• Title/Summary/Keyword: Liquid Metal

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Separation of Pd(Ⅱ) and Pb(Ⅱ) Using (Allyloxy)methyl-Crown Ethers in a Bulk Liquid Membrane System ((Allyloxy)methyl-Crown Ether를 이용한 액체막계에서의 Pd(Ⅱ) 및 Pb(Ⅱ)의 분리)

  • Lee, Yong Gu;Cho, Hyun Sung;Kim, Tae Soon;Lee, Dong Koo;Kim, Eung Tae;Cho, Moon Hwan;Lee, Young K.;Chae, Young Bok
    • Journal of the Korean Chemical Society
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    • v.41 no.9
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    • pp.460-464
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    • 1997
  • (Allyloxy)methyl-Crown Ethers have been used as metal cation carriers in a bulk liquid membrane system. Competitive transports by the AMDT18C6 and the AM18C6 are selective for Pd(Ⅱ) ion and Pb(Ⅱ) ion over other transition metal cations respectively. Studies of complexations of (Allyloxy)methyl-Crown Ethers with metal cations have been carried out by titration calorimetry and potentiometry.

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Conceptual Design of In-Service Inspection and Maintenance of tiquid Metal Reactor KALIMER (액체금속로 KALIMER의 가동중검사 및 보수 개념설계)

  • Joo, Young-Sang;Kim, Seok-Hoon;Lee, Jae-Han
    • Journal of the Korean Society for Nondestructive Testing
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    • v.24 no.2
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    • pp.171-179
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    • 2004
  • The design concepts of in-service inspection and maintenance are very important for the reactor system design of the nuclear power plant. The strategy of in-service inspection and maintenance should be reflected in the mechanical system design for the verification of the operability of liquid metal reactor KALIMER. In this paper the fundamental approaches of the in-service inspection and maintenance of the KALIMER are established to ensure the safety and reliability of the reactor system. The general method and requirement of the in-service inspection and maintenance for the reactor system and components are proposed and described to satisfy the intents of the ASME Section XI Division 3 and the design characteristics of KALIMER.

Shape Control of Platinum Nanoparticles Using a Metal Salt (금속 염을 이용한 백금 나노입자의 형상제어)

  • Kwak, Seoung Yeul;Lee, Jin Ho;Kim, Jin Woo;Jung, Taek Kyun;Kim, Young Do
    • Journal of Powder Materials
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    • v.19 no.6
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    • pp.393-397
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    • 2012
  • $AgNO_3$ has the characteristic is controlling the inhibition or promotion of particle growth by adsorbing onto specific facets of platinum nanoparticles. Therefore, in this study, $AgNO_3$ was added to control the shape of platinum nanoparticles during the liquid phase reduction process. Consequently, platinum cubes were synthesized when $AgNO_3$ of 1.1 mol% (with respect to the Pt concentration) was added into the solution. Platinum octahedrons were synthesized when 32 mol% (with respect to the Pt concentration) was added into the solution. These results demonstrate that the metal salt $AgNO_3$, effectively controlled the relative growth rates of each facet of Pt nano particles.

Dielectric $Al_2O_3-SiO_2$ Films from Metal Alkoxides

  • Soh, Deawha;Natalya, Korobova E.
    • Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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    • 2003.10a
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    • pp.957-962
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    • 2003
  • The preparation of $Al_2$O$_3$-SiO$_2$ thin films from less than one micron to several tens of microns in thickness had been prepared from metal alkoxide sols. Two methods, dip-withdrawal and electrophoretic deposition, were employed for thin films and sheets formation. The requirements to be satisfied by the solution for preparing uniform and strong films and by the factors affecting thickness and other properties of the films were examined. for the preparation of thin, continuous $Al_2$O$_3$-SiO$_2$ films, therefore, metal-organic-derived precursor solutions contained Si and Al in a chemically polymerized form has been developed and produced in a clear liquid state. In the process of applying to substrates, this liquid left a transparent, continuous film that could be converted to crystalline $Al_2$O$_3$-SiO$_2$ upon heating to 100$0^{\circ}C$. And, a significant change of the film density took place in the crystallization process, thus leading to the strict requirements as to the film thickness, which could survive crystallization.

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Effect of Oxidation Behavior of (Nd,Dy)-Fe-B Magnet on Heavy Rare Earth Extraction Process

  • Park, Sangmin;Nam, Sun-Woo;Lee, Sang-Hoon;Song, Myung-Suk;Kim, Taek-Soo
    • Journal of Powder Materials
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    • v.28 no.2
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    • pp.91-96
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    • 2021
  • Rare earth magnets with excellent magnetic properties are indispensable in the electric device, wind turbine, and e-mobility industries. The demand for the development of eco-friendly recycling techniques has increased to realize sustainable green technology, and the supply of rare earth resources, which are critical for the production of permanent magnets, are limited. Liquid metal extraction (LME), which is a type of pyrometallurgical recycling, is known to selectively extract the metal forms of rare earth elements. Although several studies have been carried out on the formation of intermetallic compounds and oxides, the effect of oxide formation on the extraction efficiency in the LME process remains unknown. In this study, microstructural and phase analyses are conducted to confirm the oxidation behavior of magnets pulverized by a jaw crusher. The LME process is performed with pulverized scrap, and extraction percentages are calculated to confirm the effect of the oxide phases on the extraction of Dy during the reaction. During the L ME process, Nd is completely extracted after 6 h, while Dy remains as Dy2Fe17 and Dy-oxide. Because the decomposition rate of Dy2Fe17 is faster than the reduction rate of Dy-oxide, the importance of controlling Dy-oxide on Dy extraction is confirmed.