• Title/Summary/Keyword: Local Force

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STM Tip Catalyzed Adsorption of Thiol Molecules and Functional Group-Selective Adsorption of a Bi-Functional Molecule Using This Catalysis

  • Min, Yeong-Hwan;Jeong, Sun-Jeong;Yun, Yeong-Sang;Park, Eun-Hui;Kim, Do-Hwan;Kim, Se-Hun
    • Proceedings of the Korean Vacuum Society Conference
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    • 2011.08a
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    • pp.197-197
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    • 2011
  • In this study, in contrast with cases in which Scanning Tunneling Microscopy (STM) tip-induced reactions were instigated by the tunneling electrons, the local electric field, or the mechanical force between a tip and a surface, we found that the tungsten oxide (WO3) covered tungsten (W) tip of a STM acted as a chemical catalyst for the S-H dissociative adsorption of phenylthiol and 1-octanethiol onto a Ge(100) surface. By varying the distance between the tip and the surface, the degree of the tip-catalyzed adsorption could be controlled. We have found that the thiol head-group is the critical functional group for this catalysis and the catalytic material is the WO3 layer of the tip. After removing the WO3 layer by field emission treatment, the catalytic activity of the tip has been lost. 3-mercapto isobutyric acid is a chiral bi-functional molecule which has two functional groups, carboxylic acid group and thiol group, at each end. 3-Mercapto Isobutyric Acid adsorbs at Ge(100) surface only through carboxylic acid group at room temperature and this adsorption was enhanced by the tunneling electrons between a STM tip and the surface. Using this enhancement, it is possible to make thiol group-terminated surface where we desire. On the other hand, surprisingly, the WO3 covered W tip of STM was found to act as a chemical catalyst to catalyze the adsorption of 3-mercapto isobutyric acid through thiol group at Ge(100) surface. Using this catalysis, it is possible to make carboxylic acid group-terminated surface where we want. This functional group-selective adsorption of bi-functional molecule using the catalysis may be used in positive lithographic methods to produce semiconductor substrate which is terminated by desired functional groups.

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Performance Analysis of A Novel Inter-Networking Architecture for Cost-Effective Mobility Management Support

  • Song, Myungseok;Jeong, Jongpil
    • KSII Transactions on Internet and Information Systems (TIIS)
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    • v.8 no.4
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    • pp.1344-1367
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    • 2014
  • Mobile traffic is increasing a masse because of the propagation of the Internet and the development of wireless mobile technology. Accordingly, the Network Local Mobility Management (NETLMM) working group [1] of the Internet Engineering Task Force (IETF) has standardized Proxy Mobile IPv6 (PMIPv6) [2] as a protocol for accomplishing the transmissibility of mobile terminals. PMIPv6 is a network-led IP-based mobility management protocol, which can control terminal mobility without depending on the type of access system or the capability of the terminal. By combining PMIPv6 and the mobility of Session Initiation Protocol (SIP), we can establish terminal mobility and session mobility through a more effective route. The mobility function can be improved and the overlap of function reduced as compared to that in the case of independent operation. PMIPv6 is appropriate for a non-real-time service using TCP, and SIP is appropriate for a real-time service using RTP/UDP. Thus, in the case of a terminal using both services, an effective mobility management is possible only by using PMIPv6 together with SIP. In order to manage mobility in this manner, researches on PMIPv6-SIP are in progress. In line with this trend, this paper suggests a new PMIPv6-SIP architecture where when a mobile terminal conducts a handover, a network-led handover while maintaining the session without the addition of a special function or middleware is possible along with effective performance evaluation through mathematical modeling by comparing the delay and the packet loss that occur during the handover to the Pure-SIP.

Reduction of Prestress Loss in PSC (Prestressed Concrete) Continuous Girder by Employing Block-out Method (지점부 블록아웃 공법으로 연속화된 프리스트레스트 콘크리트 거더의 긴장력 손실 저감)

  • Shin, Kyung-Joon;Kim, Yun-Yong;Kim, Seung-Jin;Choo, Tae-Heon;Lee, Hwan-Woo
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.18 no.4
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    • pp.77-83
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    • 2014
  • Prestressed concrete girder bridge has been one of the most widely used bridges in the world because of its excellent construction feasibility, economic efficiency, serviceability, and safety. In certain situations, the prestressing tendon is supposed to be bent by the construction error and the radius of curvature at the continuous joint of PSC girders, and this leads to the loss of prestressing force. However, this kind of prestress loss is not considered in the design and construction processes. This study proves that the prestress loss occurs at the continuous joint due to the local bending of tendon by the construction error or the radius of curvature. Also, a method that can reduce this type of prestress loss is proposed, and proved by the experiment. The result shows that maximum 10% of prestress loss occurs at the continuous joint and the proposed block-out method can reduce the prestress loss ratio by maximum 5%, approximately. This means that the block-out method can enhance the prestressing efficiency of continuous PSC girder bridges.

