• Title/Summary/Keyword: Liquid forming

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A Study for Development and Application of a Low NOx 2-staged Swirl Atomizer (저 NOx2단 선회 분무식 노즐 개발 및 실기적용 연구)

  • Song, Si-Hong;Kim, Hyeok-Pil;An, Sang-Taek;Lee, Ik-Hyeong
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.25 no.12
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    • pp.1793-1801
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    • 2001
  • A study of low NOx atomizer was carried out to reduce nitrogen oxides(NOx) in a liquid fuel burner flame. The basic concept of NOx reduction in this atomizer is the fuel 2-staging combustion which is generated by a single atomizer forming two different stoichiometric flames. Two orifices swirl atomizer was selected and modified to realize this concept, and it was tested to obtain the design process of low NOx atomizer. These experiments were achieved to find out the relationship between the injection pressures and the flow rate, spray angle and drop size of swirl atomizer as well as to confirm the NOx reduction concept in real plant(power boiler). In comparison between experimental and theoretical results, the correct discharge coefficient and spray angle were obtained. In real burning test, NOx reduction rate was reached to above 27% of the case using conventional swirl atomizer.

Influence of pH, Temperature, Ionic Strength and Metal Ions on the Degradation of an Iridoid Glucoside, Aucubin, in Buffered Aqueous Solutions (완충 수용액중 pH, 온도, 이온강도 및 금속이온이 Aucubin의 분해에 미치는 영향)

  • Chun, In-Koo;Cho, Young-Mee
    • Journal of Pharmaceutical Investigation
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    • v.25 no.3
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    • pp.239-247
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    • 1995
  • The physico-chemical stability of aucubin, a hepatoprotective iridoid glucoside, in buffered aqueous solutions was studied using a stability-indicating reversed-phase high performance liquid chromatography. The degradation of aucubin followed the pseudo-first-order kinetics. In strong acidic regions, aucubin was rapidly degraded by the specific acid catalysis, forming dark brown precipitates. From the rate-pH profiles, it was found that aucubin was most stable at the pH of about 10. From the temperature dependence of degradation, activation energies for aucubin at pH 2.1 and 4.9 were calculated to be 22.0 and 24.3 kcal/mole, respectively. The shelf-life $(t_{90%})$ for aucubin at pH 9.07 and $20^{\circ}C$ was predicted to be about 603 days. A higher ionic strength accelerated the degradation of aucubin at pH 4.01. The effect of metal ions on the degradation rate of aucubin at pH 7.16 was in the rank order of $Cu^{2+}\;>\;Fe^{3+}\;>\;Co^{2+}\;>\;Fe^{2+}\;>\;Mg^{2+}$. On the other hand, $Mn^{2+}\;and\;Ba^{2+}$ slowed the degradation rate.

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Study on an Intermediate Compound Preparation for a HTGR Nuclear Fuel (고온가스로용 핵연료 중간화합물 제조에 대한 연구)

  • Kim, Yeon-Ku;Suhr, Dong-Soo;Jeong, Kyung-Chai;Oh, Seung-Chul;Cho, Moon-Sung
    • Journal of the Korean Ceramic Society
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    • v.45 no.11
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    • pp.725-733
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    • 2008
  • In this study the preparation method of the spherical ADU droplets, intermediate compound of a HTGR nuclear fuel, was detailed-reviewed and then, the characteristics on an ageing and a washing steps among the wet process and the thermal treatment process on the died-ADU${\rightarrow}UO_3$ conversion with the high temperature furnaces were studied. The key parameters for spherical droplets forming are a precise control of feed rate and a suitable viscosity value selection of a broth solution. Also, a harmony of vibrating frequency and amplitude of a vibration dropping system are important factor. In our case, an uranium concentration is $0.5{\sim}0.7mol/l$, viscosity is $50{\sim}80$ centi-Poise, vibration frequency is about 100Hz. In thermal treatment for no crack spherical $UO_3$ particle, the heating rate in the calcination must be operated below $2^{\circ}C$/min, in air atmosphere.

