• Title/Summary/Keyword: Loss Modulus

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Steady and Dynamic Shear Rheological Properties of Buckwheat Starch-galactomannan Mixtures

  • Choi, Dong-Won;Chang, Yoon-Hyuk
    • Preventive Nutrition and Food Science
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    • v.17 no.3
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    • pp.192-196
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    • 2012
  • This study investigated the effects of galacomannans (guar gum, tara gum, and locust bean gum) on the rheological properties of buckwheat starch pastes under steady and dynamic shear conditions. The power law and Casson models were applied to describe the flow behavior of the buckwheat starch and galactomannan mixtures. The values of the apparent viscosity (${\eta}_{a,100}$), consistency index (K), and yield stress (${\sigma}_{oc}$) for buckwheat starch-galactomannan mixtures were significantly greater than those for the control, indicating that there was a high synergism of the starch with galactomannans. The magnitudes of storage modulus (G') and loss modulus (G") for the starch-galactomannan mixtures increased with increasing frequency (${\omega}$). The dynamic moduli (G', G"), and complex viscosity (${\eta}^*$) for the buckwheat starch-galactomannan mixtures were significantly higher than those for the control.

A Double Cantilever Sandwich Beam Method far Evaluating Frequency Dependence of Dynamic Modulus and Damping Factor of Rubber Materials (고무의 동탄성계수와 손실계수의 주파수 의존성을 평가하기 위한 양팔 샌드위치보 시험법의 연구)

  • 김광우;박진택;이덕보;최낙삼
    • Composites Research
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    • v.14 no.3
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    • pp.69-76
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    • 2001
  • This paper proposes a double cantilever sandwich-beam method fur evaluating the frequency dependence of dynamic characteristics of rubbers. The flexural vibration of a double cantilever sandwich-beam specimen with an inserted rubber layer was studied using a finite element simulation in combination with the sine-sweep test. Quadratic relationships of dynamic elastic modulus and material loss factor of rubbers with frequency were suggested employing the least square error method.

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Improvement of Insulation Performance of Vehicle Rubber Hoses (자동차용 고무호스의 진동 절연성능 향상에 관한 연구)

  • Jung, Heon-Seob;Min, Byung-Kwon;Lee, Seong-Hoon;Woo, Hee-Soo;Park, Hyun-Ho
    • Transactions of the Korean Society for Noise and Vibration Engineering
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    • v.22 no.9
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    • pp.837-844
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    • 2012
  • We considered an approach in terms of materials for improvement of insulation performance of vehicle rubber hoses. Ethylene propylene rubber(EPDM) for heater hoses in cooling system and acrylic rubber(AR) for intercooler hose in intake system were chosen for mixing for the vibration and noise performance. We modified EPDM and AR through changing compound of base polymer, reinforcement fillers and additives. Dynamic mechanical analysis(DMA) was used to measure viscoelastic properties such as shear modulus and loss factor($tan{\delta}$). Vehicle acceleration test was also conducted to observe indoor changes in insulation performance of hoses.

Analysis and Experiment of the Dynamic Characteristics of Rubber Materials for Anti-Vibration under Compression (압축하중을 받는 방진고무의 동특성 해석 및 실험)

  • 김국원;임종락;한용희;손희기;안태길
    • Journal of KSNVE
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    • v.8 no.5
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    • pp.900-907
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    • 1998
  • Rubber materials are extensively used in various machine design application, mainly for vibration/shock/noise control devices. Over the years an enormous effort has been put into developing procedures to provide properties of rubber material for design function. However, there are still a lot of difficulties in the understanding of dynamic characteristics of the rubber components in compression. In this paper, the dynamic characteristics of rubber materials for anti-vibration under compression were investigated. Dynamic and static tests for rubber material with 3 different hardness were performed. In dynamic tests, non-resonance method, impedance method, was used to obtain the complex modulus(storage modulus and loss factor) and the effects of static pre-strain on the dynamic characteristics were investigated. Also, a relation equation between linear dynamic and nonlinear static behavior of rubber material was discussed and its usefulness to predict their combined effects was investigated.

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Environmental aging characteristics of carbon/epoxy composite for train carbody (철도차량 차체용 탄소섬유/에폭시 복합재의 환경노화 특성 평가)

  • Oh, Jin-Oh;Yoon, Sung-Ho;Kim, Jung-Suk;Han, Seong-Ho
    • Proceedings of the KSR Conference
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    • 2007.11a
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    • pp.824-829
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    • 2007
  • Mechanical and thermal analysis properties of carbon fiber/epoxy composite for train carbody were evaluated by varying with environmental factors such as ultraviolet, temperature, and moisture. Accelerated environmental aging tester was utilized for this study. Testing temperature was set to $80^{\circ}C$ and ultraviolet was obtained through xenon-arc lamp. To consider moisture, water sprayed on specimen for 18 minutes every 2 hour. All the specimens were made of CF1263/Epoxy composite. Mechanical properties such as tensile, bending, and shear properties were evaluated through a material testing system. Also, thermal analysis properties such as storage shear modulus, loss shear modulus, and tan ${\delta}$ were measured through dynamic mechanical analyzer. Finally surfaces of the composite exposed to environmental factors were examined using a scanning electron microscope. From experimental results, those properties of CF1263/Epoxy composite were shown to be slightly decreased due to environmental factors.