Stiffness Characteristics according to Salt Cementation (소금 고결화에 따른 강성 특성)

  • Eom, Yong-Hun;Truong, Q. Hung;Yoo, Joung-Dong;Byun, Yong-Hoon;Lee, Jong-Sub
    • Proceedings of the Korean Geotechical Society Conference
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    • 2009.03a
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    • pp.255-264
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    • 2009
  • Soils containing vanishing materials lead changes in the microstructure of particulate media due to water inflow. Thus, dissolution renders some local unstability. As the moisture contents decease, the component of the vanished materials may affects on the cementation of paniculate materials. This cementation phenomenon has a huge influence on the stiffness, strength and stability under lower stress level. The goal of this study is to introduce the cementation effects on a compressional wave velocity, a shear wave velocity, and the resonant frequency of shear waves. The glass bead and salt water with different mole contents are used. Test results show that the changes of shear and compressional wave velocities consist of three stages. In the first region, compressional wave velocities increase and shear wave velocities decrease with a decreases in reducing water contents from 100% to 90~95%. In the second region, shear and compressional wave velocities become stable at 90~95% to 10% of the water contents. In the third region, shear and compressional wave velocities increases dramatically with a decrease in the water content due to the capillary force and cementation of salt. Furthermore, the resonant frequency of the shear waves shows similar phenomenon. Specimens prepared by glass beads and salt water are proved to be able to provide a meaningful insight in under structural behaviors of the cementation.

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Effect of soil in controlling the seismic response of three-dimensional PBPD high-rise concrete structures

  • Mortezaie, Hamid;Rezaie, Freydoon
    • Structural Engineering and Mechanics
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    • v.66 no.2
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    • pp.217-227
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    • 2018
  • In the last decades, valuable results have been reported regarding conventional passive, active, semi-active, and hybrid structural control systems on two-dimensional and a few three-dimensional shear buildings. In this research, using a three-dimensional finite element model of high-rise concrete structures, designed by performance based plastic design method, it was attempted to construct a relatively close to reality model of concrete structures equipped with Tuned Mass Damper (TMD) by considering the effect of soil-structure interaction (SSI), torsion effect, hysteresis behavior and cracking effect of concrete. In contrast to previous studies which have focused mainly on linearly designed structures, in this study, using performance-based plastic design (PBPD) design approach, nonlinear behavior of the structures was considered from the beginning of the design stage. Inelastic time history analysis on a detailed model of twenty-story concrete structure was performed under a far-field ground motion record set. The seismic responses of the structure by considering SSI effect are studied by eight main objective functions that are related to the performance of the structure, containing: lateral displacement, acceleration, inter-story drift, plastic energy dissipation, shear force, number of plastic hinges, local plastic energy and rotation of plastic hinges. The tuning problem of TMD based on tuned mass spectra is set by considering five of the eight previously described functions. Results reveal that the structural damage distribution range is retracted and inter-story drift distribution in height of the structure is more uniform. It is strongly suggested to consider the effect of SSI in structural design and analysis.

Triple Helix of University-Industry-Government Relations in Biotechnology Cluster: the Case of Singapore (바이오 클러스터에서의 트리플 힐릭스 관계 연구: 싱가포르 사례를 중심으로)

  • Nam, Jae-Geol
    • Journal of the Economic Geographical Society of Korea
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    • v.17 no.4
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    • pp.801-816
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    • 2014
  • This paper is a theoretically grounded empirical study aimed at shedding light on the Triple Helix of University-Industry-Government (U-I-G) relations in biotechnology cluster of Singapore. It questions the issue about the gap between theoretical consideration of the Triple Helix of U-I-G relations and the actual reality in biotechnology cluster, and the experience of Singapore was investigated. In terms of evolutionary perspective, biotechnology cluster in Singapore has gone through ongoing processes from a certain stage to other, and within the processes the Triple Helix nexus has been found. Analysis of the empirical study reveals significant findings: first, the government policies play a critical role in the operation of U-I-G relations rather than universities; second, therefore, the binding force of U-I-G relationships is based on the government policies being comprehensive including researchers immigration, student scholarship for local students, and tax and non-tax incentives for firms, rather than focusing on a targeted policy; third, the role of government starts from an initial stage, and it's role is ongoing processes by supporting infrastructure, human sources and continuous nourishment enabling the triple helix of U-I-G relations.

