to be slightly decreased due to environmental factors.

• Structural Engineering and Mechanics
• /
• v.43 no.1
• /
• pp.15-30
• /
• 2012

A damped Timoshenko beam element is introduced for the DOF-efficient forced vibration analysis of beam-like structures coated with viscoelastic damping layers. The rotary inertia as well as the shear deformation is considered, and the damping effect of viscoelastic layers is modeled as an imaginary loss factor in the complex shear modulus. A complex composite cross-section of structures is replaced with a homogeneous one by means of the transformed section approach in order to construct an equivalent single-layer finite element model capable of employing the standard $C^{0}$-continuity basis functions. The numerical reliability and the DOF-efficiency are explored through the comparative numerical experiments.

• Korea-Australia Rheology Journal
• /
• v.18 no.2
• /
• pp.67-81
• /
• 2006

Using a strain-controlled rheometer, the dynamic viscoelastic properties of aqueous xanthan gum solutions with different concentrations were measured over a wide range of strain amplitudes and then the linear viscoelastic behavior in small amplitude oscillatory shear flow fields was investigated over a broad range of angular frequencies. In this article, both the strain amplitude and concentration dependencies of dynamic viscoelastic behavior were reported at full length from the experimental data obtained from strain-sweep tests. In addition, the linear viscoelastic behavior was explained in detail and the effects of angular frequency and concentration on this behavior were discussed using the well-known power-law type equations. Finally, a fractional derivative model originally developed by Ma and Barbosa-Canovas (1996) was employed to make a quantitative description of a linear viscoelastic behavior and then the applicability of this model was examined with a brief comment on its limitations. Main findings obtained from this study can be summarized as follows: (1) At strain amplitude range larger than 10%, the storage modulus shows a nonlinear strain-thinning behavior, indicating a decrease in storage modulus as an increase in strain amplitude. (2) At strain amplitude range larger than 80%, the loss modulus exhibits an exceptional nonlinear strain-overshoot behavior, indicating that the loss modulus is first increased up to a certain strain amplitude(${\gamma}_0{\approx}150%$) beyond which followed by a decrease in loss modulus with an increase in strain amplitude. (3) At sufficiently large strain amplitude range (${\gamma}_0>200%$), a viscous behavior becomes superior to an elastic behavior. (4) An ability to flow without fracture at large strain amplitudes is one of the most important differences between typical strong gel systems and concentrated xanthan gum solutions. (5) The linear viscoelastic behavior of concentrated xanthan gum solutions is dominated by an elastic nature rather than a viscous nature and a gel-like structure is present in these systems. (6) As the polymer concentration is increased, xanthan gum solutions become more elastic and can be characterized by a slower relaxation mechanism. (7) Concentrated xanthan gum solutions do not form a chemically cross-linked stable (strong) gel but exhibit a weak gel-like behavior. (8) A fractional derivative model may be an attractive means for predicting a linear viscoelastic behavior of concentrated xanthan gum solutions but classified as a semi-empirical relationship because there exists no real physical meaning for the model parameters.

• Proceedings of the KSR Conference
• /
• 2007.11a
• /
• pp.852-858
• /
• 2007

The durability of carbon/epoxy composites under salt water environment was investigated through salt water spray tester. Salt water environment was obtained through salt spray and salt immersion. 5% NaCl solution was used for salt water as natural salt water. Mechanical test was performed to obtain tensile properties, flexural properties, and shear properties of carbon/epoxy composite over 12 months under salt water environment. Dynamic mechanical analyzer was used to investigate thermal analysis properties such storage modulus, loss modulus, and tan ${\delta}$. Also FT/IR test was conducted to investigate a change in chemical structure. According to the results, mechanical properties were found to be slowly degraded as a function of exposure times. Regarding to thermal analysis properties, storage modulus was insensitive to exposure times, but loss modulus was shown to be slightly decreased. Although the shape and location of peak in FT/IR were not much changed, the intensity of peak in FT/IR was affected on exposure times. We also found that salt water immersion was more severe to the durability of carbon/epoxy composite rather than salt water spray.