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Correlation Study on Tire Belt Adhesion Properties and Durability Performance (타이어의 벨트 부착력과 내구성능 간의 상관성 연구)

  • Hong Seungjun;Lee Hoguen
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.29 no.6 s.237
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    • pp.804-808
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    • 2005
  • A pneumatic tire is made up of many flexible filaments of high modulus cord of natural textile, synthetic polymer, glass fiber, or fine hard drawn steel embedded in and bonded to a matrix of low modulus polymetric material. Adhesion property of these materials is very important in tire durability safety because belt-leaving-belt tread separation reduces the ability of a driver to control a vehicle, whether or not the separation is accompanied by a loss of air. In this study adhesion test of carcass-belt-tread is conducted on material properties of 5 PCR tire model, which are on sale in domestic market and analyzed adhesion properties. For those tire models FMVSS 109 indoor high speed durability test is conducted to analyze the correlation between adhesion force and high speed performance of tires and found the correlation between the two test results.

Estimation of polydispersity of Polyethylenes via Rheological Properties (유변학적 물성 측정을 통한 폴리에틸렌의 다분산성 예측)

  • 박오옥
    • The Korean Journal of Rheology
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    • v.10 no.3
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    • pp.137-142
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    • 1998
  • 유변물성 자료로부터 고분자의 다분산성을 예측하는 방법은 신속한 중합반응 공정 제어를 위해서 중요한 연구분야중 하나이다. 본 연구에서는 다양한 분자량과 분자량 분포를 가진 폴리에틸렌에 대한 Shroff와 macridis 가 제시한 다분산성 매개변수 ER과 ET를 구하 고 겔투과 크로마토그래피에서 얻은 Mw/Mn과의 상관관계를 조상하였다. Mw/Mn과 비례적 인 상관관계를 보여주었으나 ET는 상관성이 없는 것으로 나타났다. ER값에는 분자량 분포 도 외에 LCB의영향도 큰 것으로 나타났다. 또한 분자량 분포중에서 고분자량 부분의 미미 한 변화에도 ER이 크게 변해 GPC보다 다분산성의 변화를 더 민감하게 예측할수 있음을 알 수있었다.

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유동성 조절제가 고농도 도공액의 유동특성에 미치는 영향

  • Lee, Y.K.;Yoo, S.J.
    • Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
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    • 2008.10a
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    • pp.107-122
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    • 2008
  • 종이의 도공액이 고농도화 됨에 따라 도공액의 유동학적 특성에 대한 연구가 더욱 더 중요시 되고 있다. 기존의 합성 증점제의 경우는 단순히 증점 보수제의 기능을 가지고 있으므로 고농도/고속 도공시 블레이드하에서 점탄성적인 성질 중 팽윤에 의한 탄성의 성질이 더 강하게 남아있게 되어 다양한 도공 트러블의 원인이 될 수 있다. 최근에는 이러한 단점을 개선하기 위한 표면 흡착형 유동성 조절제가 소개되고 있다. 따라서 본 연구에서는 알카리 팽윤형 합성 증점제와 표면 흡착형 유동성 개량제로 업계에 알려진 2종의 유동성 조절제가 고농도 도공액의 점탄성적인 유동특성에 미치는 영향성을 검토하였고, PDA(Penetration Dynamic Analyzer) 모듈을 이용하여 원지에 흡수되는 흡수 거동을 관찰하였다.

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Influence of Glycidyl Methacrylate Grafted Multi-walled Carbon Nanotubes on Viscoelastic Behaviors of Polypropylene Nanocomposites

  • Shim, Young-Sun;Park, Soo-Jin
    • Carbon letters
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    • v.11 no.4
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    • pp.311-315
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    • 2010
  • In this work, the effect of glycidyl methacrylate grafted multi-walled carbon nanotubes (GMA-MWCNTs) on the viscoelastic behaviors of polypropylene (PP) based nanocomposites was studied. The GMA-MWCNTs/PP was prepared using a bravender at $200^{\circ}C$ by melt mixing as a function of GMA-MWCNT content. The viscoelastic behaviors of GMA-MWCNTs/PP nanocomposites were measured by a rheometer. It was found that the GMA-MWCNTs were homogeneously dispersed in the PP matrix. The GMA-MWCNTs/PP nanocomposites showed higher storage modulus, loss modulus, and shear viscosity compared to pure PP nanocomposites and the maximum value was shown at 2.0 wt% GMA-MWCNTs loading. These results were probably attributed to the strong interfacial interaction between the GMA-MWCNT and the PP matrix.

Structure -Properties Relations of Polypropylene/ Liquid Crystalline Polymer Blends

  • Sahoo, N.G.;Das, C.K.;Jeong, Hye-Won;Ha, Chang-Sik
    • Macromolecular Research
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    • v.11 no.4
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    • pp.224-230
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    • 2003
  • The blends of polypropylene (PP) with glass filled thermotropic liquid crystalline polymer (LCP-g) have been prepared by melt mixing techniques at different blend ratios. The thermal, dynamic mechanical, crystalline and morphological characteristics of these blends were investigated. Higher percent crystallinity was observed for 10% level of LCP-g in the blend in comparison to that of other blend ratios. The thermal stability increased with LCP-g concentration in the blend with PP. The variation of storage modulus, stiffness and loss modulus as a function of blend ratios suggested the phase inversion at the 50% level of LCP-g in the blend. The scanning electron microscopy (SEM) photographs showed the creation of voids and destruction of the fiber structures during the dynamic mechanical measurements. Processing behavior of the blends depended on the fiber forming characteristics of LCP-g, which again varied with the molding temperatures.