• Bulletin of the Korean Chemical Society
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• 제32권3호
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• pp.829-835
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• 2011

A dispersive liquid-liquid microextraction based on solidification of floating organic droplet (DLLME-SFO) has been developed as a new approach for the extraction of trace copper in water and beverage samples followed by the determination with flame atomic absorption spectrometry. In the DLLME-SFO, 8-hydroxy quinoline, 1-dodecanol, and methanol were used as chelating agent, extraction solvent and dispersive solvent, respectively. The experimental parameters related to the DLLME-SFO such as the type and volume of the extraction and dispersive solvent, extraction time, sample volume, the concentration of chelating agent and salt addition were investigated and optimized. Under the optimum conditions, the enrichment factor for copper was 122. The method was linear in the range from 0.5 to $300\;ng\;mL^{-1}$ of copper in the samples with a correlation coefficient (r) of 0.9996 and a limit of detection of $0.1\;ng\;mL^{-1}$. The method was applied to the determination of copper in water and beverage samples. The recoveries for the spiked water and beverage samples at the copper concentration levels of 5.0 and $10.0\;ng\;mL^{-1}$ were in the range between 92.0% and 108.0%. The relative standard deviations (RSD) varied from 3.0% to 5.6%.

• 한국추진공학회지
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• 제6권2호
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• pp.37-44
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• 2002

액체로켓엔진에 사용되는 2-유체 동축형 분사기의 분무 연소 특성을 수치적으로 해석하였다. 가스 역학적 상호작용에 의한 미립화 및 그에 따른 물리 현상들에 대해 유동에 대한 보존방정식과 이론식들을 적용, 수치화하여 액체 제트의 상태, 제트의 속도, 제트의 붕괴길이, 액적의 크기등을 예측 하였으며, 액체제트 분사공 크기에 따른 미립화의 변화를 고찰하였다. 모델 검증을 위하여 액체 제트의 접촉길이와 액적의 크기를 기존의 실험결과와 비교하였으며, 그 결과 정성적으로 일치함을 나타내었다. 액체 제트의 접촉길이는 분사공의 직경이 증가할수록 짧아지고 액적의 크기도 분사공의 직경이 증가할수록 작아진다. 액체 제트는 박리율 증가에 따른 분무화에 의하여 단면적이 감소되며, 그에 따른 질량유속의 보존과 가스로부터의 운동량 화산에 따라 미립화가 활발해지는 영역으로부터 그 속도가 급속히 증가된다.

• 대한기계학회논문집
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• 제19권12호
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• pp.3317-3328
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• 1995

The objective of the present study is to predict the characteristics of heat and mass transfer around an evaporative condenser. Numerical calculations have been performed using multi-zone method to investigate heat transfer rate and evaporation rate with the variation of inlet condition(velocity, relative humidity and temperature) of the moist air, the flow rate of the cooling water and the shape of the condenser tube. From the results it is found that the profile of heat flux is the same as that of evaporation rate since heat transfer along the gas-liquid interface is dominated by the transport of latent heat in association with the vaporization(evaporation) of the liquid film. The evaporation rate and heat transfer rate is increased as mass flow rate increases or relative humidity and temperature decrease respectively. But the flow rate of the cooling water hardly affect the evaporation rate and heat flux along the gas-liquid interface. The elliptic tube which the ratio of semi-minor axis to semi-major axis is 0.8 is more effective than the circular tube because the pressure drop is decreased. But the evaporation rate and heat flux shown independency on the tube shape.

• 대한기계학회:학술대회논문집
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• 대한기계학회 2004년도 추계학술대회
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• pp.1359-1364
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• 2004

An experiment was performed to study the evaporation heat transfer and the pressure drop characteristics of liquid nitrogen in a horizontal stainless steel tube with wire coil inserts. The inner diameter of test tube is 4.3mm and the length is 1.5m. Four wire coils having different pitch and thickness were inserted into the plain test tube. The wire coil length is 1.5m and the diameter is 3.65mm with thickness of 0.5mm and 0.9mm. Experiments were conducted at saturation temperature of $-191^{\circ}C$ mass flux from 200 to 370 $kg/m^{2}s$ and heat flux of 62 $kW/m^{2}$. Direct heating method was used to apply heat to the test section. Boiling heat transfer coefficients of both the plain and the enhanced tubes were calculated. Pressure drops between inlet and outlet side of test section were also measured, and they are used to estimate EPR(Enhancement Performance Ratio).

• 접착 및 계면
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• 제4권2호
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• pp.1-9
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• 2003

Epoxy-amine liquid prepolymers are extensively applied onto metallic substrates and cured to obtain painted materials or bonded joint structures. Overall performances of such systems depend on the created interphase between the organic layer and the substrate. When epoxy-amine liquid mixtures are applied onto more or less hydrated metallic oxide layer, concomitant amine chemical sorption and hydroxide dissolution appear lending to the chelate formation. As soon as the chelate concentration is higher than the solubility product, these species crystallize as sharp needles. Moreover, intrinsic and thermal residual stresses are developed within painted or bonded systems. When residual stresses are higher than the organic layer/substrate adhesion, buckling, blistering, debonding may occur leading to a catastrophic drop of system performances. Practical adhesion can be evaluated with either ultimate parameters (Fmax or Dmax) or the critical strain energy release rate, using the three point flexure test (ISO 14679-1997). We observe that, for the same system, the ultimate load decreases while residual stresses increase when the liquid/solid time increases. Ultimate loads and residual stresses depend on the metallic surface treatment. For these systems, the critical strain energy release rate which takes into account the residual stress profile and the Young's modulus gradient remains quite constant whatever the metallic surface treatment was. These variations will be discussed and correlate to the formation mechanisms of the interphase.

