• 방사성폐기물학회지
• /
• 제20권1호
• /
• pp.33-41
• /
• 2022

Liquid Bi pool is a candidate electrode for an electrometallurgical process in the molten LiCl-KCl eutectic to treat the spent nuclear fuels from nuclear power plants. The electrochemical behavior of Bi³⁺ ions and the electrode reaction on liquid Bi pool were investigated with the cyclic voltammetry in an environment with or without BiCl₃ in the molten LiCl-KCl eutectic. Experimental results showed that two redox reactions of Bi³⁺ on inert W electrode and the shift of cathodic peak potentials of Li⁺ and Bi³⁺ on liquid Bi pool electrode in molten LiCl-KCl eutectic. It is confirmed that the redox reaction of lithium with respect to the liquid Bi pool electrode would occur in a wide range of potentials in molten LiCl-KCl eutectic. The obtained data will be used to design the electrometallurgical process for treating actinide and lanthanide from the spent nuclear fuels and to understand the electrochemical reactions of actinide and lanthanide at liquid Bi pool electrode in the molten LiCl-KCl eutectic.

• 대한기계학회논문집B
• /
• 제28권12호
• /
• pp.1591-1599
• /
• 2004

A series of experiments were conducted to study the effectiveness of the extinction of a liquid pool fire with two different water atomizing nozzles. Fire source is a small-scale circular stainless steel pan of 120mm in diameter with the fuels of hexane and ethanol. K-type thermocouples were used to measure the flame and fuel temperature along the pool centerline and under fuel surface. A digital camera was used to visualize the process of the fire suppression. The experimental results show that water mist droplet size is l15∼180${\mu}{\textrm}{m}$ with nozzle A and 130∼190${\mu}{\textrm}{m}$ with nozzle B. The extinguishing time of pool fire was reduced with the increase of pressure. When water droplets are small, they do not reach the flame base since they may be deflected or evaporated by the fire plume. However, influence of flow rate is more important than droplet size on fire extinction. Among the fire extinction mechanisms, drop of flame temperature is superior to suffocation of $O_2$ concentration.

• 한국연소학회:학술대회논문집
• /
• 대한연소학회 2003년도 제27회 KOSCO SYMPOSIUM 논문집
• /
• pp.215-221
• /
• 2003

A series of experiments were conducted to study the effectiveness of the extinction of a liquid pool fire with two different water atomizing nozzles. Fire source is small-scale circular stainless steel pan of 120mm in diameter with the fuels of hexane and ethanol. K-type thermocouples were used to measure the flame and fuel temperature along the pool centerline and under fuel surface. A digital camera was used to visualize the process of the fire suppression. The experimental results show that water mist droplet size is $115{\sim}180{\mu}m$ with nozzle A and $130{\sim}190{\mu}m$ with nozzle B. The extinguishing time of pool fire was reduced with the increase of pressure. When water droplets are small, they do not reach the flame base since they may be deflected or evaporated by the fire plume. However, influence of flow rate is more important than droplet size on fire extinction. Among the fire extinction mechanisms, drop of flame temperature is superior to suffocation of O2 concentration.

• 한국화재소방학회논문지
• /
• 제18권3호
• /
• pp.39-44
• /
• 2004

Pool화재의 화염 거동을 알아보기 위하여 산업에서 많이 사용되는 가연성 액체인 아세톤 메탄을 헥산 그리고 헵탄을 직경 50mrn에서 400nun까지의 용기 내에 넣고 연소실험을 하였다. 용기의 재질은 스테인리스와 구리를 사용하였다. 연소시간과 용기 벽면의 온도 및 열유속 등을 측정하였으며 연소 시 화염의 거동은 비디오카메라를 이용하여 촬영하였다. 실험을 통해서 연소속도와 화염의 높이는 용기 직경의 증가와 함께 증가하였으며 화염의 와류 생성 주기는 용기 직경에 반비례하였다. 또한 pool화재의 특성은 액체연료의 물리 화학적 성질과 용기의 재질에 의해서도 영향을 받는 것을 알 수 있었다.

• Nuclear Engineering and Technology
• /
• 제52권5호
• /
• pp.947-955
• /
• 2020

Predicting the sloshing motion of a coolant during a seismic assessment of a rectangular spent fuel pool is of critical concern. Linear theory, which provides a simple analytical method, has been used to predict the sloshing motion in rectangular pools and tanks. However, this theory is not suitable for the high-frequency excitation problem. In this study, the authors developed a simple analytical method for predicting the sloshing motion in a rectangular pool for a wide range of excitation frequencies. The correlation among the linear theory parameters, influencing on excitation and convective waves, and the excitation frequency is investigated. Sloshing waves in a rectangular pool with several liquid heights are predicted using the original linear theory, a modified linear theory and computational fluid dynamics analysis. The results demonstrate that the developed method can predict sloshing motion over a wide range of excitation frequencies. However, the developed method has the limitations of linear solutions since it neglects the nonlinear features of sloshing motion. Despite these limitations, the authors believe that the developed method can be useful as a simple analytical method for predicting the sloshing motion in a rectangular pool under various external excitations.

