• Animal Bioscience
• /
• v.36 no.9
• /
• pp.1435-1444
• /
• 2023

Objective: This study was conducted to evaluate Raman spectroscopy technique as a noninvasive tool to predict meat quality traits on Braford longissimus thoracis et lumborum muscle. Methods: Thirty samples of muscle from Braford steers were analyzed by classical meat quality techniques and by Raman spectroscopy with 785 nm laser excitation. Water holding capacity (WHC), intramuscular fat content (IMF), cooking loss (CL), and texture profile analysis recording hardness, cohesiveness, and chewiness were determined, along with fiber diameter and sarcomere length by scanning electron microscopy. Warner-Bratzler shear force (WBSF) analysis was used to differentiate tender and tough meat groups. Results: Higher values of cohesiveness and CL, together with lower values of WHC, IMF, and shorter sarcomere were obtained for tender meat samples than for the tougher ones. Raman spectra analysis allows tender and tough sample differentiation. The correlation between the quality attributes predicted by Raman and the physical measurements resulted in values of R² = 0.69 for hardness and 0,58 for WBSF. Pearson's correlation coefficient of hardness (r = 0.84) and WBSF (r = 0.79) parameters with the phenylalanine Raman signal at 1,003 cm^-1, suggests that the content of this amino acid could explain the differences between samples. Conclusion: Raman spectroscopy with 785 nm laser excitation is a suitable and accurate technique to identify beef with different quality attributes.

• Bulletin of the Korean Chemical Society
• /
• v.32 no.spc8
• /
• pp.2941-2948
• /
• 2011

A nanogap formed by a metal nanoparticle and a flat metal substrate is one kind of "hot site" for surface-enhanced Raman scattering (SERS). The characteristics of a typical nanogap formed by a planar Au and either an Au and Ag nanoparticle have been well studied using 4-aminobenzenethiol (4-ABT) as a probe. 4-ABT is, however, an unusual molecule in the sense that its SERS spectral feature is dependent not only on the kinds of SERS substrates but also on the measurement conditions; thus further characterization is required using other adsorbate molecules such as 1,4-phenylenediisocyanide (1,4-PDI). In fact, no Raman signal was observable when 1,4-PDI was selfassembled on a flat Au substrate, but a distinct spectrum was obtained when 60 nm-sized Au or Ag nanoparticles were adsorbed on the pendent -NC groups of 1,4-PDI. This is definitely due to the electromagnetic coupling between the localized surface plasmon of Au or Ag nanoparticle with the surface plasmon polariton of the planar Au substrate, allowing an intense electric field to be induced in the gap between them. A higher Raman signal was observed when Ag nanoparticles were attached to 1,4-PDI, irrespective of the excitation wavelength, and especially the highest Raman signal was measured at the 632.8 nm excitation (with the enhancement factor on the order of ${\sim}10^3$), followed by the excitation at 568 and 514.5 nm, in agreement with the finite-difference timedomain calculation. From a separate potential-dependent SERS study, the voltage applied to the planar Au appeared to be transmitted without loss to the Au or Ag nanoparticles, and from the study of the effect of volatile organics, the voltage transmission from Au or Ag nanoparticles to the planar Au also appeared as equally probable to that from the planar Au to the Au or Ag nanoparticles in a nanogap electrode. The response of the Au-Ag nanogap to the external stimuli was, however, not the same as that of the Au-Au nanogap.

• Journal of the Institute of Electronics Engineers of Korea TC
• /
• v.42 no.12
• /
• pp.127-134
• /
• 2005

Lost packet robustness is an most important quality measure for voice over IP networks(VoIP). Recovery of the lost packet from the received information is crucial to realize this robustness. So, this paper proposes the lost packet recovery method from the received information for real-time communication for CELP coder. The proposed BS-PLC (Both Side Packet Loss Concealment) based WSOLA(Waveform Shift OverLab Add) allow the lost packet to be recovered from both the 'previous' and 'next' good packet as the LP parameter and the excitation signal are respectively recovered. The burst of packet loss is modeled by Gilbert model. The proposed scheme is applied to G.729 most used in VoIP and is evaluated through the SNR(signal to noise) and the MOS(Mean Opinion Score) test. As a simulation result, The proposed scheme provide 0.3 higher in Mean Opinion Score and 2 dB higher in terms of SNR than an error concealment procedure in the decoder of G.729 at $20\%$ average packet loss rate.

