• Title/Summary/Keyword: Loss Modulus

Search Result 372, Processing Time 0.019 seconds

Preparation and Stabilization of an O/W Emulsion Using Liquid Crystalline Phases (액정상을 이용한 O/W형 에멀젼의 제조 및 제형 안정화에 관한 연구)

  • An, Bong-Jeun;Lee, Jin-Tae;Lee, In-Chol;Kwak, Jae-Hoon;Park, Jung-Mi;Park, Chan-Ik
    • Journal of the Korean Applied Science and Technology
    • /
    • v.21 no.1
    • /
    • pp.31-36
    • /
    • 2004
  • Liquid crystalline phases were formed from acylglutamate; polyglyceryl-10 myristate and glycerine mixture and they were used as a base material for preparing an O/W emulsion. When an oil phase is added into the liquid crystalline phases, it was inserted into the dispersed liquid crystal droplets rather than stayed outside the liquid crystals, which can be known by the fact that the size of liquid crystal droplets increases with the increasing oil phase content. Along with the increase in the droplet size, the complex modulus increases from 100 to 350 pascals and the loss angle decreases from 60 to 24 degrees, from which it can be known that the increase in the internal phase volume results in the increase in the elastic property of oil in liquid crystalline-phases (O/LC). When the water phase was lastly added into the O/LC phase, the emulsification occurred to form a O/W emulsion and the averaged particle size of the O/W emulsion changes from 22.5nm to 538nm with the addition of water phase. The results from the droplet size measurements and stability tests under accelerated conditions such as high temperature show that the obtained O/W emulsion is very consistent with time.

The Effect of Chemical Properties of Comonomer on Adhesion Properties of Acrylic Pressure Sensitive Adhesives (공단량체의 화학적 구조에 따른 아크릴 접착제의 접착특성)

  • Choi, Woon-Jin;Kim, Ho-Gyum;Cho, Kwang-Soo;Lee, Dong-Ho;Min, Kyung-Eun
    • Polymer(Korea)
    • /
    • v.31 no.5
    • /
    • pp.369-373
    • /
    • 2007
  • In this study, solvent-free pressure sensitive adhesives (PSA) using acrylic copolymer was prepared by UV radiation to investigate the effect of comonomer on the adhesion properties. Adhesive force value of PSA was increased with the amount of comonomer having shorter side chain due to the enhanced intrinsic surface energy. Peel and shear strength were also influenced by chemical properties of comonomer. The addition of comonomer, ethyl and n-butyl acrylate allows PSA sample with high peel and shear strength. This nay be explained in terms of correlation between loss modulus and glass transition temperature of PSA. As the addition of acrylic comonomers with long side chain length decreases the loss modulus of PSA, the deformation of PSA can not be inhibited.

Preparation of the Blends of Poly(amic acid) and PBO Precursor and Their Properties (Poly(amic acid)와 PBO 전구체의 블렌드 제조 및 특성)

  • Yoon, Doo-Soo;Choi, Jae-Kon;Jo, Byung-Wook
    • Polymer(Korea)
    • /
    • v.32 no.1
    • /
    • pp.77-84
    • /
    • 2008
  • The thermal properties, morphology, mechanical properties and gas permeability of the blends of poly (amic acid) (PAA) and poly (o-hydroxyamides) (PHAs) having pendant group was investigated. The 5% weight loss and major weight loss of the b)ends occurred in the ranges of $348{\sim}407^{\circ}C$ and $589{\sim}615^{\circ}C$ upon a heating process. After a thermical annealing, the tensile strength and initial modulus of blends increased $3.7{\sim}52.9%$ and $34.4{\sim}70%$ from the value of pure PAA, respectively. Especially the tensile strength and modulus of the PAA/MP-PHA=9/1 showed the highest values (97.5 MPa and 2.67 GPa, respectively), which were 53 and 70% higher than those of pure PAA. The fine PHA domains were found to be uniformly dispersed. The interfacial adhesion between PAA and PHA was identified to be good. The gas permeabilities of PAA/M-PHA blend increased with M-PHA contents.

The effect of calcium concentration and temperature on the gelation of Aigeok Polysaccharide (Aigeok polysaccharide의 겔화에 미치는 칼슘농도와 온도의 효과)

  • Lee, Hyang-Aee;Kim, Keyng-Yi
    • Korean Journal of Food Science and Technology
    • /
    • v.33 no.1
    • /
    • pp.7-11
    • /
    • 2001
  • The influence of temperature and calcium concentration on the gelation kinetics of purified Aigeok system has been investigated by small deformation oscillatory measurement. DE(degree of esterification) of the present sample was indicated of low methoxyl Aigeok polysaccharide by FT-IR. The calcium induced gelation of Aigeok has been studied. Both moduli reached the saturation value during the period of experiments. Rate constant increased with increasing calcium concentration, however above 4.08 mM calcium chloride caused a sudden drop in gel strength. The experimental result that the decrease in gel strength at high calcium concentration was seems to be phase separation or competitive inhibition between calcium ions. The storage and loss shear moduli decreased with increasing temperature. The rate constant of Aigeok system remarkably dropped above $35^{\circ}C$. Thus hydrogen bonding is prior to hydrophobic interaction for Aigeok molecule.

