• 제목/요약/키워드: Local Corrosion

검색결과 240건 처리시간 0.022초

SPPH강의 용접결함과 응력부식에 따른 음향 방출 신호의 특성 (Characterization of Acoustic Emission Signal for Welding Flaw and Stress Corrosion of SPPH Steels)

  • 김승대;정우광;이종오;정유진
    • 비파괴검사학회지
    • /
    • 제27권2호
    • /
    • pp.97-104
    • /
    • 2007
  • SPPH강의 응력부식 균열과 용접 결함의 AE 신호의 특성을 살펴보았다. 고압배관 용접부의 결함 진전을 유도하기 위하여 부식용액(NaOH)과 국부가열 후 급랭 등의 기법을 적용하여 시험체를 제작하였다. AE 신호분석 결과, 결함으로 의심되는 영역에서 발생되는 AE 신호의 진폭은 $60{\sim}75\;dB$로 나타났으며 누적 진폭 분포 특성 조사에서 용접결함만이 존재하는 시험체는 0.034, 0.034, 0.035의 기울기를 나타내며 부식을 가한 시험체는 용접결함 기구와 부식기구가 합해져 새로운 기울기인 0.040, 0.039, 0.041로 그 차이는 적으나 기울기의 증가가 확인되었다. 가압 3분 이후 각 구간에서 응력부식결함에 의한 AE신호의 검출이 용이하였고 본 실험을 통하여 급작스런 취성파괴를 일으키는 특성을 가지고 있는 응력부식균열(SCC)의 발생 예측과 피해 예방이 가능함을 알 수 있었다.

원형 강관의 국부 부식손상 수준 및 손상형태에 따른 압축강도 성능평가 (Evaluation of Compressive Strengths of Tubular Steel Members According to Corrosion Damage and Shape)

  • 안진희;남동균;이원홍;허정원;김인태
    • 한국강구조학회 논문집
    • /
    • 제28권4호
    • /
    • pp.213-222
    • /
    • 2016
  • 극심한 대기부식 환경에 설치된 강구조물은 사용기간 증가에 따라 발생한 부식손상에 따라 구조성능의 변화나 감소가 발생할 수 있다. 본 연구는 부식손상 특징에 따른 강관부재의 압축강도 성능 변화를 평가하기 위하여 강관 시험체에 인위적인 부식손상을 도입한 후 압축강도 평가시험을 통하여 부식손상에 따른 압축강도 변화 및 거동변화를 평가하였다. 부식손상의 경우 단면에 대한 국부적인 부식손상의 형태 및 위치의 영향이 있는 것으로 평가되었으며, 국부부식 위치와 부식손상으로 인한 단면이 변화부 주위에서 국부 변형에 의한 파괴가 발생하는 것으로 분석되었다. 또한 본 연구결과를 통하여 부식의 분포 및 부식의 손상량에 따른 강관부재의 압축강도 변화관계를 부식손상량에 따라 평가할 수 있도록 제시하였다

대형 상수관로 노후상태 조사 및 평가에 관한 연구 (Investigation and Assessment of the Deterioration on Aging Large Water Mains)

  • 김주환;배철호;김정현;홍성호;이경재
    • 상하수도학회지
    • /
    • 제20권4호
    • /
    • pp.545-558
    • /
    • 2006
  • The current conditions of large water mains are evaluated by deteriorations and the causes of deterioration are investigated through visual assessments in the field, mechanical tests and analysis of chemical compositions in laboratory for each pipe material, unlined cast iron pipes (CIPs), ductile iron pipes (DCIPs) and steel pipes (SPs) Tubercles and scales from internal and external corrosion of unlined cast iron pipes were identified as the causes of functional performance limitations in large water mains. It is investigated that main causes of internal and external corrosion of water pipes are from lots of depositions of organic and inorganic substances on pipe surface, concentrated pitting, and uniform corrosion by local or global exfoliation or detachment of lining and coatings of DCIPs and SPs. Internal and external corrosion depths of CIPs were higher than those of DCIPs and SPs. Consequently, total corrosion rate summed internal and external corrosion rates of CIPs also were shown to be higher than those of DCIPs and SPs. The failure time from hole generation of CIPs by total corrosion rate was predicted to be taken sixteen years, and DCIPs and SPs were twenty-six years and one hundred and fifty three years. And longitudinal deflection of investigated water mains were not happened and mechanical strengths such as tensile strength, elongation, and hardness also were mostly suited to Korea Standards. It was thought that the weakness of tensile strength of one sample(S-11) was, however, due to higher carbon contents(%) in CIPs. Pipe deterioration score of S-46 was 55.2 and was preferentially assessed to be rehabilitated.