• Journal of the Korean Chemical Society
• /
• v.67 no.6
• /
• pp.407-414
• /
• 2023

The present study uses quasi-classical trajectory procedures to examine the vibrational relaxation and dissociation of the methyl and ring C-H bonds in excited methylpyrazine (MP) during collision with either N₂ or O₂. The energy-loss (-ΔE) of the excited MP is calculated as the total vibrational energy (E_T) of MP is increased in the range of 5,000 to 40,000cm^-1. The results indicate that the collision-induced vibrational relaxation of MP is not large, increasing gradually with increasing E_T between 5,000 and 30,000 cm^-1, but then decreasing with the further increase in E_T. In both N₂ and O₂ collisions, the vibrational relaxation of MP occurs mainly via the vibration-to-translation (V→T) and vibration-to-vibration (V→V) energy transfer pathways, while the vibration-to-rotation (V→R) energy transfer pathway is negligible. In both collision systems, the V→T transfer shows a similar pattern and amount of energy loss in the ET range of 5,000 to 40,000cm^-1, whereas the pattern and amount of energy transfer via the V→V pathway differs significantly between two collision systems. The collision-induced dissociation of the C-H_methyl or C-H_ring bond occurs when highly excited MP (65,000-72,000 cm^-1) interacts with the ground-state N₂ or O₂. Here, the dissociation probability is low (10^-4-10^-1), but increases exponentially with increasing vibrational excitation. This can be interpreted as the intermolecular interaction below E_T = 71,000 cm^-1. By contrast, the bond dissociation above E_T = 71,000 cm^-1 is due to the intramolecular energy flow between the excited C-H bonds. The probability of C-H_methyl dissociation is higher than that of C-H_ring dissociation.

• Proceedings of the Korean Vacuum Society Conference
• /
• 2016.02a
• /
• pp.179-179
• /
• 2016

A radio-frequency (RF) Inductively Coupled Plasma (ICP) torch system was used for boron-nitride nano-tube (BNNT) synthesis. Because of electrodeless plasma generation, no electrode pollution and effective heating transfer during nano-material synthesis can be realized. For stable plasma generation, argon and nitrogen gases were injected with 60 kW grid power in the difference pressure from 200 Torr to 630 Torr. Varying hydrogen gas flow rate from 0 to 20 slpm, the electrical and optical plasma properties were investigated. Through the spectroscopic analysis of atomic argon line, hydrogen line and nitrogen molecular band, we investigated the plasma electron excitation temperature, gas temperature and electron density. Based on the plasma characterization, we performed the synthesis of BNNT by inserting 0.5~1 um hexagonal-boron nitride (h-BN) powder into the plasma. We analysis the structure characterization of BNNT by SEM (Scanning Electron Microscopy) and TEM (Transmission Electron Microscopy), also grasp the ingredient of BNNT by EELS (Electron Energy Loss Spectroscopy) and Raman spectroscopy. We treated bundles of BNNT with the atmospheric pressure plasma, so that we grow the surface morphology in the water attachment of BNNT. We reduce the advancing contact angle to purity bundles of BNNT.

• Smart Structures and Systems
• /
• v.12 no.3_4
• /
• pp.327-344
• /
• 2013

Beam string structure (BSS) is introduced as a new type of hybrid prestressed string structures. The composition and mechanics features of BSS are discussed. The main principles of wavelet packet transform (WPT), principal component analysis (PCA) and support vector machine (SVM) have been reviewed. WPT is applied to the structural response signals, and feature vectors are obtained by feature extraction and PCA. The feature vectors are used for training and classification as the inputs of the support vector machine. The method is used to a single one-way arched beam string structure for damage detection. The cable prestress loss and web members damage experiment for a beam string structure is carried through. Different prestressing forces are applied on the cable to simulate cable prestress loss, the prestressing forces are calculated by the frequencies which are solved by Fourier transform or wavelet transform under impulse excitation. Test results verify this method is accurate and convenient. The damage cases of web members on the beam are tested to validate the efficiency of the method presented in this study. Wavelet packet decomposition is applied to the structural response signals under ambient vibration, feature vectors are obtained by feature extraction method. The feature vectors are used for training and classification as the inputs of the support vector machine. The structural damage position and degree can be identified and classified, and the test result is highly accurate especially combined with principle component analysis.