• 한국추진공학회:학술대회논문집
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• 한국추진공학회 2006년도 제27회 추계학술대회논문집
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• pp.191-195
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• 2006

우주 발사체의 성공적인 비행을 위해서는 로켓 엔진의 성능 분산 관리가 필수적이다. 양산되는 엔진의 성능편차를 정량적으로 예측하기 위한 해석을 수행하고 성능영향계수를 이용하여 보정에 필요한 차압을 산출하였다. 별도의 추력제어 시스템을 갖추지 않은 엔진의 진공 추력 분산은 +9.1%, -8.7%로 나타났으며 엔진 혼합비 오차는 +9.7%, -9.6%에 달했다. 보정에 필요한 요구차압은 동일한 혼합비 보정에 대해 연소기 배관 산화제 측에서 더 작게 나타났으나 가스발생기 배관의 요구차압은 더 크게 요구된다.

• 한국분무공학회지
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• 제11권3호
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• pp.168-175
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• 2006

The static pressure distribution and flow characteristics inside the high-pressure swirl spray were investigated by measuring the static pressure inside the spray and applying the computational fluid dynamics (CFD). The static pressure difference between inner and outer part of spray was measured at different axial locations and operating conditions using a piezo-resislive pressure transducer. To obtain the qualitative value of swirl motion at different operating conditions, the spray impact-pressure at the nozzle exit was measured using a piezo-electric pressure transducer, and the flow angle was measured using a microscopic imaging system. The flow characteristics inside the high pressure swirl spray was simulated by the 1-phase 3-dimensional CFD model. The effect of pressure alternations on spray development was discussed with macroscopic spray images and a mathematical liquid film model. The results showed that the static pressure drop is observed inside the swirl spray as a result of the dragged air motion and the centrifugal force of the air. The recirculation vortex inside the spray was also observed inside the swirl spray as a result of the adverse pressure gradient along the axial locations. The results of analytical liquid film model and macroscopic spray images showed that the static pressure structure is one of the main parameters affecting the swirl spray development.

• 대한기계학회논문집B
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• 제26권1호
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• pp.45-54
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• 2002

The breakup phenomena of a vertical laminar jet issuing from capillary tubes in a quiescent ambient air are investigated using a forced vibration analysis of the surface wave. Using a linear approach to the transient jet velocity, an approximate solution fur the longitudinal motion of a vertical liquid jet is theoretically derived, thus performing an instability analysis by a vibration method. The damping term of this equation is nonlinear as it depends on dimensionless parameters, a Weber number, and an Ohnesorge number. The instability condition is determined based on whether the coefficient of the damping term is less than zero or not. Uniform drop formation is dependent on the vibration frequency fur the forced vibration case.

• 한국항공우주학회지
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• 제40권9호
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• pp.781-788
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• 2012

공개소스 전산유체 해석 라이브러리인 OpenFOAM을 이용하여 액체 로켓 연소기의 산화제 매니폴드 내 유동 해석을 수행하였다. 정상 상태의 비압축성 난류 유동 해석을 통하여 분사기 차압 모사를 위한 다공성 매질 영역이 포함된 복잡한 3차원 형상에 대한 유동해석에 있어서의 OpenFOAM 적용 가능성을 평가하였다. 향후 로켓 연소장치 내의 주요 물리적 현상을 포함한 보다 다양한 해석 사례에 대한 평가를 수행함으로써 설계 평가 및 해석 도구로서의 OpenFOAM의 유용성 및 적용 범위를 확인/확대해나갈 계획이다.

• 한국분무공학회지
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• 제12권3호
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• pp.146-153
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• 2007

The prediction of diesel spray penetration has been the subject of several works and intensive investigations are still underway by many researchers. It is required to summarize the correlations developed before 1990 days and to introduce the correlations reported recently in the literature. The existing zero-dimensional models for the prediction of diesel fuel spray penetration can be classified as theoretical and empirical correlations. Of various correlations, the models considered in this paper were selected as based on the evaluation results of previous reviews and the recently published works in the literature. The existing theoretical correlations can be classified into seven categories and the existing empirical ones as two categories in this review. According to the review of existing models, the dominating factors for the prediction of spray tip penetration are the spray angle, discharge coefficient, pressure drop across nozzle, ambient density and orifice diameter and time after the start of injection. Especially, the definition for the measurement of spray angle is different with researchers. It is required to evaluate the existing spray tip penetration models for the very high injection pressure and other fuel sprays such as DME. It is also required to evaluate the correlations for the prediction of diesel spray penetration with the connection of liquid-phase penetration.