아연 및 알루미늄이 도금된 Hot-Press Forming 강의 염화물 환경 내 전기화학적 부식 및 수소확산거동 (Electrochemical Corrosion and Hydrogen Diffusion Behaviors of Zn and Al Coated Hot-Press Forming Steel Sheets in Chloride Containing Environments)

  • 박진성;이호종;김성진
    • 한국재료학회지
    • /
    • 제28권5호
    • /
    • pp.286-294
    • /
    • 2018
  • Hot-press forming(HPF) steel can be applied successfully to auto parts because of its superior mechanical properties. However, its resistances to aqueous corrosion and the subsequent hydrogen embrittlement(HE) decrease significantly when the steel is exposed to corrosive environments. Considering that the resistances are greatly dependent on the properties of coating materials formed on the steel surface, the characteristics of the corrosion and hydrogen diffusion behaviors regarding the types of coating material should be clearly understood. Electrochemical polarization and impedance measurements reveal a higher corrosion potential and polarization resistance and a lower corrosion current of the Al-coating compared with Zn-coating. Furthermore, it was expected that the diffusion kinetics of the hydrogen atoms would be much slower in the Al-coating, and this would be due mainly to the much lower diffusion coefficient of hydrogen in the Al-coating with a face-centered cubic structure. The superior surface inhibiting effect of the Al-coating, however, is degraded by the formation of local cracks in the coated layer under severe stress conditions, and therefore further study will be necessary to gain a clearer understanding of the effect of cracks formed on the coated layer on the subsequent corrosion and hydrogen diffusion behaviors.

The Specific Case Analysis of Biomineralization Induced by Sulfate Reducing Bacteria

  • Liu, Hongwei;Qin, Shuang;Fu, Chaoyang;Xiao, Fei;Wang, Deli;Han, Xia;Wang, Tianli;Liu, Hongfang
    • Corrosion Science and Technology
    • /
    • 제16권6호
    • /
    • pp.285-293
    • /
    • 2017
  • The effects of sulfate reducing bacteria (SRB) on the corrosion and scaling of the Q235 carbon steel has been investigated in the simulated sewage water and oil field gathering pipelines production water, using scanning electron microscopy (SEM), energy dispersive x-ray spectrometry (EDS), and three-dimensional stereoscopic microscope. Results indicated that the concentration of SRB reached the maximum value on the ninth day in simulated sewage water with a large amount of scaling on the surface of specimen. In oil field gathering pipelines, a large amount of scaling and mineralization of mineral salts and thick deposition of extracellular polymeric substance (EPS) layers were also observed on the surface of specimen. The thickness of biofilm was about $245{\mu}m$ within 30 days. After adding microbicides, the thickness of corrosion products film was only up to $48-106{\mu}m$ within 30 days, suggesting that SRB could induce biomineralization. Under-deposit corrosion morphology was uniform in the absence of microbicides while local corrosion was observed in the presence of microbicides.

소둔 및 용접후열처리가 슈퍼 오스테나이트계 스테인리스강의 부식거동에 미치는 영향 (Effects of Annealing and Post-weld Heat Treatments on Corrosion Behaviors of Super Austenitic Stainless Steel)

  • 윤덕빈;박진성;조동민;홍승갑;김성진
    • Corrosion Science and Technology
    • /
    • 제20권6호
    • /
    • pp.426-434
    • /
    • 2021
  • The effect of two different annealing temperatures on the level of the second phase precipitated in the microstructure and the corrosion behaviors of super austenitic stainless steel were examined. The sample annealed at a higher temperature had a significantly lower fraction of the sigma phase enriched with Cr and Mo elements, showing more stable passivity behavior during the potentiodynamic polarization measurement. However, after the welding process with Inconel-type welding material, severe corrosion damage along the interface between the base metal and the weld metal was observed regardless of the annealing temperature. This was closely associated with the precipitation of the fine sigma phase with a high Mo concentration in the unmixed zone (UMZ) during the welding process, leading to the local depletion of Mo concentrations around the sigma phase. On the other hand, the fraction of the newly precipitated fine sigma phase in the UMZ was greatly reduced by post-weld heat treatment (PWHT), and the corrosion resistance was greatly improved. Based on the results, it is proposed that the alloy composition of welding materials and PWHT conditions should be further optimized to ensure the superior corrosion resistance of welded super austenitic stainless steel.

