• 제목/요약/키워드: Liquid transfer

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금속수소화물 기반 수소저장시스템의 열관리 인자 조사 (Investigation of Thermal Management Parameters of Metal Hydride Based Hydrogen Storage System)

  • 박주식;김종원;배기광;정성욱;강경수
    • 한국수소및신에너지학회논문집
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    • 제29권3호
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    • pp.251-259
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    • 2018
  • Metal hydride based hydrogen storage under moderate temperature and pressure gives the safety advantage over the gas and liquid storage methods. Still solid-state hydrogen storage including metal hydride is below the DOE target level for automotive applications, but it can be adapted to stationary or miliary application reasonably. In order to develop a modular solid state hydrogen storage system that can be applied to a distributed power supply system composed of renewable energy - water electrolysis - fuel cell, the heat transfer and hydrogen storage characteristics of the metal hydride necessary for the module system design were investigated using AB5 type metal hydride, LCN2 ($La_{0.9}Ce_{0.1}Ni_5$). The planetary high energy mill (PHEM) treatment of LCN2 confirmed the initial hydrogen storage activation and hydrogen storage capacity through surface modification of LCN2 material. Expanded natural graphite (ENG) addition to LCN2, and compression molding at 500 atm improved the thermal conductivity of the solid hydrogen storage material.

열복사를 적용한 드럼 건조기의 건조 메커니즘 분석 및 성능 예측에 관한 연구 (Numerical Investigation of the Effect of IR Heating on Drying Mechanism in a Tumble Dryer)

  • 최철진;장정현;김종민;김만영
    • 대한기계학회논문집B
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    • 제34권3호
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    • pp.219-228
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    • 2010
  • 텀블형 드럼 건조기의 적외선 건조 과정동안의 온도 및 수분량의 변화를 예측할 수 있는 2 차원 수학적 모델을 개발하였다. 본 모델에서는 건조대상 물질의 액체 수분의 이동과 건조공기의 유동 및 열전달을 고려하였다. 유체의 유동과 열전달 현상, 그리고 복사열전달은 유한체적법을 이용하여 해석하였다. 텀블 건조기의 2 차원 모델을 모사하기 위한 지배방정식을 소개한 후 적외선 히터, 히터의 온도, 그리고 가열 패턴에 따른 수치해석을 수행하였고, 적외선 히터를 도입함으로써 건조시간을 감소시킬 수 있음을 제시하였다.

항동해제에 따른 생쥐 동결수정란의 생존율및 체외발달율 (Survival and In Vitro Development Rate of Frozen Mouse Embryos in Various Cryoprotectants)

  • 차상헌;선우재근;박효숙;이임순;조태호
    • Clinical and Experimental Reproductive Medicine
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    • 제17권2호
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    • pp.167-172
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    • 1990
  • This study was carried out to clarify the effects of various kinds of cryoprotectants which were frequently used in freezing embryos of domestic animals on the survival of frozen-thawed mouse embryos. Mouse embryos were collected by hyperstimulation induction of ICR mouse. The samples were slowly cooled ($l^{\circ}C/min$) to temperatures between $-7^{\circ}C$ and $-30^{circ}C$ before direct transfer to liquid nitrogen ($-196^{\circ}C$) and thawed rapidly ($-500^{\circ}C$/min). As cryoprotectants, Glycerol, DMSO, Ethylene glycol and Propylene glycol were used and applied each 2 cell, 8 cell, morula in embryo stage. After normal mouse embryos developed to blastocyst by in vitro culture, we observed recovery rate and developing rate of embryos at thawing. The results obtained in these experiments were as follows : 1. The in vitro development rate from the frozen-thawed 2 cell embryos to the blastocyst were 67.7% in ethylene glycol, 65.7% in Propylene glycol, 55.2% in glycerol and 50.0% in DMSO respectively. 2. The in vitro development rate from the frozen-thawed 8 cell embryos to the blastocyst were 83.6% in DMSO, 75.7% in glycerol, 52.2% in propylene glycol respectively. 3. The in vitro development rate from the frozen-thawed morula to the blastocyst were 84.2% in glycerol, 80.0% in DMSO, 66.6% in propylene glycol and 55.2% in ethylene glycol respectively.

