• 한국가시화정보학회지
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• 제21권2호
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• pp.45-54
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• 2023

In the present study, we propose new type of a spinning disk reactor(SDR) with high performance and very convenient structure to make a large scale equipment from lab-scale than the conventional one. A split-disk experimental equipment, based on new type of spinning disk reactor, has been developed to generate an energy to break a bulk of injected gas into smaller gas bubble. Several cases of an experimental observation make it to confirm that a bulk of injecting gas could be continuously break into smaller bubbles. It shows the feasibility to make a scale-up of SDR by using the characteristic of Taylor-Proudman column in rotating flow. A theoretical study on single phase liquid flow is given to predict a liquid induced shear stress, which make the present study to be self-containment.

• 대한기계학회논문집A
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• 제21권7호
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• pp.1042-1049
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• 1997

LMFBR(Liquid Metal Fast Breeder Reactor) vessel is operated under the high temperatures of 500-550.deg. C. Thus, transient thermal loads were severe enough to cause inelastic deformation due to creep-fatigue and plasticity. For reduction of such inelastic deformations, Y-piece structure in the form of a thermal sleeve is used in LMFBR vessel under repeated start-up, service and shut-down conditions. Therefore, a systematic method for inelastic analysis is needed for design of the Y-piece structure subjected to such loading conditions. In the present investigation, finite element analysis of heat transfer and inelastic thermal stress were carried out for the Y-piece structure in LMFBR vessel under service conditions. For such analysis, ABAQUS program was employed based on the elasto-plastic and Chaboche viscoplastic constitutive equations. Based on numerical data obtained from the analysis, creep-fatigue damage estimation according to ASME Code Case N-47 was made and compared to each other. Finally, it was found out that the numerical predictio of damage level due to creep based on Chaboche unified viscoplastic constitutive equation was relatively better compared to elasto-plastic constitutive formulation.

• Nuclear Engineering and Technology
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• 제38권3호
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• pp.293-300
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• 2006

A liquid metal reactor (LMR) operated at high temperatures is subjected to both cyclic mechanical loading and thermal loading; thus, creep-fatigue is a major concern to be addressed with regard to maintaining structural integrity. The Korea Advanced Liquid Metal Reactor (KALIMER), which has a normal operating temperature of $545^{\circ}C$ and a total service life time of 60 years, is composed of various cylindrical structures, such as the reactor vessel and the reactor baffle. This study focuses on the creepfatigue crack initiation for a cylindrical Y-junction structure made of 316 stainless steel (SS), which is subjected to cyclic axial tensile loading and thermal loading at a high-temperature hold time of $545^{\circ}C$. The evaluation of the considered creep-fatigue crack initiation was carried out utilizing the ${\sigma}_d$ approach of the RCC-MR A16 guide, which is the high-temperature defect assessment procedure. This procedure is based on the total accumulated strain during the service time. To confirm the evaluated result, a high-temperature creep-fatigue structural test was performed. The test model had a circumferential through wall defect at the center of the model. The defect front of the test model was investigated after the $100^{th}$ cycle of the testing by utilizing a metallurgical inspection technique with an optical microscope, after which the test result was compared with the evaluation result. This study shows how creep-fatigue crack initiation for a high-temperature structure can be predicted with conservatism per the RCC-MR A16 guide.

• Bulletin of the Korean Chemical Society
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• 제28권1호
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• pp.108-114
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• 2007

The lyotropic behaviors to form the structure of distearoylphosphatidylcholine (DSPC)-based liquid crystal (LC) hydrated by only propylene glycol (PG) without water were examined by differential scanning calorimetry (DSC), X-ray diffractions (XRD), polarized microscope (PM) and transmission electron microscope (TEM). By increasing the amount of PG instead of water, it showed the phase transition to be gradually changed from anisotropic structures to other structures more close to isotropic ones and their appearance to be changed from solid-like states to liquid-like ones with more fluidity. Below 50% w/w PG, the mixtures of DSPC and PG resulted in no direct observation of LC structure through PM because they were very close to solid-states. From 55% w/w to 90% w/w of PG, the dense lamella crystalline structures were observed through PM, and their thickness and area decreased as the content of PG increased. Measured by DSC with heating process, the main phase transition from α -lamella phase to isotropic phase appeared from 52.89 °C to 47.41 °C to show linearly decreasing behaviors because PG affects the hydrophobic region of DSPC-based lamella phase. The repeating distance of the lamella phase and the interlayer distance between bilayers were calculated with XRDs and the average number of bilayers related to the thickness in LC structure was approximately estimated by combining with TEM results. The WAXS and DSC measurements showed that all of PG molecules contributed to swelling both the lipid layer in the edge region of lamella phase close to phosphate groups and the interlayer between bilayers below 90% w/w of PG. The phase and thermal behaviors were found to depend on the amount of PG used by means of dissolving DSPC as a phospholipid and rearranging its structure. Instead of water, the inducement of PG as a polar solvent in solid-lamella phase is discussed in terms of the swelling effect of PG for DSPC-based lamella membrane.

• 대한화학회지
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• 제20권2호
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• pp.118-128
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• 1976

액체에 대한 significant structure theory 와 상의 전이에 대한 Bragg-Williams근사를 사용하여 액정 화합물인 p-azoxyanisole의 열역학적 성질을 nematic phase와 isotropic phase의 온도범위에 걸쳐 계산하였다. Isotropic phase는 일반적인 액체로 보았으며 nematic phase는 액체적인 성질외에도 분자쌍극자의 배열에 의한 영향도 고려하였다. p-Azoxyanisole의 액체적인 성질은 significant structure theory로 기술하였으며 분자쌍극과 배열에 의한 영향은 Bragg-Williams 근사로써 고려하였다. 부피, 증기압, 정압비열, 열팽창계수, nematic-isotropic 전이점에서의 엔트로피 엔탈피 변화, 절대엔트로피, Helmholtz free energy등을 계산하여 실험치와 비교하였다.

