• Title/Summary/Keyword: Liquid forming

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Effects of Boride on Properties of SiC Composites (SiC계 복합체의 특성에 미치는 Boride의 영향)

  • Shin, Yong-Deok;Ju, Jing-Young;Jeon, Jae-Duck;So, Byung-Moon;Lee, Dong-Yoon
    • Proceedings of the KIEE Conference
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    • 2004.11a
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    • pp.191-193
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    • 2004
  • The composites were fabricated, respectively, using 61vol.% SiC-39vol.% $TiB_2$ and using 61vol.% SiC-39vol.% $ZrB_2$ powders with the liquid forming additives of 12wt% $Al_2O_3+Y_2O_3$ by hot pressing annealing at $1650^{\circ}C$ for 4 hours. Reactions between SiC and transition metal $TiB_2$, $ZrB_2$ were not observed in this microstructure. The result of phase analysis of composites by XRD revealed SiC(6H, 3C), $TiB_2$, $ZrB_2$ and $YAG(Al_5Y_3O_{12})$ crystal phase on the SiC-$TiB_2$, and SiC-$ZrB_2$ composites. The ${\beta}\;{\alpha}$-SiC phase transformation was occurred on the $SiC-TiB_2$, $SiC-ZrB_2$ composites. The relative density, the flexural strength and Young's modulus showed respectively value of 98.57%, 226.06Mpa and $86.37{\times}10^3Mpa$ in SiC-$ZrB_2$ composites.

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Effect of Annealing on Properties of SiC-$TiB_2$ Composites (SiC-$TB_2$ 복합체의 특성에 미치는 annealing의 영향)

  • Shin, Yong-Deok;Ju, Jin-Young;Ko, Tae-Hun;Kim, Young-Bek
    • Proceedings of the KIEE Conference
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    • 2007.07a
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    • pp.1289-1290
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    • 2007
  • The composites were fabricated 61Vo.% ${\beta}$-SiC and 39Vol.% $TiB_2$ powders with the liquid forming additives of 12wt% $Al_{2}O_{3}+Y_{2}O_{3}$ as a sintering aid by pressure or pressureless annealing at $1650^{\circ}C$ for 4 hours. The present study investigated the influence of annealed sintering on the microstructure and mechanical of SiC-$TiB_2$ electroconductmive ceramic composites. Reactions between SiC and transition metal $TiB_2$ were not observed in the microstructure and the phase analysis of the SiC-$TiB_2$ electroconductive ceramic composites. Phase analysis of SiC-$TiB_2$ composites by XRD revealed mostly of ${\alpha}$-SiC(6H), $TiB_2$, and In Situ YAG($Al_{5}Y_{3}O_{12}$). The relative density, the flexural strength, the Young's modulus showed the highest value of 86.69[%], 136.43[MPa], 52.82[GPa] for pressure annealed SiC-$TiB_2$ ceramic composites.

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A study on the properties of the Electrocondutive Ceramic $SiC-TiB_2$ Composites according to Annealing Temperature. (Annealing 온도 변화에 따른 $\beta-SiC-TiB_2$ 도전성 세라믹 복합체의 특성 연구)

  • Shin, Yong-Deok;Ju, Jing-Young;Choi, Kwang-Soo;Oh, Sang-Soo;Lee, Dong-Yoon
    • Proceedings of the KIEE Conference
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    • 2002.11a
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    • pp.106-108
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    • 2002
  • The composites were fabricated 61vol.% $\beta-SiC$ and 39vol.% $TiB_2$ powders with the liquid forming additives of l2wt% $Al_2O_3+Y_2O_3$ by pressureless annealing at $1700^{\circ}C,\;1750^{\circ}C,\;1800^{\circ}C$ for 4 hours respectively. The result of Phase analysis of composites by XRD revealed $\alpha-SiC$(6H), $TiB_2$, and YAG($Al_5Y_3O_{12}$) crystal phase. The relative density and the Young's modulus showed the highest value of 92.9701% and 92.884Gpa for composites by pressureless annealing temperature $1700^{\circ}C$ at room temperature.

