• Membrane Journal
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• v.34 no.3
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• pp.163-171
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• 2024

Growing demand on clean energy to control environmental pollution is growing rapidly. Rechargeable battery such as lithium ion battery is excellent source of clean energy but there is rapid depletion of lithium metal due to high demand and supply mismatch. Recovery of the precious metal from the battery waste is one of the possible solution along with the environmental pollution control. Membrane based separation method is highly successful commercial process available to recover lithium from the waste. This work will cover various methods reported recently and will be compiled in the form of a review.

• Proceedings of the IEEK Conference
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• 2001.10a
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• pp.252-256
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• 2001

The rapid development of communication equipment and information processing technology has led to a constant improvement in cordless communication. Lithium ion batteries used in cellular phones and laptop computers, in particular, have been in the forefront of the above revolution. These batteries use high value added raw materials and have a high and stable energy output and are increasingly coming into common use. The development of the material for the negative terminal has led to an improvement in the quality and efficiency of the batteries, whereas a reduction in the cost of the battery by researching new materials for the positive anode has become a research theme by itself. These long life batteries, it is being increasingly realized, can have value added to them by recycling. Research is increasingly being done on recycling the aluminum case and the load casing for the negative diode. This paper aims to introduce the current situation of recycling of lithium ion batteries. 1. Introduction 2. Various types of batteries and the situation of their recycling and the facts regarding recycling. 3. Example of cobalt recycling from waste Lithium ion secondary cell. 3-1) Flow Chart of Lithium ion battery recycling 3-2) Materials that make a lithium ion secondary cell. 3-3) Coarse grinding of Lithium ion secondary cell, and stabilization of current discharge 3-4) Burning 3-5) Grinding 3-6) Magnetic Separation 3-7) Dry sieving 3-8) Dry Classifying 3-9) Content Ratio of recycled cobalt parts 3-10) Summary of the Line used for the recovery of Cobalt from waste Lithium ion battery. 4. Conclusion.

• International Journal of Internet, Broadcasting and Communication
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• v.15 no.3
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• pp.118-121
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• 2023

Recently, green energy support policies have been announced around the world in accordance with environmental regulations, and asthe market grows rapidly, demand for batteries is also increasing. Therefore, various methodologies for battery diagnosis and recycling methods are being discussed, but current accurate life prediction of batteries has limitations due to the nonlinear form according to the internal structure or chemical change of the battery. In this paper, CS2 lithium-ion battery measurement data measured at the A. James Clark School of Engineering, University of Marylan was used to predict battery performance with high accuracy using a convolutional neural network (CNN) model among deep learning-based models. As a result, the battery performance was predicted with high accuracy. A data structure with a matrix of total data 3,931 ☓ 19 was designed as test data for the CS2 battery and checking the result values, the MAE was 0.8451, the RMSE was 1.3448, and the accuracy was 0.984, confirming excellent performance.

• Resources Recycling
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• v.33 no.1
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• pp.15-21
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• 2024

The demand for electric vehicles powered by lithium-ion batteries is continuously increasing. Recovery of valuable metals from waste lithium-ion batteries will be necessary in the future. This research investigated the effect of reaction temperature on the lithium recovery ratio from hydrogen reduction followed by water leaching from lithium-ion battery NCM-based cathode materials. As the reaction temperature increased, the weight loss ratio observed after initiation increased rapidly owing to hydrogen reduction of NiO and CoO; at the same time, the H₂O amount generated increased. Above 602 ℃, the anode materials Ni and Co were reduced and existed in the metallic phases. As the hydrogen reduction temperature was increased, the Li recovery ratio also increased; at 704 ℃ and above, the Li recovery ratio reached a maximum of approximately 92%. Therefore, it is expected that Li can be selectively recovered by hydrogen reduction as a waste lithium-ion battery pretreatment, and the residue can be reprocessed to efficiently separate and recover valuable metals.

• Resources Recycling
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• v.17 no.2
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• pp.30-35
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• 2008

Mixed acidophilic bacteria were approached for leaching of cobalt and lithium from wastes of lithium ion battery industries. The growth substrates for the mixed mesophilic bacteria are elemental sulfur and ferrous ion. Bioleaching of the metal was due to the protonic action of sulfate ion on the metals present in the waste. It was investigated that bioleaching of cobalt was faster than lithium. Bacterial action could leach out about 80 % of cobalt and 20 % of lithium from the solid wastes within 12 days of the experimental period. Higher solid/liquid ratio was found to be detrimental for bacterial growth due to the toxic nature of the metals. At high elemental sulfur concentration, the sulfur powder was observed to be in undissolved form and hence the leaching rate also decreased with increase of sulfur amount.