Effect of Shell Structure of Artificial Lightweight Aggregates on the Emission Rate of Absorbed Water (인공경량골재의 표피층 구조가 흡수된 물의 방출속도에 미치는 영향)

  • Kang, Seung-Gu
    • Journal of the Korean Ceramic Society
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    • v.45 no.11
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    • pp.750-754
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    • 2008
  • The artificial aggregates with dense surface layer (shell) was fabricated and the dependence of water emission rate upon the shell structures was studied. The EAF dust containing many flux components and waste white clay with ignition loss of above 48% were used as for liquid phase and gas forming agents during a sintering process respectively. In addition, the shell structure was modified with various processes and the modification effect on water emission rate was analyzed. The pores under $10{\mu}m$ were found in the sintered artificial light aggregates and disappeared by incorporating to a bigger pore during re-sintering. The water emission rate in an initial step depended on a void content of aggregates filled in a bottle rather than a shell structure. But, after 7 days where the water emission of the aggregate with a shell is above 40%, the shell of aggregates suppressed the water emission. The core of aggregates was exposed and most shell was lost when crushed to smaller size so, the ability for suppressing water emission of the crushed aggregates decreased. The activation energy for the water emission was $3.46{\pm}0.25{\times}10^{-1}$J/mol for the most specimens showing that the activation energy is irrelevant to the pore size distribution and shell structure.

Reversed-Phase Ion-Interaction Chromatography of Aromatic Sulfonic and Carboxylic Acids (방향족 슬폰산 및 카르복시산의 역상 이온-상호작용 크로마토그래피)

  • Kang Sam-Woo;Oh Hae-Beom;Lee Seung-Seok
    • Journal of the Korean Chemical Society
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    • v.32 no.2
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    • pp.113-121
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    • 1988
  • The retention mechanism and separation of various aromatic sulfonic and carboxylic acids on reversed-phase liquid chromatographic column were studied in the mobile phase containing dodecyltrimethylammonium bromide (DTAB). The retention mechanism was found to be followed the ion-interaction model where the DTAB occupies a primary layer at the stationary phase while the sample anions and other co-anions in the system compete for forming the secondary layer. The capacity factors of samples were influenced by the several factors such as pH, concentration of various organic solvents, co-anions in the mobile phase and functional groups in sample molecules. Some mixtures of organic samples were attempted to separate under optimum condition.

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A Study on the concept of 'Trans Architecture' in Marcos Novak (마르코스 노박(Marcos Novak)의 트렌스 건축(Trans Architecture) 개념에 관한 연구)

  • Lee Kyu-Hong;Kim Kai-Chun
    • Korean Institute of Interior Design Journal
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    • v.15 no.4 s.57
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    • pp.46-54
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    • 2006
  • The present study examined Marcos Novak, a digital architect who has researched digital architecture and produced related works since the early 1990s. Starting from digital ideas originating from science and mathematics, he pursued 'trans architecture' based on the concept of 'architecture beyond the boundary of architecture' and 'architecture as invisible foundation.' His concept of 'trans architecture' is considered an important viewpoint in expressing the architecture of a diversified and hybridized age like today. The objective of this study was to understand the concepts of Allobio and Eversion, which are important digital terms forming the background of Novak's trans architecture, and to analyze architecture philosophy and architecture design concepts observed in his works through Novak's digital terminology centering on the concept of trans architecture pursued by him. Through this, we purposed to analyze the concept of architectural space, methods of form creation and the characteristics of trans architecture space, which were unique to Novak, the leader of digital architecture, and ultimately to provide basic materials on Novak. Novak's trans architecture represents digital architecture in the contemporary diversified and hybridized age, and his works involve various different digital elements and ideas, scientific paradigms, mathematic algorithms, 4 dimensional geometry, etc. In this sense, he is regarded as a prominent leading advocate of digital architecture.

Tribological Behaviour of the Si/SiC and the Si/SiC/Graphite Composites

  • Kim, In-Sub;Shin, Dong-Woo;So, You-Young;Lee, Byung-Ha
    • The Korean Journal of Ceramics
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    • v.3 no.1
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    • pp.47-51
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    • 1997
  • The dense sintered bodies of Si/SiC composite with various Si contents could be fabricated by changing the green density in the forming process. The Si/SiC/graphite composites with various graphite contents could be also fabricated by changing a graphite content in the starting composition. Their mechanical and tribological properties were characterized and wear mechanism was also studided. The hardness and strength of the Si/SiC and the Si/SiC/graphite were decreased with increasing the contents of free Si and graphite, respectively. However, the friction coefficient and specific wear rate had no specific relations to their hardness and strength. Adhesion of free Si was a main factor to determine a wear resistance of the Si/SiC composite. In the case of the Si/SiC/graphite, solid lubricationl and liquid reservoir of the graphite particles played the main role of the reduction of the friction force. In the torque test to estimate the possibility of practical of practical applications, the value of torque between the Al2O3 disk and Si/SiC/graphite disk was 1/6 lower compared with two $Al_2O_3$ disks on the basis of 100,000 cycles.

