• Journal of Power Electronics
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• v.18 no.4
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• pp.1127-1139
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• 2018

A reduced particle-unscented Kalman filter estimation method, along with a splice-equivalent circuit model, is proposed for the state-of-charge estimation of an aeronautical lithium-ion battery pack. The linearization treatment is not required in this method and only a few sigma data points are used, which reduce the computational requirement of state-of-charge estimation. This method also improves the estimation covariance properties by introducing the equilibrium parameter state of balance for the aeronautical lithium-ion battery pack. In addition, the estimation performance is validated by the experimental results. The proposed state-of-charge estimation method exhibits a root-mean-square error value of 1.42% and a mean error value of 4.96%. This method is insensitive to the parameter variation of the splice-equivalent circuit model, and thus, it plays an important role in the popularization and application of the aeronautical lithium-ion battery pack.

• Journal of Electrochemical Science and Technology
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• v.15 no.1
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• pp.168-177
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• 2024

Ni-rich cathode is one of the promising candidates for high-energy lithium-ion battery applications. Due to its specific capacity, easy industrialization, and good circulation ability, Ni-rich cathode materials have been widely used for lithium-ion batteries. However, due to the limitation of the co-precipitation method, including sewage pollution, and the instability of the long production cycles, developing a new efficient and environmentally friendly synthetic approach is critical. In this study, the Ni_0.91Co_0.06Mn_0.03CO₃ precursor powder was successfully synthesized by an efficient spray-drying method using carbonate compounds as a raw material. This Ni_0.91Co_0.06Mn_0.03CO₃ precursor was calcined by mixing with LiOH·H₂O (5 wt% excess) at 480℃ for 5 hours and then sintered at two different temperatures (780℃/800℃) for 15 hours under an oxygen atmosphere to complete the cathode active material preparation, which is a key component of lithium-ion batteries. As a result, LiNi_0.91Co_0.06Mn_0.03O₂ cathode active material powders were obtained successfully via a simple sintering process on the Ni_0.91Co_0.06Mn_0.03CO₃ precursor powder. Furthermore, the obtained LiNi_0.91Co_0.06Mn_0.03O₂ cathode active material powders were characterized. Overall, the material sintered at 780℃ shows superior electrochemical performance by delivering a discharge capacity of 190.76 mAh/g at 1^st cycle (0.1 C) and excellent capacity retention of 66.80% even after 50 cycles.

• Journal of the Korean Ceramic Society
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• v.39 no.1
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• pp.1-11
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• 2002

A bibliographical review of inorganic lithium ion conductors is presented with a focus on those potential candidates for lithium battery application. A wide variety of inorganic lithium ion conductors, both crystalline ceramics and non-crystalline glasses, are considered.

• The Transactions of the Korean Institute of Power Electronics
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• v.24 no.5
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• pp.365-371
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• 2019

This study shows the feasibility of the parameter of the 1st RC parallel equivalent circuit as a factor of the heat generation of lithium-ion cell. The internal resistance of a lithium-ion cell consists of ohmic and polarization resistances. The internal resistances at various SOCs of the lithium-ion cell are obtained via an electrical characteristic test. The internal resistance is inversely obtained through the amount of heat generated during the experiment. By comparing the resistances obtained using the two methods, the summation of ohmic and polarization resistances is identified as the heating factor of lithium-ion battery. Finally, the amounts of heat generated from the 2C, 3C, and 4C-rate discharge experiments and the COMSOL multiphysics simulation using the summation of ohmic and polarization resistances as the heating parameter are compared. The comparison shows the feasibility of the electrical parameters of the 1st RC parallel equivalent circuit as the heating factor.

• Proceedings of the Materials Research Society of Korea Conference
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• 2007.11a
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• pp.128.2-128.2
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• 2007

• Proceedings of the KIPE Conference
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• 2016.07a
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• pp.423-424
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• 2016

Recently, the mass production of Energy storage system (ESS) is actively perform around world. Energy storage system is a technique that stores power to energy storage device to supply energy into grid and load at peak-load. Therefore, the efficient energy management is available by using ESS system. The life of Lithium-ion battery is varied corresponding to the power usage, especially selected depth of discharge (DOD). The lifetime of battery is the one of the most issue of the ESS system because of its stability and reliability. Therefore, lifetime management of battery and power converter of ESS module is required. In this paper, the battery lifetime management method estimating residual power and lifetime of lithium ion battery of ESS system is proposed. Also, total avenue prediction of ESS system is simulated considering the total lifetime of battery.

