• Electrical & Electronic Materials
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• v.8 no.4
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• pp.487-494
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• 1995

The purpose of this study is to research and develop solid polymer electrolyte(SPE) for Li secondary battery. We investigated the effects of lithium salts, plasticizer addition, temperature dependence of conductivity and electrochemical stability window of polyethylene oxide(PEO) electrolytes. PEO electrolyte completed with LiCIO$\_$4/ shows the better conductivity than the others. PEO-LiCIO$\_$4/ electrolyte, when EO/Li$\^$+/ ratio is 8, showed adequate conductivity around room temperature. By adding propylene carbonate and ethylene carbonate to PEO-LiCIO$\_$4/ electrolyte, its conductivity was higher than that of PEO-LiCIO$\_$4/ without those. Also PEO$\_$8/LiCIO$\_$4/ electrolyte remains stable up to 4.5V vs. Li/Li.

• Transactions of Materials Processing
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• v.13 no.4
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• pp.307-318
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• 2004

Rectangular drawn case with extreme aspect ratio is widely used for electrical parts such as a lithium-ion battery container, semi-conductor case and so on. Additionally, from the recent trend towards miniaturization of the multi-functional mobile device, demands for rectangular case with the narrow width are increased. In this study, numerical and experimental approaches for the multi-stage deep drawing process have been carried out. Based on the research results of the width of 5.95mm model, finite element analysis for storage case of rectangular cup type was verified to the width of 4.95mm. Also, a series of manufacturing experiments for rectangular case is conducted and the deformed configuration of the rectangular drawn case are investigated by comparing with the results of the numerical analysis. And the modification of the initial blank is performed to minimize the trimmed material amount. By the application of the modified blank, the sound shape of the deformed parts is improved.

• Proceedings of the Korean Institute of Surface Engineering Conference
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• 2017.05a
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• pp.146-146
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• 2017

산화비스무트는 리튬이온과의 반응에서 현재 상용화된 그래파이트보다 높은 이론용량을 가지고 있으나, 리튬이온과의 반응에서 비교적 큰 부피팽창 특성을 가져 리튬이차전지의 음극재로서 상용화가 어려운 단점이 있다. 본 연구에서는, 이러한 문제점을 개선하기 위하여 양극산화법을 통해 충 방전시 부피팽창 변화가 매우 적은 타이타니아 나노튜브를 제조한 후, 그 위에 스프레이 방법으로 산화비스무트를 코팅하여 두 물질의 복함체를 만듦으로써 용량과 구조적 안정성을 향상시키는 방법을 소개한다. 음극재의 구조적 특성은 고분해능 주사전자현미경 (HR-SEM), 고분해능 엑스선 회절분석기(XRD)를 통해 조사하였으며, 전기화학 임피던스 분광법 (EIS), 순환전류법 (CV), 충 방전 싸이클 분석을 통해 리튬이차전지의 작동원리와 보다 향상된 성능을 규명하였다.

• Journal of Electrochemical Science and Technology
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• v.8 no.2
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• pp.162-168
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• 2017

$LiNi_xCo_yMn_zO_2$ cathode materials have been the focus of much attention because of their high specific capacity. However, because of the poor interfacial stability between cathodes and electrolytes, the cycling performance of these materials fades rapidly, especially at high temperatures. In the present paper, we propose the use of tris(trimethylsilyl) phosphate (TMSPO), which contains phosphate and silyl functional groups, as a functional additive in electrolytes. The addition of TMSPO resulted in the formation of cathode electrolyte interphase (CEI) layers on the surfaces of the cathodes and effectively suppressed electrolyte decomposition reactions, even at high temperatures. As a result, cells cycled with TMSPO exhibited remarkable capacity, which remained after 50 cycles (82.0%), compared to cells cycled without TMSPO (64.6%).

• Proceedings of the KIPE Conference
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• 2018.07a
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• pp.246-248
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• 2018

본 논문에서는 배터리 수명의 지표인 SOH(state of health) 추정 시 배터리 노화에 따라 방전 용량의 급격한 변화가 발생하면 SOH도 변화하게 된다. 이로 인해 잘못된 SOH의 정보를 가지고 오게 되며 배터리의 안정성 및 신뢰성에 문제가 된다. 본 논문에서는 방전 용량과 내부 저항의 선형적 관계를 확인하고, 방전 용량과 내부저항을 고려한 단순선형회귀모형(simple linear regression model)을 모델링하였다. 방전 용량의 급격한 변화나 오프라인 기반 방전 용량을 측정함에 어려움이 있는 경우 단순선형회귀모형에 따라 방전 용량을 추정하여 SOH를 보정하는 기법을 제안하고 이에 대한 검증을 수행하였다.