• Nuclear Engineering and Technology
• /
• 제51권2호
• /
• pp.410-423
• /
• 2019

Fire suppression using a water mist nozzle directly above an n-Heptane pool in a fire compartment with a door opening was numerically investigated using the Fire Dynamics Simulator (FDS) for the purpose of application in nuclear power plants. Input parameters for the numerical simulation were determined by experimental measurements. Water mist was activated 10 s after the fire began. The sensitivity analysis was conducted for three input parameters: total number of cubic cells of 6032-2,926,400, droplets per second of 1000-500,000, and extinguishing coefficient of 0-100. In a new simple calibration method of this study, the extinguishing coefficient yielding the fire suppression time closest to that measured by experiments was found for use as the FDS simulation input value. When the water mist jet flow made contact with the developed fire, the heat release rate instantaneously increased, and then rapidly decreased. This phenomenon occurred with a displacement of the flame near the liquid fuel pool. Changing the configuration of the door opening with different aspect ratios and opening ratios had impact on the maximum value of the heat release rate due to the flame displacement.

• 한국화재소방학회논문지
• /
• 제31권5호
• /
• pp.12-18
• /
• 2017

본 연구는 FDS의 액체증발모델을 이용하여 메탄올 풀 화재의 질량연소플럭스를 예측하고 복사분율, 평균흡수계수와 같은 연료의 열적 물성값에 따른 영향을 평가하였다. 해석대상 풀의 직경은 5 cm에서 200 cm 사이이며 해석영역의 크기는 풀의 크기에 비례하여 구성하였다. 해석에 적용된 기준격자는 격자민감도 평가를 통해 결정되었으며 약 750,000개의 격자를 적용하였다. 메탄올 풀 화재에 대해 FDS 액체증발모델을 적용하여 계산된 질량연소플럭스는 해석대상 풀 직경에 따른 천이특성을 잘 나타냈으며 전체적으로 실험편차 내에서 기존 실험과 일치된 결과를 예측하였다. 질량연소플럭스는 복사분율 증가에 따라 증가하는 경향을 보였으며 풀의 직경이 작은 경우 평균흡수계수의 영향이 상대적으로 크게 나타났다.

• 한국안전학회지
• /
• 제19권3호
• /
• pp.45-50
• /
• 2004

4-panel of 1m height and 45cm width were fixed on the $40cm{\times}40cm$ bottom plate and the opening of the panel comer was 5cm. Diameter of stainless vessel is loom and its height is 2cm and it located at the center of the bottom plate. 78mL liquid fuel was filled in the vessel and its depth was 1cm. Flame temperature was measured with K type thermocouple, and radiation heat of flame was measured with heat flux meter. Flame height and its behavior was visualized with video camera. and mass burning rate was measured by fuel combustion time. According to the development of fire, flame swirling was begin. From the experiment the mass burning rate was larger and the height of flame was higher than the usual pool fire flame. Flame temperature and heat flux also increased far more than the pool fire. Consequently the swirling air flow through the openings between the panel and thermal buoyance contribute to increase of heat release rate, flame length and mass burning rate.

• Nuclear Engineering and Technology
• /
• 제43권3호
• /
• pp.205-216
• /
• 2011

Recently, many research studies have investigated the enormous critical heat flux (CHF) enhancement caused by nanofluids during pool boiling and flow boiling. One of the main reasons for this enhancement is nanoparticle deposition on the heated surface. However, in real applications, nanofluids create many problems when used as working fluids because of sedimentation and aggregation. Therefore, artificial surfaces on silicon and metal have been developed to create an effect similar to that of nanoparticle deposition. These modified surfaces have proved capable of greatly increasing the CHF during pool boiling, and good results have also been observed during flow boiling. In this study, we demonstrate that the wetting ability of a surface, i.e., wettability, and the liquid spreading ability (hydrophilic surface property), are key parameters for increasing the CHF during both pool and flow boiling. We also demonstrate that when the fuel surface in nuclear power plants is modified in a similar manner, it has the same effect, producing a large CHF enhancement.

• Nuclear Engineering and Technology
• /
• 제34권2호
• /
• pp.117-131
• /
• 2002

Core disruptive accidents have been investigated at Korea Atomic Energy Research Institute(KAERI) as part of the work to demonstrate the inherent and ultimate safety of conceptual design of the Korea Advanced Liquid Metal Reactor(KALIMER), a 150 MWe pool- type sodium cooled prototype fast reactor that uses U-Pu-Zr metallic fuel. In this study, a simple method and associated computer program, SCHAMBETA, was developed using a modified Bethe-Tait method to simulate the kinetics and thermodynamic behavior of a homogeneous spherical core over the period of the super-prompt critical power excursion induced by the ramp reactivity insertion. Calculations of the energy release during excursions in the sodium-voided core of the KALIMER were subsequently performed using the SCHAMBETA code for various reactivity insertion rates up to 100 S/s, which has been widely considered to be the upper limit of ramp rates due to fuel compaction. Benchmark calculations were made to compare with the results of more detailed analysis for core meltdown energetics of the oxide fuelled fast reactor. A set of parametric studies were also performed to investigate the sensitivity of the results on the various thermodynamics and reactor parameters.