• Proceedings of the KIEE Conference
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• 2005.05a
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• pp.275-277
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• 2005

In a lithium-ion battery which is being used in many portable electronic goods, electrolyte is disaggregated and then the gas is happened when electric charging volt is over the 4.5V. So, the pressure on the safety valve is increased and electrolyte is leaked out in the cell. It leads to the risk of explosion. On the other hand, in the case which the battery is discharged excessively, the negative pole is damaged and the performance of the battery is deteriorated. The protection module of a lithium-ion battery is used for preventing such risk and the inspection system is needed to check the performance of such protection module. In this research, a PC-based auto inspection system is developed for the inspection of a battery protection module using Dallas chipset. In the inspection system, AVRl28 chip is used as a controller and the communication protocol is developed for the data communication between the protection module and the AVR128 chip. And GPIB interface is used for the control of measuring devices. Also, MMI environment is developed using LabView for convenient monitoring by the tester.

• Proceedings of the KIPE Conference
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• 2015.11a
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• pp.7-8
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• 2015

In this paper a cell-to-cell fast charge balancing circuit for the Lithium-Ion battery module is proposed. In the proposed topology the energy in a high voltage cell is transferred directly to a low voltage cell through the operation of the dc-dc converter. Furthermore, the charge balancing can be performed regardless of the battery operation whether it is being charged, discharged or relaxed. The monitoring circuit composed of a DSP and a battery monitoring IC is designed to monitor the cell voltage and detect the inferior cell thereby protecting the battery module from failure. In order to demonstrate the performance of the proposed topology, a prototype circuit was designed and applied to 12 Lithium-Ion battery module. It has been verified with the experiments that the charge equalization time of the proposed method was shorter compared with those of other methods.

• Journal of Industrial Technology
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• v.43 no.1
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• pp.15-23
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• 2023

Lithium-ion batteries are predominantly employed in electric vehicles and energy storage devices, offering the advantage of high energy density. However, they are susceptible to efficiency degradation when operated at high temperatures due to their sensitivity to the external environment. In this study, we conducted experiments using an indirect cooling method to prevent thermal runaway and explosions in lithium-ion batteries. The results were validated by comparing them with heat transfer simulations conducted through a commercial finite element analysis program. The experiments included single-cell exothermic tests and cooling experiments on a battery pack with 10 cells connected in series, utilizing 21700 lithium-ion batteries. To block external temperature influences, the experimental environment featured an extrusion method insulation in the environmental chamber. The cooling system, suitable for indirect cooling, was constructed with copper tubes and pins. The heat transfer analysis began by presenting a single-cell heating model using commercial software, which was then employed to analyze the heating and cooling of the battery pack.

• Journal of Industrial Technology
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• v.42 no.1
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• pp.7-12
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• 2022

High nickel layered oxide cathodes are gaining increasing attention for lithium-ion batteries due to their higher energy density and lower cost compared to LiCoO₂. However, they suffer from the formation of residual lithium on the surface in the form of LiOH and Li₂CO₃ on exposure to ambient air. The residual lithium causes notorious issues, such as slurry gelation during electrode preparation and gas evolution during cell cycling. In this review, we investigate the residual lithium issues through its impact on cathode slurry instability based on deformed polyvinylidene fluoride (PVdF) as well as its formation and reduction mechanism in terms of inherently off-stoichiometric synthesis of high nickel cathodes. Additionally, new analysis method with anhydrous methanol was introduced to exclude Li⁺/H⁺ exchange effect during sample preparation with distilled water. We hope that this review would contribute to encouraging the academic efforts to consider practical aspects and mitigation in global high-energy-density lithium-ion battery manufacturers.