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Evaluating Plant Uptake of Veterinary Antibiotics with Hydroponic Method

  • Park, Saet Byel;Kim, Sun Ju;Kim, Sung Chul
    • 한국토양비료학회지
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    • 제49권3호
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    • pp.242-250
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    • 2016
  • Veterinary antibiotics (VAs) has been used to treat animal disease and to increase animal weight as growth promoter. However, abused usage of VAs can cause production of antibiotic resistance genes (ARGs) in the environment and additionally, residual of VAs in soil can be transferred into crops. Therefore, main objective of this research was to examine bioaccumulation of VAs in sprouts (red cabbage, Brassica Olearacea L. var. Capitata f. rubra and red radish, Raphanus sativus) with hydroponic method. Total of 7 VAs in 2 different classes of VAs (tetracyclcines: tetracycline, oxytetracycline, chlortetracycline, sulfonamides: sulfamethoxazole, sulfamethazine, sulfamethiazole, macrolides: tylosin) were evaluated and experiment was conducted with solid phase extraction (SPE)/high performance liquid chromatography tandem mass spectrometry (HPLC/MS/MS). Initial spiked concentration of 7 VAs was $5mg\;L^{-1}$ and cultivation period was 8 days. Result showed that growth of sprouts was inhibited about 23-27% when VAs was introduced. Amount of bioaccumulated VAs was also differed depending on class of VAs. The highest amount of bioaccmulated VAs was tetracycline and sulfamethoxazole in each class with a concentration of 4.05, $7.73mg\;kg^{-1}$ respectively. Calculated transfer ratio of VAs into crops was also ranged 0.38-54.27%. Overall, bioaccumulation of VAs in crops can be varied depending on crop species and class of VAs. However, further research should be conducted to verify bioaccumulation of VAs in crops in the soil environment.

IODINE REMOVAL EFFICIENCY IN NON-SUBMERGED AND SUBMERGED SELF-PRIMING VENTURI SCRUBBER

  • Ali, Majid;Yan, Changqi;Sun, Zhongning;Gu, Haifeng;Wang, Junlong;Khurram, Mehboob
    • Nuclear Engineering and Technology
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    • 제45권2호
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    • pp.203-210
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    • 2013
  • The objective of this conducted research is to study the iodine removal efficiency in a self-priming venturi scrubber for submerged and non-submerged operating conditions experimentally and theoretically. The alkaline solution is used as an absorbent, which is prepared by dissolving sodium hydroxide (NaOH) and sodium thiosulphate ($Na2S_2O_3$) in water to remove the gaseous iodine ($I_2$) from the gas. Iodine removal efficiency is examined at various gas flow rates and inlet concentrations of iodine for submerged and non-submerged operating conditions. In the non-submerged venturi scrubber, only the droplets take part in iodine removal efficiency. However, in a submerged venturi scrubber condition, the iodine gas is absorbed from gas to droplets inside the venturi scrubber and from bubbles to surrounding liquid at the outlet of a venturi scrubber. Experimentally, it is observed that the iodine removal efficiency is greater in the submerged venturi scrubber as compare to a non-submerged venturi scrubber condition. The highest iodine removal efficiency of $0.99{\pm}0.001$ has been achieved in a submerged self-priming venturi scrubber condition. A mathematical correlation is used to predict the theoretical iodine removal efficiency in submerged and non-submerged conditions, and it is compared against the experimental results. The Wilkinson et al. correlation is used to predict the bubble diameter theoretically whereas the Nukiyama and Tanasawa correlation is used for droplet diameter. The mass transfer coefficient for the gas phase is calculated from the Steinberger and Treybal correlation. The calculated results for a submerged venturi scrubber agree well with experimental results but underpredicts in the case of the non-submerged venturi scrubber.