• International Journal of Railway
• /
• v.1 no.3
• /
• pp.113-116
• /
• 2008

The long-tenn exposure of polymeric composite materials to extreme-use environments, such as pressure, temperature, moisture, and load cycles, results in changes in the original properties of the material. In this study, the effect of combined environmental factors such as ultraviolet ray, high temperature and high moisture on mechanical and thermal analysis properties of glass fabric and phenolic composites are evaluated through a 2.5 KW accelerated environmental aging tester. The environmental factors such as temperature, moisture and ultraviolet ray applied of specimens. A xenon-arc lamp is utilized for ultraviolet light and exposure time of up to 3000 hours are applied. Several types of specimens - tensile, bending, and shear specimens that are warp direction and fill direction are used to investigate the effects of environmental factors on mechanical properties of the composites. Mechanical degradations for tensile, bending and shear properties are evaluated through a Universal Testing Machine (UTM). Also, storage shear modulus, loss shear modulus and tan a are measured as a function of exposure time through a Dynamic Mechanical Analyzer (DMA). From the experimental results, changes in material properties of glass fabric and phenolic composites are shown to be slightly degraded due to combined environmental effects.

• Transactions of the Korean Society for Noise and Vibration Engineering
• /
• v.22 no.9
• /
• pp.837-844
• /
• 2012

We considered an approach in terms of materials for improvement of insulation performance of vehicle rubber hoses. Ethylene propylene rubber(EPDM) for heater hoses in cooling system and acrylic rubber(AR) for intercooler hose in intake system were chosen for mixing for the vibration and noise performance. We modified EPDM and AR through changing compound of base polymer, reinforcement fillers and additives. Dynamic mechanical analysis(DMA) was used to measure viscoelastic properties such as shear modulus and loss factor($tan{\delta}$). Vehicle acceleration test was also conducted to observe indoor changes in insulation performance of hoses.

• Proceedings of the KSR Conference
• /
• 2003.10c
• /
• pp.333-338
• /
• 2003

Polymeric composite structures used in ground transportation applications such as the carbody of tilting train may be exposed to a ground environmental conditions during long-term missions. In this study, the degradation of mechanical and physical properties of graphite/epoxy composite and glass fabric/phenol composite under ground environmental conditions was investigated. Accelerated environmental conditions of ultraviolet radiation, temperature, and moisture were considered. Several types of specimens were used to investigate the effects of environmental conditions on mechanical properties of the composites. Also, storage shear modulus, loss shear modulus, and tan 8 were measured as a function of exposure times through a dynamic mechanical analyzer. Finally, composite surfaces exposed to environmental conditions were examined using a scanning electron microscope.

• Korea-Australia Rheology Journal
• /
• v.21 no.3
• /
• pp.185-191
• /
• 2009

Polystyrene/multi-walled carbon nanotube (PS/MWCNT) composites were prepared by the use of latex technology. The monodisperse PS latex was synthesized by an emulsifier-free emulsion polymerization from styrene/potassium persulfate/water system in the presence of ethanol. The MWCNTs were first treated with acid mixture to eliminate impurities, dispersed in deionized water driven by ultrasonicator, and then mixed with the PS latex. From these mixtures, PS/MWCNT composites were prepared by freeze-drying and subsequent compression molding. In the small-amplitude oscillatory shear experiments, both complex viscosity and storage modulus increased with increasing MWCNT content. A pronounced effect of MWCNT content was observed, resulting in larger storage modulus and stronger yield behavior at low frequencies when compared to unmodified PS. It showed a transition from viscous to elastic behavior with increasing MWCNT content. Over the MWCNT content of 3 wt%, the storage modulus was higher than the loss modulus across all frequencies.