• 한국인쇄학회지
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• 제18권1호
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• pp.59-69
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• 2000

The characteristics of liquid crystal polymer composite(LCPC) films are possessed of large-area and flexible display, polarizer free, high contrast, wide angle of visual filed and high responsiveness. It is well known that the LCPC films consisting of a continuous LC phase embeded in a three-dimentional network of polymer matrix are formed by photopolymerization-induced phase separation. In this study, we have investigated the point that both liquid crystals and polymer having different properties have to coexiste as composed films. The purpose of this study has been the development of new application with liquid crystals and UV-curable monomers. In the results abtained on the miscibility of nematic liquid crystal and UV-curable resins, difunctional monomer HX-620 turned out to shows the best. From the results abtained on structures, electro-optical properties and dynamic visocoelasticity for LCPC films, the best mixing ratio of monomer to LC mixture were 3/7(photoinitiator; 4wt%) by weight, and this ratio has been provided the most thermal stability for LCPC films. In the results abtained on structure and discoloration properties of LCPC films, it has been demonstrated that consiste of a 8:2 mixture of chiral nematic liquid crystal and HX-620 has the greatest domain and it was the best discoloration.

• 한국응용과학기술학회지
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• 제30권4호
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• pp.770-778
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• 2013

In this study, a liquid carbonation method was applied for producing precipitate calcium carbonate by liquid-liquid reaction. We recycled the recycling water of ready-mixed concrete, one of construction waste for use source of carbonate ion. A supernatant separated from the recycling water of ready-mixed concrete, as a result of ICP analysis of a cation, $Ca^{2+}$ was contained up to 1100 ppm. We used MEA as a $CO_2$ absorbent for the liquid carbonation. A precipitate $CaCO_3$ was produced at more than MEA 20 wt%. The precipitate $CaCO_3$ as a final product was separated and dried. The result of XRD was confirmed the generation of $CaCO_3$ to calcite structure.

• Nuclear Engineering and Technology
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• 제53권9호
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• pp.2866-2877
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• 2021

The complex coupling relationship between liquid sodium and concrete materials affects both the sodium fire characteristics and concrete properties through heat and chemical erosion. In this study, experiments on direct and indirect (separated by a steel plate) contact of the columnar sodium fire with the concrete surface were performed. It was found that the combustion efficiency of liquid sodium in direct contact with concrete was significantly enhanced and accompanied by intermittent explosions and splashing of small concrete fragments. The sodium fire on the surface of the concrete considerably increased the internal temperature, pore size, and distribution density of the concrete. In addition, the depth of influence on the loosening of the concrete structure was also greatly extended. The contact of liquid sodium with the concrete substantially affected its permeability resistance. The water absorption of the concrete surface was increased by more than 70% when liquid sodium directly impacted the bare concrete surface. However, the change in water absorption in the centre of the concrete was primarily affected by the duration of the external heat.

• Structural Engineering and Mechanics
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• 제28권1호
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• pp.89-105
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• 2008

The paper presents a study on the effects of soil-structure-interaction (SSI) on the performance of the compliant liquid column damper (CLCD) for the seismic vibration control of short period structures. The frequency-domain formulation for the input-output relation of a flexible-base structure with CLCD has been derived. The superstructure has been modeled as a linear, single degreeof-freedom (SDOF) system. The foundation has been considered to be attached to the underlying soil medium through linear springs and viscous dashpots, the properties of which have been represented by complex valued impedance functions. By using a standard equivalent linearization technique, the nonlinear orifice damping of the CLCD has been replaced by equivalent linear viscous damping. A numerical stochastic study has been carried out to study the functioning of the CLCD for varying degrees of SSI. Comparison of the damper performance when it is tuned to the fixed-base structural frequency and when tuned to the flexible-base structural frequency has been made. The effects of SSI on the optimal value of the orifice damping coefficient of the damper has also been studied. A more convenient approach for designing the damper while considering SSI, by using an established model of a replacement oscillator for the structure-soil system has also been presented. Finally, a simulation study, using a recorded accelerogram, has been carried out on the CLCD performance for the flexible-base structure.

• 동력기계공학회지
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• 제11권3호
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• pp.22-28
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• 2007

Liquefied gas vaporizer is a machine to vaporize liquefied gas such as liquid nitrogen($LN_{2}$), liquefied natural gas(LNG), liquid oxygen($LO_{2}$) etc. For the air type vaporizer, the frozen dew is created by temperature drop (below 273 K) on vaporizer surface. The layer of ice make a contractions on vaporizer. The structure analysis on the heat transfer was studied to see the effect of geometric parameters of the vaporizer, which are length 1000 mm of various type vaporizer. Structure analysis result such as temperature variation, thermal stress and thermal strain have high efficiency of heat emission as increase of thermal conductivity. As the result, Frist, With-fin model shows high temperature distribution better than without-fin on the temperature analysis. Second, Without-fin model shows double contractions better then with-fin model under the super low temperature load on the thermal strain analysis. Third, Vaporizer fin can be apply not only heat exchange but also a stiffener of structure. Finally, we confirm that All model vaporizer can be stand for sudden load change because of compressive yield stress shows within 280 MPa on thermal stress analysis.