Enzymatic Synthesis and Characterization of Galactosyl Trehalose Trisaccharides

  • Kim, Bong-Gwan;Lee, Kyung-Ju;Han, Nam-Soo;Park, Kwan-Hwa;Lee, Soo-Bok
    • Food Science and Biotechnology
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    • 제16권1호
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    • pp.127-132
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    • 2007
  • [ ${\alpha},\;{\alpha}$ ]-Trehalose was efficiently modified by a transgalactosylation reaction of Escherichia coli ${\beta}-galactosidase$ using lactose as a donor to yield two galactosyl trehalose trisaccharides. The reaction products of trehalose by the enzyme were observed by thin layer chromatography (TLC) and high performance anion exchange chromatography (HPAEC) and were purified by BioGel P2 gel permeation chromatography and recycling preparative HPLC. Liquid chromatography-mass spectrometry (LC-MS) and ^{13}C$ nuclear magnetic resonance (NMR) analyses revealed that the structures of the main products were $6^2-{\beta}-D-galactosyl$ trehalose (1) and $4^2-{\beta}-D-galactosyl$ trehalose (2). A reaction of 30%(w/v) trehalose and 15%(w/v) lactose at pH 7.5 and $45^{\circ}C$ resulted in a total yield of approximately 27-30% based on the amount of trehalose used. The galactosyl trehalose products were not hydrolyzed by trehalose. In addition the mixture of transfer products (9:1 ratio of 1 to 2) showed higher thermal stability than glucose, lactose, and maltose, but less than trehalose, against heat treatment over $100^{\circ}C$ at pH 4 and 7. It also exhibited better thermal stability than sucrose at pH 4 alone.

300MW급 IGCC를 위한 건식 분류층 석탄 가스화 공정의 동적 상태 모사 (The Process Simulation of Entrained Flow Coal Gasification in Dynamic State for 300MW IGCC)

  • 김미영;주용진;최인규;이중원
    • 한국수소및신에너지학회논문집
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    • 제21권5호
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    • pp.460-469
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    • 2010
  • To develop coal gasfication system, many studies have been actively conducted to describe the simulation of steady state. Now, it is necessary to study the gasification system not only in steady state but also in dynamic state to elucidate abnormal condition such as start-up, shut-down, disturbance, and develop control logic. In this study, a model was proposed with process simulation in dynamic state being conducted using a chemical process simulation tool, where a heat and mass transfer model in the gasifier is incorporated, The proposed model was verified by comparison of the results of the simulation with those available from NETL (National Energy Technology Laboratory) report under steady state condition. The simulation results were that the coal gas efficiency was 80.7%, gas thermal efficiency was 95.4%, which indicated the error was under 1 %. Also, the compositions of syngas were similar to those of the NETL report. Controlled variables of the proposed model was verified by increasing oxygen flow rate to gasifier in order to validate the dynamic state of the system. As a result, trends of major process variables were resonable when oxygen flow rate increased by 5% from the steady state value. Coal flow rate to gasifier and quench gas flow rate were increased, and flow rate of liquid slag was also increased. The proposed model in this study is able to be used for the prediction of gasification of various coals and dynamic analysis of coal gasification.

