• 분석과학
• /
• 제13권3호
• /
• pp.399-402
• /
• 2000

To determine the concentrations of microcystins present in lake water or in tap water using high performance liquid chromatography, it is necessary to concentrate a large volume of water samples (about 20 L) into very small volume (0.1-0.3 mL). Concentration can be conveniently done when disc type solid phase extraction (SPE) apparatus is used. Using this apparatus we have investigated the recovery rates of three kinds of microcystins, RR, YR, LR. The recovery rates were relatively low and the reproducibilities were not good either. It is expected, however, that the appropriate selection of the disc conditioning and eluting solvents and reproducible reconcentration process after SPE will improve both the recovery rates and the reproducibilities.

• 한국연소학회:학술대회논문집
• /
• 한국연소학회 1999년도 제19회 KOSCO SYMPOSIUM 논문집
• /
• pp.21-26
• /
• 1999

Liquefied petroleum gas(LPG) has been used as motor fuel due to its low emissions and low cost. The fuel feeding system has been improved with stringent requirement for exhaust emissions. LPG carburation system was firstly introduced, then the system changed into a gas injection system controlled precisely, but those gas feeding system has a limitation on improving power output. In order to improve an engine performance, a multi-point port injection system was introduced recently, and a liquid direct injection system into a cylinder was suggested as a next generation system to maximize a fuel economy as well as a power. This study addresses the analysis of the LPG spray from diesel injectors. The spray images are visualized and compared with diesel sprays in a wide injection pressure range. The photographs show much wider dispersion of LPG sprays.

• Journal of Advanced Marine Engineering and Technology
• /
• 제28권3호
• /
• pp.538-550
• /
• 2004

The convection heat transfer coefficients on the top surface of a large liquid petroleum liquid injection(LPLi) engine piston with the oil gallery are analyzed by solving an inverse thermal conduction problem. The heat transfer coefficients are numerically found so that the difference between analyzed temperatures from the finite element method and measured temperatures is minimized. Using the resulting heat transfer coefficients as the boundary condition, temperature of a large LPLi engine piston is analyzed. With varying cooling water temperature, temperature, stress, and thermal expansion of the piston are analyzed and evaluated.

• Journal of Advanced Marine Engineering and Technology
• /
• 제28권5호
• /
• pp.762-772
• /
• 2004

Fatigue life of a Piston for large liquid Petroleum liquid injection(LPLi) bus engines is analyzed considering effects of cooling condition parameters : temperature of cooling water, and heat transfer coefficients at oil gallery and bottom surface of piston head. Temperature of the piston is analyzed with varying cooling conditions Stresses of the piston from two load cases of pressure loading. and pressure and thermal loading are analyzed Fatigue life under repeated peak pressure and thermal cycle is analyzed by the strain-life theory. For the two load cases, required loading cycles for engine life are defined, and loading cycles to failure and partial damages are calculated. Based on the resulting accumulated fatigue usage factors, endurance of the piston is evaluated and effects of varying cooling condition Parameters are discussed.

• Bulletin of the Korean Chemical Society
• /
• 제22권1호
• /
• pp.59-62
• /
• 2001

The dried fruit-body of Daedaleopsis tricolor was extracted by the petroleum ether. The extracts were purified by liquid-liquid extraction, column chromatography, and recrystallization. The purified compound was a colorless orthorhombic crystal form. Its melting point, molecular weight and molar extinction coefficient $(\varepsilon)$ were estimated $168-170^{\circ}C$, 424 and 3,935 at 208 nm, respectively. Its structure was elucidated to be 20(29)-lupen-3-one by UV-Vis, FT-IR, NMR and X-ray crystallographic analysis. It showed antifungal activities against Saccharomyces cerevisiae and Microsporum gypseum, and antibacterial activities against Escherichia coli, Proteus vulgaris, Pseudomonas pyocyanea, Bacillus subtilis, and Staphylococcus aureus. In addition, this compound showed an antioxidative activity on lipid-peroxidation by 6.4%.

• Korean Chemical Engineering Research
• /
• 제59권2호
• /
• pp.247-253
• /
• 2021

Electrocoalescence is an active technique in petroleum industry, formation of raindrop in cloud, and digital microfluidics. In the present work, electrocoalescence of two droplets under the constant electric potential in air was studied. Through this experiment, we found that the electrocoalescence process could be divided three phases; deformation, formation of liquid bridge, and merging. And the condition for formation of liquid bridge between two droplets was obtained. For the connection of experimental result in constant potential condition with general case in constant charge condition, relationship of charge and potential difference was deduced by numerical computation. In high electric potential case, flat interfaces after recoiling were observed. It was interpreted through a numerical simulation of electric field.