  • PDF

Understanding the Technical Properties of Delonix regia (HOOK.) RAF. Wood: A Lesser Used Wood Species

  • Funke Grace Adebawo;Olayiwola Olaleye Ajala;Olaoluwa Adeniyi Adegoke;Timileyin Samuel Aderemi
    • Journal of Forest and Environmental Science
    • /
    • v.39 no.1
    • /
    • pp.55-64
    • /
    • 2023
  • Properties of a lesser-used wood species were investigated to determine its potential for structural utilization. Trees of Delonix regia were felled and sampled at the base, middle and top and then sectioned to inner wood, middle wood, and outer wood for variation across the axial and radial directions. Hence, selected physical and mechanical properties as well as natural durability of D. regia along the radial and axial directions were examined. Obtained data were analyzed using analysis of variance (ANOVA) at α0.05. There was no significant difference in the Moisture content (MC) of the wood but specific gravity (SG) decreased from base to top ranging from 0.35-0.44. Water absorption, volumetric swelling, and volumetric shrinkage range from 46.18-51.86%, 2.57-4.02%, and 2.26-3.96% respectively along the axial plane. The weight loss for graveyard exposure and accelerated laboratory decay test ranged from 25.14-48.00% and 32.02-44.45% respectively. Modulus of Rupture and Modulus of Elasticity values range from 29.42-72.68 Nmm2 and 3,834.54-8,830.37 Nmm2 respectively. The SG values has confirmed the species as a medium density wood and values of other properties tested showed that the wood is dimensional stable and moderately resistance to fungi and termite. Hence, it could be used for light construction purposes such as furniture and other interior woodwork.

Wear Behavior of Silica filled Styrene-Butadiene Rubber: A Comparative Study Between the Blade-Type and Akron-Type Abrader

  • Gi-Bbeum Lee;Dongwon Kim;Seowon Lee;Seonhong Kim;Myung-Su Ahn;Bismark Mensah;Changwoon Nah
    • Elastomers and Composites
    • /
    • v.58 no.4
    • /
    • pp.179-190
    • /
    • 2023
  • The effect of the particle size and silica structure on the wear behavior of Silica/Styrene-Butadiene Rubber (SBR) compounds was investigated using a blade-type abrader and the findings were compared with those obtained with an Akron abrader. The compensated characteristic parameter (Ψc), which was the contributory factor of the combined effect of the particle size and filler structure, was introduced. This parameter was found to exhibit a linear relationship with the Young's modulus. The Young's modulus correlated more with Ψc than the uncompensated characteristic parameter (Ψ) modeled for carbon black. The wear rate and volume loss measured using a blade-type abrader and Akron abrader were respectively observed to be inversely proportional to Ψc, that is, the wear resistance of Silica/SBR compound improved as the particle size became smaller and the silica structure became intricate. The coefficient of determination (R2) obtained from the linear relationship between Ψc and wear rate was higher than those between Ψc and volume loss for the Silica/SBR compound. Thus, the blade-type abrader exhibited high potential to be used for accurately evaluating the effect of particle size and structural properties of silica on the wear behavior of SBR compounds.

Studies on the Physical Properties of Synthetic Rubber Blends Containing Rein-forcing Fillers (보강성 충전제를 함유한 합성고무 블렌드의 물리적 특성에 관한 연구)

  • Go, Jin-Hwan;Lee, Seog
    • Elastomers and Composites
    • /
    • v.33 no.4
    • /
    • pp.231-237
    • /
    • 1998
  • In order to investigate the physical properties of rubber blend compound, this experiment was carried out on the cure rate, loss tangent, reinforcement and abrasion properties of S-SBR (solution styrene-butadiene rubber) blends containing silane coupled silica and E-SBR (emulsion styrene-butadiene rubber) blends containing carbon black as a model compound. E-SBR blend showed the highest total bound rubber(TBR), while S-SBR blends showed constant TBR level regardless of rubber type. Rapid cure rate was achieved when the styrene and vinyl content of rubber microstructure decreased and TBR content of rubber compounds increased. The modulus as the index of rubber reinforcement showed the linear relation with TBR content. The large amount of PICO loss was observed when the styrene and vinyl content of rubber microstructure increased, while the small amount of PICO loss was observed when the ratio of bu-tadiene increased in the S-SBR blends with silane copuled silica. The high loss tangent at $0^{\circ}C$, the low loss tangent at $60^{\circ}C$, and the large difference of loss tangent were shown in the S-SBR blends with high styrene content compared to E-SBR blend.