• Proceedings of the Korean Vacuum Society Conference
• /
• 2010.02a
• /
• pp.4-5
• /
• 2010

The surface phonon is defined as a coherent vibrational excitation of surface atoms propagating along the surface. It is characterized by a phonon dispersion curves, which were extensively studied in 1990's using helium atom scattering and high-resolution electron-energy-loss spectroscopy (HREELS)[1].The understanding is mainly based on the theoretical framework of a classical bond model or cluster calculations. The recent sample preparation and first principles calculations open the naval way to deep insight for surface phonon problems. The surface phonon dispersion on the hydrogen-terminated Si(111)-($1{\times}1$) surface [H:Si(111)] is the typical system and already reported experimentally [2] and theoretically [3], although the understandingis incomplete. The sample contaminated by the oxygen atoms on the surface and the calculations were also classical. In this study, firstly, we have prepared an ultra-clean H:Si(111) surface [4] and measured the surface phonon dispersion curvesusing HREELS. Secondly, we have performed first-principles density functional calculations with the projector augmented wave functionals, as implemented in VASP, using generalized gradient approximations. We used aslab of six silicon layers and both top and bottom surfaces were terminated with hydrogen atoms. Finally, we have compared with the surface phonon dispersion of deuterium-terminatedSi(111)-($1{\times}1$) surface[5] and led to our conclusions. The Si-H stretching and the bending modes are observed at 258.5 and 78.2 meV, respectively. These energies are the same as the previously reported values [2], but the energy-loss peaks at the lower energy regions are dramatically shifted. Through this combination study, we have formulated the procedure of preparing ultra-clean H:Si(111)/D:Si(111), which was confirmed by HREELS vibrational analysis. The Si surface will be utilized for further nano-physics research as well as for the materials for nano-fubrication.

• Journal of Mechanical Science and Technology
• /
• v.17 no.4
• /
• pp.562-570
• /
• 2003

This experimental study concerns the characteristics of vortex flow in a concentric annulus with a diameter ratio of 0.52, whose outer cylinder is stationary and inner one is rotating. Pressure losses and skin friction coefficients have been measured for fully developed flows of water and of 0.4% aqueous solution of sodium carboxymethyl cellulose (CMC), respectively, when the inner cylinder rotates at the speed of 0～600 rpm. Also, the visualization of vortex flows has been performed to observe the unstable waves. The results of present study reveal the relation of the bulk flow Reynolds number Re and Rossby number Ro with respect to the skin friction coefficients. In somehow, they show the existence of flow instability mechanism. The effect of rotation on the skin friction coefficient is significantly dependent on the flow regime. The change of skin friction coefficient corresponding to the variation of rotating speed is large for the laminar flow regime, whereas it becomes smaller as Re increases for the transitional flow regime and. then, it gradually approach to zero for the turbulent flow regime. Consequently, the critical (bulk flow) Reynolds number Re$\_$c/ decreases as the rotational speed increases. Thus, the rotation of the inner cylinder promotes the onset of transition due to the excitation of Taylor vortices.

• Structural Engineering and Mechanics
• /
• v.49 no.3
• /
• pp.285-296
• /
• 2014

Material damping affects the dynamic behaviors of engineering structures considerably, but up to till now little research is maintained on influence factors of material damping. Based on the damping-stress function of steel, the material damping of steel beams is obtained by calculating the stress distribution of the beams with an analytical method. Some key influence factors of the material damping, such as boundary condition, amplitude and frequency of excitation, load position as well as the cross-sectional dimension of a steel beam are analyzed respectively. The calculated results show that even in elastic scope, material damping does not remain constant but varies with these influence factors. Although boundary condition affects material damping to some extent, such influence can be neglected when the maximum stress amplitude of the beam is less than the fatigue limit of steel. Exciting frequency, load position and cross-section dimension have great effects on the material damping of the beam which maintain the similar changing trend under different boundary conditions respectively.

• Journal of the Society of Naval Architects of Korea
• /
• v.45 no.2
• /
• pp.144-150
• /
• 2008

Ships and offshore structures are exposed to wave and engine excitation loadings during navigation and cargo/ballasting operations. These excessive loads may cause damages to hull and may result loss of life the ship. Therefore, it is important to develop a system that allow accurate measurements of global hull loads. The objective of the study is developing a fiber optic monitoring system that is capable of monitoring, recording and warning of the vessel performance. A method for measurement of global loads on a vessel, using strain measurements from a network of fiber optic strain sensors and extensive finite-element analyses(FEA) with idealistic load cases, is presented. The method has been successfully validated on the idealized ship structure model with strain sensors.