• 한국지반환경공학회 논문집
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• 제10권4호
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• pp.25-31
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• 2009

본 연구의 목적은 기존 흙 포장의 문제점인 장기적인 내구성 결여 및 균열발생을 보완한 친환경적 흙포장재를 개발하기 위한 것이다. 액상형태의 혼합이 용이한 무기질 결합재와 화강풍화토를 첨가량별로 배합하여 일축압축시험 및 투수시험을 실시하였다. 시험결과에 따라 적정 배합비를 산정하고 6가크롬($Cr^{6+}$)검출시험, 재령별 SEM촬영, 동결융해시험을 실시하여 적정성을 검증하였다. 연구 결과, 분말형 무기계 결합재의 배합비는 시멘트:플라이애시:석고의 비율이 각각 50:33:7이 가장 적합한 것으로 판단되었다. 그리고 6가크롬($Cr^{6+}$) 검출시험결과 6가크롬($Cr^{6+}$)의 발생량이 미미하였고, SEM촬영 결과 재령 3일에 에트린자이트 형성이 확인되어 재료가 화학적으로 조기강도 발현이 가능함을 알 수 있었다.

• 한국도로학회논문집
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• 제16권4호
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• pp.45-50
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• 2014

PURPOSES : The objective of this study is to analyze the performance of anti-stripping agent depending on its type and content to reduce pothole, an increasing pavement distress due to abnormal climate intensity. METHODS : In the past years, U.S and many countries in Europe use hydrated lime and liquid anti-stripping agent in asphalt mixtures. Hydrated lime or liquid anti-stripping agent is substituted for filler and binder, respectively, to improve the anti-stripping property of asphalt mixtures. To investigate this, indirect tensile strength test was performed and TSR values were compared for different content of hydrated lime and types of liquid anti-stripping agent in asphalt mixture. RESULTS : Test results indicate that hydrated lime remarkably increased the asphalt mixture performance on anti-stripping denoted by the increased in TSR values from 55% to 100%. Liquid anti-stripping agent also increased the value of TSR but not significant. In addition, depending on the types of aggregate, TSR values and effect of liquid anti-stripping were different. CONCLUSIONS : Using anti-stripping agents improve the anti-stripping property of asphalt mixture especially hydrated lime; however, more experiments should be conducted to improve the reliability about the effect of liquid anti-stripping agent.

• 한국추진공학회지
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• 제4권2호
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• pp.1-5
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• 2000

추진제의 기계적 특성을 증진시키고 점도를 낮추기 위하여 소량의 coupling agent인 silane 화합물이 적용되어왔다. silane 화합물 적용시 PEG(polyethylene glycol)계 추진제에서는 그 효과가 크게 나타났으나, PCP(polycaprolactone)계 추진제에서는 오히려 기계적 특성이 감소될 뿐 아니라 경화반응에도 심각한 문제를 일으키고 있다. 본 연구에서는 이러한 문제점을 규명하기 위하여 silane 화합 물로 TESPN(triethoxysilyl propionitrile)을 PEG, PCP 바인더에 적용하여 연구하였다. 그 원인은 silane의 alkoxy 그룹이 바인더 용액의 수분과 반응을 하여 생성된 alcohol이 PCP의 ester기와 trans-esterification 반응으로 주 사슬이 끊어지는 현상이었다.

• 한국건축시공학회지
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• 제11권6호
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• pp.538-546
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• 2011

This paper is to experimentally investigate the strength and autogenous shrinkage of high strength mortar with the 20 % of water?binder ratio(W/B). In this study, the water substituting liquid(WSL) was used including gasoline, light oil, lamp oil, edible oil, HFE, ethanol, methanol and acetone in order to explore changes in strength and autogenous shrinkage depending on WSL type and replacement. For fresh properties, the replacement of WSL did not affect the fluidity of mortar mixtures considerably, except for ethanol and methanol. However, the replacement of WSL resulted in a slight decrease in flexural and compressive strength. For autogenous shrinkage, the replacement of WSL led to reduce autogenous shrinkage, and especially, the replacement of edible oil led to reduce autogenous shrinkage significantly due to saponification between edible oil and cement.

• Bulletin of the Korean Chemical Society
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• 제29권5호
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• pp.915-920
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• 2008

In this paper the electrochemical behaviors of hydroquinone ($H_2Q$) were investigated on a carbon paste electrode using room temperature ionic liquid N-butylpyridinium hexafluorophosphate ($BPPF_6$) as binder (ILCPE) and further applied to $H_2Q$ determination. In pH 2.5 phosphate buffer solution (PBS), the electrochemical response of H2Q was greatly improved on the IL-CPE with a pair of well-defined quasi-reversible redox peaks appeared, which was attributed to the electrocatalytic activity of IL-CPE to the $H_2Q$. The redox peak potentials were located at 0.340 V (Epa) and 0.240 V (Epc) (vs. the saturated calomel electrode, SCE), respectively. The formal potential ($E^0$') was calculated as 0.290 V and the peak-to-peak separation (${\Delta}E_p$) was 0.100 V. The electrochemical parameters of $H_2Q$ on the IL-CPE were further calculated by cyclic voltammetry. Under the selected conditions the anodic peak current was linear with $H_2Q$ concentration over the range from $5.0\;{{\times}}\;10^{-6}$ to $5.0\;{\times}\;10^{-3}\;mol\;L^{-1}$ with the detection limit as $2.5\;{\times}\;10^{-6}\;mol\;L^{-1}$ (3$\sigma$ ) by cyclic voltammetry. The proposed method was successful applied to determination of $H_2Q$ content in a synthetic wastewater sample without the interferences of commonly coexisting substances.