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The Effects of Rotating Magnetic Field on Growth Rate, Cell Metabolic Activity and Biofilm Formation by Staphylococcus Aureus and Escherichia Coli

  • Fijalkowski, Karol;Nawrotek, Pawel;Struk, Magdalena;Kordas, Marian;Rakoczy, Rafal
    • Journal of Magnetics
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    • v.18 no.3
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    • pp.289-296
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    • 2013
  • This work presents results of the study which concerns the influence of the rotating magnetic field (RMF) on the growth rate, cell metabolic activity and ability to form biofilms by E. coli and S. aureus. Liquid cultures of the bacteria were exposed to the RMF (RMF frequency f = 1-50 Hz, RMF magnetic induction B = 22-34 mT, time of exposure t = 60 min, temperature of incubation $37^{\circ}C$). The present study indicate the exposition to the RMF, as compared to the unexposed controls causing an increase in the growth dynamics, cell metabolic activities and percentage of biofilm-forming bacteria, in both S. aureus and E. coli cultures. It was also found that the stimulating effects of the RMF exposition enhanced with its increasing frequencies and magnetic inductions.

Simulation of oxygen mass transfer in fuel assemblies under flowing lead-bismuth eutectic

  • Feng, Wenpei;Zhang, Xue;Chen, Hongli
    • Nuclear Engineering and Technology
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    • v.52 no.5
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    • pp.908-917
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    • 2020
  • Corrosion of structural materials presents a critical challenge in the use of lead-bismuth eutectic (LBE) as a nuclear coolant in an accelerator-driven system. By forming a protective layer on the steel surfaces, corrosion of steels in LBE cooled reactors can be mitigated. The amount of oxygen concentration required to create a continuous and stable oxide layer on steel surfaces is related to the oxidation process. So far, there is no oxidation experiment in fuel assemblies (FA), let alone specific oxidation detail information. This information can be, however, obtained by numerical simulation. In the present study, a new coupling method is developed to implement a coupling between the oxygen mass transfer model and the commercial computational fluid dynamics (CFD) software ANSYS-CFX. The coupling approach is verified. Using the coupling tool, we study the oxidation process of the FA and investigate the effects of different inlet parameters, such as temperature, flow rate on the mass transfer process.

Miscibility Gap in Cu-Zr-Ag Alloy System and its Effect on the Structure and Plasticity of Metallic Glass (Cu-Zr-Ag계 비정질 합금의 불혼화 영역이 구조 및 소성에 미치는 영향)

  • Lee, Jin-ju;Park, Kyoung-Won;Kim, Do-Hyang;Fleury, Eric
    • Korean Journal of Metals and Materials
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    • v.49 no.12
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    • pp.930-936
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    • 2011
  • In the present study, we show that the addition of Ag, an element having a positive enthalpy of mixing with Cu in the liquid state, enables the simultaneous enhancement of the glass forming ability and the plasticity in Cu-Zr-Ag bulk metallic glasses (BMGs). Rods of 4 mm diameter could be prepared with a fully amorphous structure and values of plastic strain up to 18% were measured under a compression mode for compositions around $Cu_{42.5}Zr_{47.5}Ag_{10}$. The possible role of Ag in the change of the atomic structure and the enhancement of the plastic strain in the ternary Cu-Zr-Ag BMGs is discussed based on analyses from transmission electron microscopy and EXAFS (extended X-ray absorption fine structure).

Research on the inlet preswirl effect of clearance flow in canned motor reactor coolant pump

  • Xu, Rui;Song, Yuchen;Gu, Xiyao;Lin, Bin;Wang, Dezhong
    • Nuclear Engineering and Technology
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    • v.54 no.7
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    • pp.2540-2549
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    • 2022
  • For a pressurized water reactor power plant, the reactor coolant pump (RCP) is a kernel component. And for a canned motor RCP, the rotor system's properties determines its safety. The liquid coolant inside the canned motor RCP fills clearance between the metal shields of rotor and stator, forming a lengthy clearance flow. The influence of inlet preswirl on rotordynamic coefficients of clearance flow in canned motor RCP and their effects on the rotordynamic characteristics of the pump are numerically and experimentally investigated in this work. A quasi-steady state computational fluid dynamics (CFD) method has been used to investigate the influence of inlet preswirl. A vertical experiment rig has also been established for this purpose. Rotordynamic coefficients on different inlet preswirl ratios (IR) are obtained through CFD and experiment. Results show that the cross-coupled stiffness of the clearance flow would change significantly with inlet preswirl, but other rotordynamic coefficients would not change significantly with inlet preswirl. For the case of clearance flow between the stator and rotor cans, influence of inlet preswirl is not so significant as the IR is not large enough.