• 유체기계공업학회:학술대회논문집
• /
• 유체기계공업학회 2003년도 유체기계 연구개발 발표회 논문집
• /
• pp.149-153
• /
• 2003

As the fastest growing flowmeter technology, multi-path ultrasonic flow-meters are gaining wider range in petroleum industry for liquid hydrocarbon custody transfer measurement. This paper describes the mult-path ultrasonic flowmeter, URO-Ex1000 the requirements necessary to prove and test in Korea & China. URO-Ex1000 haver a good results with accuracy range, but a little exceed with repeatability.

• Journal of Microbiology and Biotechnology
• /
• 제15권5호
• /
• pp.952-964
• /
• 2005

The diesel-degrading activities of biofilms sampled from petroleum-contaminated groundwaters in urban subway drainage systems were examined in liquid cultures, and the microbial populations of the biofilms were characterized by denaturing gel gradient electrophoresis (DGGE) and 16S rDNA sequence analysis. Biofilm samples derived from two sites (19 K and 20 K) at subway Station N and Station I could degrade around $80\%$ of applied diesel within 20 and 40 days, respectively, at $15^{\circ}C$, and these results were strongly correlated with the growth patterns of the biofilms. The closest phylogenetic neighbor of a dominant component in the 19 K biofilm was Thiothrix fructosivorans strain Q ($100\%$ similarity). Four dominant strains in the 20 K biofilm were closely related to Thiothrix fructosivorans strain Q ($100\%$ similarity), Thiothrix sp. CC-5 ($100\%$ similarity), Sphaerotilus sp. IF14 ($99\%$ similarity), and Cytophaga-Flexibacter-Bacterioides (CFB) group bacterium RW262 ($98\%$ similarity). Three dominant members in the Station I biofilms were very similar to uncultured Cytophagales clone CRE-PA82 ($91\%$ similarity), Pseudomonas sp. WDL5 ($97\%$ similarity), and uncultured CFB group bacterium LCK-64 ($94\%$ similarity). The microbial components of the biofilms differed depending on the sampling site. This is the first report on the isolation of clones highly similar to Thiothrix fructosivorans and Thiothrix sp. from biofilms in petroleum-polluted groundwaters, and the first evidence that these organisms may play major roles in petroleum degradation and/or biofilm-development.

• 공업화학
• /
• 제27권6호
• /
• pp.664-668
• /
• 2016

무단 폐기물 투기로 인해 토양, 지하수, 하천 등 환경오염이 심각해지고 있다. 본 연구에서는 J시에서 발생된 무단 투기 유류를 분석함으로써 어떤 유종인지를 분석하였다. 물, 고형불순물, 유류 혼합물 형태를 전처리하여 균질한 유류성분을 얻은 뒤, 물성분석, 원소분석, 및 가스크로마토그래피를 이용해 분석한 결과, 11.8%의 산소함량, $-6^{\circ}C$의 유동점, 크로마토그램의 패턴 결과 식물성기름으로 판단하였다. 또한 어떤 식물성 기름인지 알기 위해 HPLC를 이용해 구성성분을 분석한 결과, LLO, OOL, POL이 높은 비율로 분석되어졌으며, 이는 대두유가 주성분이면서 다른 식물성기름의 혼합형태인 폐유로 최종 판단하였다. 본 연구를 통해 향후, 불법 투기되는 유류에 대한 유종 구분 및 오염원인자 판단을 위해 활용 가능할 것으로 판단된다.

• Membrane and Water Treatment
• /
• 제8권1호
• /
• pp.19-34
• /
• 2017

Boron exists in dilute concentrations in sea water, ground water and waste waters. Reactive liquid extraction can be used for removing boron to make the treated water suitable for drinking and irrigation, with its final concentration less than 0.5 ppm. The results of equilibrium experiments are reported on the removal of boron using 2-butyl-2-ethyl-1, 3-propanediol (BEPD as a nonionic carrier) in sunflower oil, a non-traditional solvent. The results of removal of boron from aqueous solutions in the concentration range 0.5-20 ppm are presented. It is shown that this new liquid membrane system, is able to remove boron from ground waters at their natural pH of 6-8 (without any chemical addition for pH adjustments). The removal efficiency is good when the process is upgraded to a hollow-fibre membrane contactor and approximately 45% boron can be removed in a single-stage contact. There are additional advantages of this new approach that includes reduced operational health and safety and environmental issues. The results reported here provide guidelines to the development of boron removal process using renewable, biodegradable, safe and cheap solvent system such as sunflower oil.