  • PDF

An Analytical Study on the Performance Analysis of a Unit-In-jector System of a Diesel Engine

  • Kim, Chul-Ho;Lee, Jong-Soo
    • Journal of Mechanical Science and Technology
    • /
    • v.17 no.1
    • /
    • pp.146-156
    • /
    • 2003
  • A numerical algorithm is developed to analyze the performance of a Unit-injector (UI) System for a diesel engine. The fundamental theory of the algorithm is based on the continuity equation of fluid dynamics. The loss factors that should be seriously regarded on the continuity equation are the compressibility effect of liquid fuel, the wall friction loss in high-pressure fuel lines of the system, the kinetic energy loss of fuel in the system, and the leakage of fuel out of the control volume. For an evaluation of the developed simulation algorithm, the calculation results are compared with the experimental outputs provided by the Technical Research Center of Doowon Precision Industry Co. (DPICO) ; the maximum pressure in the plunger chamber (P$\_$p/) and total amount of fuel injected into a cylinder per cycle (Q$\_$f/) at each operational condition. The result shows that the average error rate (%) of P$\_$p/ and Q$\_$f/ are 2.90% and 4.87%, respectively, in the specified operational conditions. Hence, it can be concluded that the analytical simulation algorithm developed in this study can be reasonably applied to the performance prediction of newly designed UI system.

THE EFFECTS OF MONO-POLY ON THE SOFT DENTURE LINERS (의치상용 연성 이장재에 대한 mono-poly의 효과)

  • Heo, Ji-Hyun;Jin, Tai-Ho;Cho, Hye-Won
    • The Journal of Korean Academy of Prosthodontics
    • /
    • v.38 no.4
    • /
    • pp.484-491
    • /
    • 2000
  • Soft denture liners or conditioners may be valuable therapeutic materials. The life of these liners is short and varies, but it can be extended by the use of a mono-poly(polymethyl methacrylate coating material). This study determined whether coating three temporary soft denture liners with mono-poly affected the resiliency of soft liners, and evaluated the ability of mono-poly to prevent water absorption and alcohol loss from the underlying soft liners. $20{\times}12mm$ cylindrical specimens of Coe-Soft, Soft-Liner, Coe-Comfort soft lining materials were made and divided into two groups of mono-poly uncoated(control) and mono-poly coated specimens. Specimens were immersed in water and compressed on an instron universal testing machine and weighed at initial, 24 hours, 1 week, 2 weeks, and 4 weeks. Resiliency was determined by measuring the energy absorbed by the soft liners when stressed to a specific yield point. Mono-poly coating significantly increased the resiliency of the Soft-Liner, but had no effect on the other soft liners. Among the 3 soft liners, Soft-Liner showed the hightest resiliency and modulus of elasticity. The weight loss in Soft-Liner was the least among the 3 liners, and the weight loss in Coe-Soft was decreased by monopoly coating.

  • PDF

Spalling Characteristics of High Performance Concrete According to Changes in PP Fiber Ratio and Type of Aggregate (PP섬유 혼입율 및 잔골재 종류 변화에 따른 고성능 콘크리트의 폭렬특성)

  • Jung, Hong-Keun;Kim, Won-Ki;Pei, Chang-Chun;Han, Min-Cheol;Yang, Seng-Hwan;Han, Cheon-Goo
    • Proceedings of the Korean Institute of Building Construction Conference
    • /
    • 2009.05b
    • /
    • pp.61-64
    • /
    • 2009
  • This study is reviewed fire resistance characteristics of high strength concrete according to changes in PP fiber mixing ratio and type of fine aggregate, and the results can be summarized as follows. As fire resistance characteristics, all plain crushed sands prevented spalling regardless of increase in mixing ratio of PP fiber. Mixtures other than the plain showed satisfactory spalling prevention when 0.05 % or more of PP fiber was mixed. After the fire resistance experiment, the plain showed 5.5 % of mass loss rate when fiber was not mixed and others could not be measured. According to increase in mixing ratio of fiber, river sand with fineness modulus of 2.2 showed most satisfactory result of 34 %${\sim}$42 %. Mass loss rate after fire resistance experiment was most satisfactory at about 10 % in the plain crushed sand without mixing of fiber, and all other mixes with 0.05 % PP fiber or more showed 5${\sim}$10 % loss rate.

  • PDF