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Hot Pressing and Spark Plasma Sintering of AlN-SiC-TiB2 Systems using Boron and Carbon Additives (보론과 카본 조제를 사용한 AlN-SiC-TiB2계의 고온가압 및 Spark Plasma Sintering)

  • Lee, Sea-Hoon;Kim, Hai-Doo
    • Journal of the Korean Ceramic Society
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    • v.46 no.5
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    • pp.467-471
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    • 2009
  • Effects of boron and carbon on the densification and thermal decomposition of an AlN-SiC-$TiB_2$ system were investigated. $SiO_2$ was mostly removed by the addition of carbon, while $Al_2O_3$ formed $Al_4O_4C$ and promoted the densification of the systems above $1850^{\circ}C$. Rather porous specimens were obtained without the additives after hot pressing at $2100^{\circ}C$, while densification was mostly completed at $2000^{\circ}C$ by using the additives. The sintering temperature decreased further to $1950^{\circ}C$ by applying spark plasma sintering. The additives promoted the shrinkage of AlN by forming a liquid phase which was originated from the carbo- and boro-thermal reduction of $Al_2O_3$ and AlN.

Spray Characteristics of Gas-centered Swirl Coaxial(GCSC) Injector in High Pressure Condition (고압환경에서의 기체-액체 분사기 분무 특성 연구)

  • Kim, Jong-Gyu;Han, Yeoung-Min;Bae, Tae-Won;Choi, Hwan-Seok;Yoon, Young-Bin
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2010.11a
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    • pp.5-8
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    • 2010
  • The GCSC injectors studied in this paper are those applied to the combustion chamber of staged combustion engines. Liquid fuel is injected through tangential holes along the outer wall of the GCSC injector forming a swirling sheet and oxygen rich gas generated by a preburner enters axially through the center orifice of the injector to form a gaseous jet. The spray characteristics of GCSC injectors under ambient/high pressure conditions and the effect of recess on spray characteristics have been examined in this paper. These results are expected to be used as fundamental data to develop of a staged combustion engine.

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Phenoloxidases and Photomorphogenesis in Coprinus congregatus (Coprinus congregatus의 분화와 Phenoloxidase와의 관계)

  • 최형태
    • Proceedings of the Botanical Society of Korea Conference
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    • 1987.07a
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    • pp.157-167
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    • 1987
  • The have been many reports that phenoloxidase are correlated with development in many fungi. C. congregatus, one of nushroom-forming basidiomycetes, which requires light for its development also has phenoloxidases. In C. congragatus, there are two sets of membrane-associated phenoloxidase (PHO I and PHO II) which are differentiated by their isozyme patterns, and each enzyme set consists of two different subtrate specific enzyme protein; o-tolidine reacting enzyme, and DOPA reacting enzyme. PHO I which is localized by a protoplast-concanavalin A technique by using a new solidifying agent, Pluronic Polyol F 127, instead of agar appears in the vegetative hyphae, and PHO II appears at the early primordial stage on agar and at the sclerotial stage of liquid shake cultures. Inhibition of PHO I with the enzyme inhibitors inhibits mushroom formation as well as melanization of the vegetative hyphae at concentrations which do not inhibit the vegetative growth. PHO I deficient mutants do not form mushrooms or melanins, and the mutants show abnormal nuclear migration patterns. PHO II has roles; possibly cementing the adjacent hyphae during the actual three dimensonal structure formation, and melanizing mushrooms and sclerotia. The possible roles of PHO I in the light reception complex and in melanin formation, the function of malanin, and possible roles of postulated post translational modifying enzymes which regulate the phenoloxidases, nuclear migration pattern, and self-nonself recognition mechanism are discussed.

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