• 한국분말재료학회지
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• 제6권4호
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• pp.294-300
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• 1999

This study was carried out to investigate the possibility whether Metal Injection Molding (MIM) process could be applied to 95wt.%W-3.5wt.%Ni-1.5wt.%Fe heavy alloy in order to obtain an intricate shape. Methylcellulose was used in the injection molding for binder. $FeCl_2-4H_2O$ was added in solvent substituting Fe powder and $FeCl_2$ was doped on W-Ni premixed powder. When $FeCl_2-4H_2O$ was added in solvent, the binder separation occurred for injection molding so that the matrix content was changed. Such problem was solved when $FeCl_2$ was doped. In this study. the debinding process did not affect residual carbon content. The sintered microsouctures as addition methods of Fe element and the sintering temperature from $1420^{\circ}C$ to $1470^{\circ}C$, which are around the temperature of liquid phase formation, were observed.

• 한국인쇄학회지
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• 제22권2호
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• pp.139-150
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• 2004

Development of the paper coating technologies to prevent print mottle is needed to obtain high quality printing. Printing mottle is recognized as the most common printing problems in using coated paper and which is one of the most difficult problems to solve in offset printing. Print mottle is one of the most important quality properties of printed products and manufacturers strive to improve the paper surface to gain higher and more even print mottle. The prevention of printed mottle requires of coating color formation, especially the minimum of binder migration. The results the uniformity of liquid absorption by paper at very short contact time between paper and testing printing liquids.

• International Journal of Concrete Structures and Materials
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• 제3권2호
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• pp.97-101
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• 2009

It has been known that acid-resistant concretes on the liquid glass basis have high porosity (up to 18${\sim}$20%), low strength and insufficient water resistance. Therefore they can not be used as materials for load-bearing structural elements. Significant increasing of silicate matrix strength and density was carried out by incorporation of special liquid organic alkali-soluble silicate additives, which block of superficial pores and reduces concrete shrinkage deformation. It was demonstrated that introduction of tetrafurfuryloxisilane additive sharply increases strength, durability and shock resistance of silicate polymer concrete in aggressive media. This effect is attributable to hardening of contacts between silicate binder gel globes and modification of alkaline component owing to "inoculation" of the furan radical. The optimal concrete composition with the increased strength, chemical resistance in the aggressive environments, density and crack resistance was obtained.

• 대한기계학회논문집B
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• 제23권7호
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• pp.811-819
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• 1999

A theoretical model to predict the effective thermal conductivity of sands Is developed by considering the participating heat transfer mechanisms and their relationship to the model geometry. Comparison between the calculations and the measurements indicates that the assumptions to introduce two model constants (${\phi}_{af}$ and ${\delta}$) for model development were justified. As a results, the model was proved to predict the effective thermal conductivities of 2- and 3-component systems of two silica sands saturated with fluids or bonded with liquid binders in a reasonable accuracy.

• Computers and Concrete
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• 제9권6호
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• pp.427-437
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• 2012

This article presents the effect of replacement fly ash (FA) with diatomite (DE) on the properties of geopolymer mortars. DE was used to partially replace FA at the levels of 0, 60, 80 and 100% by weight of binder. Sodium silicate ($Na_2SiO_3$) and sodium hydroxide (NaOH) solutions were used as the liquid portion in the mixture in order to activate the geopolymerization. The NaOH concentrations of 15M, $Na_2SiO_3$/NaOH ratios of 1.5 by weight, and the alkaline liquid/binder (LB) ratios by weight of 0.40, 0.50, 0.60 and 0.70 were used. The curing at temperature of $75^{\circ}C$ for 24 h was used to accelerate the geopolymerization. The flows of all fresh geopolymer mortars were tested. The compressive strengths and the stress-strain characteristics of the mortar at the age of 7 days, and the unit weights were also tested. The results revealed that the use of DE to replace part of FA as source material in making geopolymer mortars resulted in the increased in the workability, and strain capacity of mortar specimens and in the reductions in the unit weights and compressive strengths. The strain capacity of the mortar increased from 0.0028 to 0.0150 with the increase in the DE replacement levels from 0 to 100%. The mixes with 15M NaOH, $Na_2SiO_3$/NaOH of 1.5, LB ratio of 0.50, and using $75^{\circ}C$ curing temperature showed 7 days compressive strengths 22.0-81.0 MPa which are in the range of normal to high strength mortars.