Pilot-scale 회전식 드럼 바이오필터를 이용한 Styrene 제거 (Removal of Gaseous Styrene using a Pilot-Scale Rotating Drum Biotrickling Filter)

  • 황재웅;임지성;장석진;이은열;최차용;박성훈
    • KSBB Journal
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    • 제21권3호
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    • pp.188-193
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    • 2006
  • 본 연구에서는 신 개념의 바이오필터 시스템인 RDBF를 이용하여 기상의 styrene을 제거하고자 하였다. 다양한 운전조건에서 시스템의 성능을 평가하고, 진공흡입을 통해 과다성장 미생물을 제어하고자 하였다. RDBF에서는 sheet 형태의 충진 담체를 사용하므로 영양원 및 공기의 균일한 공급이 가능하였고, 빠른 속도로 균일한 미생물 층을 담체 표면에 형성할 수 있었다. 또한 기-액 접촉면적을 증대 시켜 95% 이상의 안정적이고 높은 styrene 분해 효율과 $125g/m^3{\cdot}hr$의 높은 제거 용량을 가질 수 있게 해주었다. 하지만 우수한 성능은 미생물의 과다성장에 따른 기공의 폐쇄현상 때문에 오래 지속되지 않았고 반응기의 성능과 안정성은 급속히 저하되었다. 이를 해결하기 위해 진공흡입을 통한 미생물 제거를 시도하였으나 제한적인 효과만을 확인하였다. 향후 RDBF 반응기의 상업화를 위해서는 보다 효율적인 미생물 제어 방법이 개발될 필요가 있다.

Improvement of Degradation Characteristics in a Large, Racetrack-shaped 2G HTS Coil for MW-class Rotating Machines

  • Park, Heui Joo;Kim, Yeong-chun;Moon, Heejong;Park, Minwon;Yu, Inkeun
    • Journal of Electrical Engineering and Technology
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    • 제13권3호
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    • pp.1166-1172
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    • 2018
  • Degradation due to delamination occurs frequently in the high temperature superconductors (HTS) coil of rotating machines made with 2nd generation (2G) HTS wire, and the authors have observed other similar cases. Since an HTS field coil for a rotating machine is required to have stable current control and maintain a steady state, co-winding techniques for insulation material and epoxy resin for shape retention and heat transfer improvement are applied during coil fabrication. However, the most important limiting factor of this technique is delamination, which is known to be caused by the difference in thermal expansion between the epoxy resin and 2G HTS wire. Therefore, in this study, the experimental results of mixing the ratio of epoxy resin and alumina ($Al_2O3$) filler were applied to the fabrication of small and large test coils to solve the problem of degradation. For the verification of this scheme, eight prototypes of single pancake coils with different shapes were fabricated. They showed good results. The energization and operation maintenance tests of the stacked coils were carried out under liquid neon conditions similar to the operation temperature of an MW-class rotating machine. In conclusion, it was confirmed that the alumina powder mixed with epoxy resin in an appropriate ratio is an effective solution of de-lamination problem of 2G HTS coil.

자동차 워셔액 가열시스템의 온도 변화 특성에 관한 연구 (A Study on the Characteristics of Time Dependent Temperature Change in a Automobile Washer Heater)

  • 하지수;이선봉;이동권
    • 한국산학기술학회논문지
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    • 제14권3호
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    • pp.1040-1044
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    • 2013
  • 본 논문은 추운 겨울 자동차 앞면 유리에 생기는 성에를 제거하는 워셔액 가열시스템의 가열과 분사에 따른 온도변화 특성에 관한 연구이다. 지금까지 다른 연구에서는 워셔액 가열시스템에 대한 온도 변화 특성을 간단한 수학적 모델링을 통하여 분석하였으나 본 연구에서는 워셔액 가열시스템의 보다 더 최적화된 제어시스템 설계를 위해 워셔액 가열시스템의 시간에 따른 열유동 특성 변화를 전산유체해석(CFD)을 통해 파악하기로 한다. 이를 위해서 워셔액 가열시스템의 주요 부분인 히터와 워셔액에 대한 비정상상태 해석을 수행하고 워셔액 전체의 온도 변화 특성을 분석하였다. 이를 토대로 워셔액의 가열시간과 분사시 온도 특성을 파악하여 워셔액 가열시스템의 최적설계의 기본자료로 활용하도록 하였다.