• Bulletin of the Korean Chemical Society
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• v.32 no.1
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• pp.105-108
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• 2011

The cycling behavior of $Li_4Ti_5O_{12}$ electrode in the ionic liquid (IL)-based electrolytes containing 1-butyl-1-methylpyrrolidinium bis(trifluoromethanesulfonyl) imide and a small amount of additive (vinylene carbonate, ethylene carbonate, fluoroethylene carbonate) was investigated. The $Li_4Ti_5O_{12}$ electrode in the IL electrolyte with an additive exhibited reversible cycling behavior with good capacity retention. Electrochemical impedance spectroscopy and FTIR studies revealed that an electrochemically stable solid electrolyte interphase was formed on the $Li_4Ti_5O_{12}$ electrode in the presence of vinylene carbonate and ethylene carbonate during cycling.

• Journal of the Korean Electrochemical Society
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• v.5 no.4
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• pp.197-201
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• 2002

In this study, a gel polymer electrolyte was prepared from urethane acrylate and its electrochemical performances were evaluated. And, $LiCoO_2/GPE/graphite$ cells were prepared and their performances depending on discharge currents and temperatures were evaluated. The precursor containing $5 vol\%$ curable mixture had a low viscosity relatively. Ionic conductivity of the gel polymer electrolyte at room temperature and $-20^{\circ}C$ was ca. $5.9\times10^{-3}S{\cdot}cm^{-1}\;and\;1.7\times10^{-3}S{\cdot}cm^{-1}$, respectively. GPE showed electrochemical stability up to potential of 4.5V vs. $Li/Li^+.LiCoO_2/GPE/graphite$ cell showed a good high-rate and a low-temperature performance.

• Journal of the Korean Electrochemical Society
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• v.6 no.3
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• pp.174-177
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• 2003

Electric double-layer capacitors based on charge storage at the interface between a high surface area activated carbon electrode and an electrolyte solution are characterized by their long cycle-life and high power density in comparison with batteries. However, energy density of electric double-layer capacitors obtained at present is about 6 Wh/kg at a power density of 500W/kg which is smaller as compared with that of batteries and limits the wide spread use of the capacitors. Therefore, a new capacitor that shows larger energy density than that of electric double-layer capacitors is proposed. The new capacitor is the hybrid capacitor consisting of activated carbon cathode, carbonaceous anode and an organic electrolyte. Maximum voltage applicable to the cell is over 4.2V that is larger than that of the electric double-layer capacitor. As a result, discharged energy density on the basis of stacked volume of electrode, current collector and separator is more than 18Wh/l at a power density of 500W/l.

• Proceedings of the KIPE Conference
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• 2019.11a
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• pp.192-193
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• 2019

본 논문에서는 배터리의 장기적인 노화에 따른 파라미터 분석을 C-rate에 따라서 진행하였다. 이를 위해 배터리 등가회로 모델 기반의 파라미터를 추출하여 분석하였으며 이를 통해 배터리가 노화함에 따라 나타나는 특성을 분석한다.

• Proceedings of the KIPE Conference
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• 2019.11a
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• pp.188-189
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• 2019

본 논문은 리툼이온 배터리의 화재로 이어질 수 있는 전기적 위협(Electrical abuse) 상황 중 외부단락 상황을 재현하였다. 배터리의 초기 온도상태(60℃, 50℃, 25℃, 15℃)와 외부단락 상황에서 배터리의 최대 발열량과의 상관관계를 분석하였다. 초기온도 60℃ 보다 50℃에서 가장 큰 발열량을 보였다. 초기온도 60℃에서 더 큰 단락전류가 측정되었으나 전류가 인가되는 시간은 50℃에서 더 길어 단락실험간 최대 발열은 온도상태 50℃에서 최대 온도 117℃로 가장 크게 측정되었다.