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A Study on Dynamic Behavior of Guardrail Associated with Design Variables (설계변수에 의한 가아드레일의 동력학적 거동에 관한 연구)

  • Woo, K. S.;Ko, M. G.;Cho, S. H.;Kim, W.
    • Computational Structural Engineering
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    • v.7 no.2
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    • pp.89-99
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    • 1994
  • The nonlinear dynamic behaviors of guardrail established on the local or high way have been investigated using BARRIER VII program with respect to four design variables such as section type of beams and posts, impact angle, impact velocity and vehicle weight. Computer simulation programs are sophisticated analytical models for analyzing dynamic vehicle/barrier interactions and provide a relatively inexpensive alternative to full scale crash testing. This study has been focused on the structural adequacy, occupant risk, and vehicle trajectory. For this purpose, the maximum defection and impact force have been calculated to design the clear zone and to analyze effect of impact attenuation. Also, the acceleration of vehicle and exit angle after collision have been computed to estimate the occupant risk. From this study, it is suggested that we should strengthen the design criteria of guardrail to prevent from disastrous traffic accidents.

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Thermostable Sites and Catalytic Characterization of Xylanase XYNB of Aspergillus niger SCTCC 400264

  • Li, Xin Ran;Xu, Hui;Xie, Jie;Yi, Qiao Fu;Li, Wei;Qiao, Dai Rong;Cao, Yi;Cao, Yu
    • Journal of Microbiology and Biotechnology
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    • v.24 no.4
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    • pp.483-488
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    • 2014
  • In order to improve the expression of heat-resistant xylanase XYNB from Aspergillus niger SCTCC 400264, XynB has been cloned into Pichia pastoris secretary vector pPIC9K. The XynB production of recombinant P. pastoris was four times that of E. coli, and the $V_{max}$ and specific activity of XynB reached $2,547.7{\mu}mol/mg$ and 4,757 U/mg, respectively. XynB still had 74% residual enzyme activity after 30 min of heat treatment at $80^{\circ}C$. From the van der Waals force analysis of XYNB (ACN89393 and AAS67299), there is one more oxygen radical in AAS67299 in their catalytic site, indicating that the local cavity is much more free, and it is more optimal for substrate binding, affinity reaction, and proton transfer, etc, and eventually increasing enzyme activity. The H-bonds analysis of XYNB indicated that there are two more H-bonds in the 33rd Ser of XYNB (AAS67299) than in the 33rd Ala(ACN89393 ), and two H-bonds between Ser70 and Asp67.

Optimal Design of Friction Dampers based on the Story Shear Force Distribution of a Building Structure (경주지역에서 발생한 3개 지진의 지진원 및 지진파전파 매질특성에 관한 연구)

  • Jung, Je-Won;Kim, Jun-Kyoung
    • Journal of the Earthquake Engineering Society of Korea
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    • v.10 no.1 s.47
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    • pp.33-39
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    • 2006
  • Parameters including the seismic sources and the elastic wave propagation characteristics were analysed using the observed ground motions from 3 Kyoungju region earthquakes. The Levenberg-Marquardt algorithm was applied to invert all the variables non-linearly and simultaneously with S wave energy In frequency domain. Average stress drop of 3 events and local attenuation parameter ${\kappa}$ were estimated to about 48-bar and 0.0312 respectively. Regional attenuation parameter, Qo and ${\eta}$, were also estimated to be about 417 and 0.83. ${\kappa}$ values are much higher than that of EUS, even though smaller than that of WUS. All these values resultant from this study show that there are differences in some parameters of other studios due to differences in the governing equation. of acceleration motions

A Study on the Scour Depth Equation in Bight River (하천 만곡부에서의 세굴심 산정식에 관한 연구)

  • Choi, Han-Kuy;Park, Je-Wan;Park, Soo-Jin
    • Journal of Industrial Technology
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    • v.32 no.A
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    • pp.47-55
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    • 2012
  • Currently, we only estimate the average flood water level by the cross-sections of the river using one-dimensional numerical analysis when establishing the basic plans. However, the reliability decreases when it comes to the river bend. In river bend, the difference of water-level between the inside and the outside of the river arises by centrifugal force. And it is estimated less than what it could be estimated when establishing the plan with average estimate of flood level. It is apprehended that the exterior of the river will be under-constructed when establishing the scour depth only with the mean depth. In the case of local scour of the abutment, it is difficult to estimate its depth precisely, and it tends to be over-estimated in the case of the empirical formulas. Therefore, the modification considering the deviation of the water depth of the exterior of the river bend is needed. In observing the deviation of each formula in river bend, it is found: Andru's formula for 58%, followed by the Laursen's for 26%, and the C.S.U's for 17% in pier, while it is 44% for Froehlich's formula in abutment. Under the 500CMS of the flood discharge, the deviation of the scour depth between pier and abutment was about 10 %. However, in further flood discharge, it shows 24~58% the biggest in deviation of piers. It is concluded that the scour depth estimate should be done with 2-dimensional numerical analysis.

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