• Journal of Powder Materials
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• v.21 no.4
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• pp.286-293
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• 2014

The electrochemical properties of cells assembled with the $LiNiO_2$ (LNO) recycled from cathode materials of waste lithium secondary batteries ($Li[Ni,Co,Mn]O_2$), were evaluated in this study. The leaching, neutralization and solvent extraction process were applied to produce high-purity $NiSO_4$ solution from waste lithium secondary batteries. High-purity NiO powder was then fabricated by the heat-treatment and mixing of the $NiSO_4$ solution and $H_2C_2O_4$. Finally, $LiNiO_2$ as a cathode material for lithium ion secondary batteries was synthesized by heat treatment and mixing of the NiO and $Li_2CO_3$ powders. We assembled the cells using the $LiNiO_2$ powders and evaluated the electrochemical properties. Subsequently, we evaluated the recycling possibility of the cathode materials for waste lithium secondary battery using the processes applied in this work.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.19 no.9
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• pp.326-332
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• 2018

Korea faces major changes in energy policy, which include eco-friendly and zero-nuclear power. On the other hand, there are very few policies for the waste-management of mid- to large-sized lithium-ion batteries, such as electric car batteries and energy storage systems, which are expected to increase explosively due to such energy policy changes. Therefore, this study estimated the amount of mid- to large-sized lithium ion batteries waste and performed economics analysis of a middle and large sized secondary battery recycling project. Based on the results, a policy alternative for the revitalization of the related lithium-ion battery recycling industry is suggested. As a result, the B / C ratio of a domestic mid - to large - sized lithium ion battery recycling project is 1.06, in which the benefit is higher than the cost, so the business is economic feasible. Although the recycling project's economic efficiency is high, the recycling industry has not been activated in Korea because the domestic demand for rechargeable batteries recycling is very low. To solve this problem, this study proposes a plan to activate the industry by adding lithium secondary batteries to the EPR (Extended Producer Responsibility) items.

• The Journal of the Convergence on Culture Technology
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• v.9 no.3
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• pp.727-730
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• 2023

The operation of electric automatic windows is used in harsh environments, and the energy density decreases as charging and discharging are repeated, and as soundness deteriorates due to damage to the internal separator, the vehicle's mileage decreases and the charging speed slows down, so about 5 to 10 Batteries that have been used for about a year are classified as waste batteries, and for this reason, as the risk of battery fire and explosion increases, it is essential to diagnose batteries and estimate SOH. Estimation of current battery SOH is a very important content, and it evaluates the state of the battery by measuring the time, temperature, and voltage required while repeatedly charging and discharging the battery. There are disadvantages. In this paper, measurement of discharge capacity (C-rate) using a waste battery of a Tesla car in order to predict SOH estimation of a lithium-ion battery. A Support Vector Machine (SVM), one of the machine models, was applied using the data measured from the waste battery.

• Clean Technology
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• v.27 no.1
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• pp.33-38
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• 2021

Demand for lithium-based secondary batteries is greatly increasing with the explosive growth of related industries, such as mobile devices and electric vehicles. In Korea, there are several top-rated global lithium-ion battery manufacturers accounting for 40% of the global secondary battery business. Most discarded lithium secondary batteries are recycled as scrap to recover valuable metals, such as Nickel and Cobalt, but residual wastes are disposed of according to the residual lithium-ion concentration. Furthermore, there has not been an attempt on the possibility of water discharge system contamination due to the concentration of lithium ions, and the effluent water quality standards of public sewage treatment facilities are becoming stricter year after year. In this study, the as-received waste water generated from the cathode electrode coating process in the manufacturing of high-nickel-based NCM cathode material used for high-performance and long-term purposes was analyzed. We suggested a facile recycling process chart for waste water treatment. We revealed a correlation between lithium-ion concentration and pH effect according to the proposed waste water of each recycling process through analyzing standard water quality tests and daphnia ecological toxicity. We proposed a realistic waste water treatment plan for lithium electrode manufacturing plants via comparison with other industries' ecotoxicology.

• Journal of Powder Materials
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• v.31 no.2
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• pp.163-168
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• 2024

As the demand for lithium-ion batteries for electric vehicles is increasing, it is important to recover valuable metals from waste lithium-ion batteries. In this study, the effects of gas flow rate and hydrogen partial pressure on hydrogen reduction of NCM-based lithium-ion battery cathode materials were investigated. As the gas flow rate and hydrogen partial pressure increased, the weight loss rate increased significantly from the beginning of the reaction due to the reduction of NiO and CoO by hydrogen. At 700 ℃ and hydrogen partial pressure above 0.5 atm, Ni and Li₂O were produced by hydrogen reduction. From the reduction product and Li recovery rate, the hydrogen reduction of NCM-based cathode materials was significantly affected by hydrogen partial pressure. The Li compounds recovered from the solution after water leaching of the reduction products were LiOH, LiOH·H₂O, and Li₂CO₃, with about 0.02 wt% Al as an impurity.