Improving the CO2 Sequestration Capability and Mechanical Properties of CO2 Reactive Cement Paste Using pH Swing Method (pH Swing법을 활용한 이산화탄소 반응경화형 시멘트 경화체의 CO2 고정화 성능 및 기계적 물성 개선)

  • Cho, Seong-Min;Kim, Gyeong-Ryul;Bae, Sung-Chul
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2023.05a
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    • pp.115-116
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    • 2023
  • This study aims to investigate and improve the carbon dioxide sequestration capability and the mechanical properties of non-hydraulic low calcium silicate cement especially designed for CO2 reaction and ordinary Portland cement subjected to the carbonation curing facilitating pH swing method. Nitric acid (HNO3) was utilized as an liquid for the mixing of cement paste to enhance the initial dissolution of Ca ions from the cements by promoting low pH environment and prevent the direct precipitation of Ca with the anion, owing to the high solubility of Ca(NO3)2 in water. The results presented that the higher the concentration of HNO3, the higher the compressive strength and CO2 sequestration (until 0.1 M). Ca dissolution caused by the harsh acid attack onto the anhydrous cement particle lead to the higher carbonation reaction degree, forming abundant CaCO3 crystals after the reaction. However, cement paste mixed with excessively high concentration of HNO3 presented deterioration due to the too harsh pH environment and abundant NO3- ions which are known to retard the reaction of cement.

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Liquid Extraction of Succinic Acid by Aqueous Two-Phase Systems Composed of Piperidinium Ionic Liquids and Phosphate Salt (피페리딘계 이온성 액체와 포스페이트 염으로 구성된 수상이성분계를 이용한 숙신산의 추출)

  • Lee, Woo Yun;Hong, Yeon Ki
    • Korean Chemical Engineering Research
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    • v.54 no.1
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    • pp.52-56
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    • 2016
  • As an effective method for extraction of succinic acid, aqueous two-phase systems based on piperidinium ionic liquids were used in this study. Effects of the alkyl chain length of cation in piperinidium ionic liquids on phase diagram and extraction efficiencies were investigated. Experimental results show that aqueous two phase systems can be formed by adding appropriate amount of piperidinium ionic liquids to aqueous $K_2HPO_4$ solutions. It can be found that the ability of piperidinium ionic liquids for phase separation followed the order [OMPip][Br]>[HMPip][Br]>[BMPip][Br]>[EMPip][Br]. The biphase-forming ability of piperidinium ionic liquids was higher than that of imidazolium and pyrrolidinium ionic liquids in the presence of $K_2HPO_4$. 75~95% of the succinic acid could be extracted into the ionic liquid-rich phase in a single-step extraction. There was little difference in the extraction efficiency of succinic acid by piperidinium ionic liquids comparing to other ionic liquids such as imidazolium and pyrrolonidium ionic liquids. This aqueous two phase system by piperidinium ionic liquid is suggested to have effective application for the separation of succinic acid.

The Preparation of Multi-Lamellar Emulsion Which Containing Pseudoceramide(PC-9) (유사 세라마이드(PC-9)를 함유한 다중 층상 유화물의 제조)

  • Park, Byeong-Deog;Yeom, Jong-Kyung;Lee, Myung-jin;Kim, Yoon
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.25 no.1
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    • pp.55-68
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    • 1999
  • A muti-lamellar emulsion containing a pseudoceramide, N-Ethanol-2-myristyl/ palmityl-3-oxostearmide/arachidamide(PC-9) has been prepared and its efficacy evaluation has been investigated. In order to prepare a muti-lamellar emulsion, first, the gram ratios of PC-9, fatty acid and cholesterol on the phase diagram to be capable of forming their lamellar liquid crystal structures were determined and secondly, the multi-lamellar emulsion was preprared using glyceryl monostearate and polyoxyethylene glyceryl monosteartate as emulsifers together with above mentioned pseudo-stratum corneum lipid components. Besides natural oils such as olive oil had a tendency to build up the multi-lamellar emulsion. And according as the amount of oil increased in the emulsion, it was observed that the optical anisotropy of “Maltese Cross” which was a typical configuration of multi-lamella mesophase texture diminished. In the dried state of the multi-lamella emulsion, it was examined to transform its emulsion phase into a lamella liquid crystal one. And finally, when the emulsion was applied into a human skin, it was investigated that it had effectiveness in reducing transepidermal water loss (TEWL) of the skin.

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