A Study on the Corrosion and Degradation of Boiler Tubes Steel in Fossil Power Plant

  • Baik, Young Min;Jeong, Hee Don;Kweon, Young Gak
    • Corrosion Science and Technology
    • /
    • 제5권4호
    • /
    • pp.123-128
    • /
    • 2006
  • It was analyzed the causes of boiler tube rupture due to a degradation and corrosion on the boiler tubes in fossil power plant. The experiments were carried out among samples taken from the operating facilities. The result were analyzed based on experimental results from mechanical strength, microstructure observation, and hardness measurement in order to determine the cause of local rupture on boiler tubes. In general, 2.25Cr-1Mo steel generates carbides, it is coarsened, its ductility and strength abruptly decreased as degradation is in progress, In order to confirm this phenomenon, we observed changes of the mount of Cr and Mo of carbide by carrying out EDX chemical composition analysis. The amount of Cr and Mo in the degraded material or service exposed material gradually increased the amount of Mo but initially they were almost maintained at the same amount. Furthermore, we observed that the carbide become coarsened both in the grain and at the grain boundary. Tensile test was carried out to measure a material hardness and to recognize a drop-off of hardness. Overall result for tensile strength and hardness turned out to be lower than new material and mechanical strength and hardness was degraded as the material degradation was in progress.

감육배관의 굽힘하중에 의한 손상모드와 파괴거동 평가 (Failure Mode and Fracture Behavior Evaluation of Pipes with Local Wall Thinning Subjected to Bending Load)

  • 안석환;남기우;김선진;김진환;김현수;도재윤
    • 대한기계학회논문집A
    • /
    • 제27권1호
    • /
    • pp.8-17
    • /
    • 2003
  • Fracture behaviors of pipes with local wall thinning are very important for the integrity of nuclear Power Plant. In Pipes of energy Plants, sometimes, the local wall thinning may result from severe erosion-corrosion (E/C) damage. However, the effects of local wall thinning on strength and fracture behaviors of piping system were not well studied. In this paper, the monotonic bending tests were performed of full-scale carbon steel pipes with local wall thinning. A monotonic bending load was applied to straight pipe specimens by four-point loading at ambient temperature without internal pressure. From the tests, fracture behaviors and fracture strength of locally thinned pipe were manifested systematically. The observed failure modes were divided into four types; ovalization. crack initiation/growth after ovalization, local buckling and crack initiation/growth after local buckling. Also, the strength and the allowable limit of piping system with local wall thinning were evaluated.

양극산화 후 실링처리된 알루미늄 합금의 해수 내 내식성과 캐비테이션 침식 저항성 평가 (Evaluation of Corrosion and Cavitation Erosion Resistance of Sealed Aluminum Alloy after Anodizing Treatment in Seawater)

  • 박일초;이정형;한민수;김성종
    • 한국표면공학회지
    • /
    • 제51권2호
    • /
    • pp.87-94
    • /
    • 2018
  • Various sealing techniques were applied to the anodized 5083 aluminum alloy for marine environment to reduce corrosion and cavitation erosion damage. Electrochemical experiments and cavitation erosion tests were conducted to evaluate the corrosion resistance and cavitation resistance of the anodic oxide film treated with sealing in natural seawater solution. Then, damaged surface morphology was analyzed by scanning electron microscope(SEM) and 3D microscope. As the results of the electrochemical experiments, it was observed that the surface damage of all the experimental conditions in the anodic polarization experiment was locally grown by the combination of crack and corrosion damage. In the Tafel analysis, the corrosion resistance of all sealing treatment conditions was improved compared to the anodizing. On the other hand, cavitation erosion tests showed that the anodizing and all the sealing treatment conditions generated local pit damage by cavitation erosion attack and grew to crater damage in the observation of damaged surface by SEM. Also, the weight loss and the surface damage depth measured with the experiment time presented that most of the sealing treatment conditions showed better cavitation erosion resistance than the anodizing, and they had an incubation period at the beginning of the experiment.

판폭두께비가 큰 휨부재의 부식발생에 따른 구조성능평가에 관한 연구 (Evaluation of Load-Carrying Capacity Loss due to Corrosion in Thin-Walled Section Steel Members)

  • 정경수;박만우
    • 한국강구조학회 논문집
    • /
    • 제21권6호
    • /
    • pp.619-626
    • /
    • 2009
  • 저층 장스팬 철골프레임에는 강재절감을 위해 휨모멘트 저항에 극대화한 판폭 두께비가 큰 단면 부재를 사용하고 있다. 한편, 외부환경에 노출된 강부재는 수년간을 걸쳐 부식이 진행된다. 부식에 의한 단면결손에 따른 내력감소는 판폭두께비가 큰 부재의 경우가 판폭두께비가 작은 부재에 비하여 상대적으로 크다. 또한, 부식에 의한 압축측 플랜지 및 웨브 판두께의 감소(판폭두께비 증가)에 의한 한계상태 영역이 변경될 여지도 있다. 본 논문에서, 국내 장스팬 철골프레임을 대상으로 판폭두께비가 큰 단면에 대해서 부식진행정도에 따른 모멘트-회전각관계, 초기강성, 최대내력, 최대내력이후 강성 및 에너지흡수능력에 대해서 평가를 행하였다.