• Transactions of the Korean hydrogen and new energy society
• /
• v.23 no.3
• /
• pp.227-235
• /
• 2012

Finding an alternative fuel and reducing environmental pollution are the main goals for future internal combustion engines. The purpose of this study is to obtain low-emission and high-efficiency by hydrogen enriched LPG fuel in constant volume chamber. An experimental study was carried out to obtain fundamental data for the combustion and emission characteristics of pre-mixed hydrogen and LPG in a constant volume chamber (CVC) with various fractions of hydrogen-LPG blends. To maintain equal heating value of fuel blend, the amount of LPG was decreased as hydrogen was gradually added. Exhaust emissions were measured using a HORIBA exhaust gas analyzer for various fractions of hydrogen-LPG blends. The results showed that the rapid combustion duration was shortened, and the rate of heat release elevated as the hydrogen fraction in the fuel blend was increased. Moreover, the maximum rate of pressure rise also increased. These phenomena were attributed to the burning velocity which increased exponentially with the increased hydrogen fraction in the $H_2$-LPG fuel blend. Exhaust HC and $CO_2$ concentrations decreased, while NOX emission increased with an increase in the hydrogen fraction in the fuel blend. Our results could facilitate the application of hydrogen and LPG as a fuel in the current fossil hydrocarbon-based economy and the strict emission regulations in internal combustion engines.

• Transactions of the Korean hydrogen and new energy society
• /
• v.33 no.5
• /
• pp.534-540
• /
• 2022

Liquid hydrogen has the best storage capacity per unit mass and is economical among storage methods for using hydrogen as fuel. As the demand for hydrogen increases, the need to develop a storage and supply system of liquid hydrogen is emphasizing. In order to liquefy hydrogen, it is necessary to pre-cool it to a maximum inversion temperature of -253℃. The Gifford-McMahon (GM) refrigerator is the most reliable and commercialized refrigerator among small-capacity cryogenic refrigerators, which can extract high-efficiency hydrogen through liquefied hydrogen production and boil of gas re-liquefaction. Therefore, in this study, the optimal conditions for liquefying gas hydrogen were sought using the GM cryocooler. The process was simulated by PRO/II under various cooling capacities of the GM refrigerator. In addition, the flow rate of hydrogen was calculated by comparing with specific refrigerator capacity depending on the pressure and flow rate of a refrigerant medium, helium. Simulations were performed to investigate the optimal values of the liquefaction flow rate and compression pressure, which aim for the peak refrigeration effect. Based on this, a liquefaction system can be selected in consideration of the cycle configuration and the performance of the refrigerator.

• Journal of Aerospace System Engineering
• /
• v.18 no.3
• /
• pp.8-16
• /
• 2024

Because hydrogen has very low density, a different storage method is required to store the same amount of energy as fossil fuel. One way to increase the density of hydrogen is through liquefaction. However, since the liquefied temperature of hydrogen is extremely low at -252 ℃, it is easily vaporized by external heat input. When liquid hydrogen is vaporized, a self-pressurizing phenomenon occurs in which the pressure inside the hydrogen tank increases, so when designing the tank, this rising pressure must be carefully predicted. Therefore, in this paper, the internal pressure of a cryogenic liquid fuel tank was predicted according to the liquid hydrogen filling ratio. A one-dimensional thermodynamic model was applied to predict the pressure rise inside the tank. The thermodynamic model considered heat transfer, vaporization of liquid hydrogen, and fuel discharging. Finally, it was confirmed that there was a significant difference in pressure behavior and maximum rise pressure depending on the filling ratio of liquid hydrogen in the fuel tank.

• Journal of the Korean Society of Industry Convergence
• /
• v.26 no.5
• /
• pp.875-884
• /
• 2023

Hydrogen infiltration into metals has been reported to induce alterations in their mechanical properties under load. In this study, we conducted CTOD (Crack Tip Opening Displacement) tests on steel specimens designed for use in liquid hydrogen storage systems. Electrochemical hydrogen charging was performed using both FCC series austenitic stainless steel and BCC series structural steel specimens, while CTOD testing was carried out using a 500kN-class material testing machine. Results indicate a notable divergence in behavior: SS400 test samples exhibited a higher susceptibility to failure compared to austenitic stainless steel counterparts, whereas SUS 316L test samples displayed minimal changes in displacement and maximum load due to hydrogen charging. However, SEM (Scanning Electron Microscopy) analysis results presented challenges in clearly explaining the mechanical degradation phenomenon in the tested materials. This study's resultant database holds significant promise for enhancing the safety design of liquid hydrogen storage systems, providing invaluable insights into the performance of various steel alloys under the influence of hydrogen embrittlement.

• Transactions of the Korean hydrogen and new energy society
• /
• v.30 no.6
• /
• pp.490-498
• /
• 2019

The intermittent electric power supply of renewable energy can have extremely negative effect on power grid, so long-term and large-scale storage for energy released from renewable energy source is required for ensuring a stable supply of electric power. Power to gas which can convert and store the surplus electric power as hydrogen through water electrolysis is being actively studied in response to increasing supply of renewable energy. In this paper, we proposed the novel concept of hydrogen liquefaction process combined with pre-cooling process using the liquid air. It is that hydrogen converted from surplus electric power of renewable energy was liquefied through the hydrogen liquefaction process and vaporization heat of liquid hydrogen was conversely recovered to liquid air from ambient air. Moreover, Comparisons of specific energy consumption (kWh/kg) saved for using the liquid air pre-cooling was quantitatively conducted through the performance analysis. Consequently, about 12% of specific energy consumption of hydrogen liquefaction process was reduced with introducing liquid air for pre-cooling and optimal design point of helium Brayton cycle was identified by sensitivity analysis on change of compression/expansion ratio.

• Composites Research
• /
• v.37 no.1
• /
• pp.32-39
• /
• 2024

Solid-state hydrogen storage is gaining prominence as a crucial subject in advancing the hydrogen-based economy and innovating energy storage technology. This storage method shows superior characteristics in terms of safety, storage, and operational efficiency compared to existing methods such as compression and liquefied hydrogen storage. In this study, we aim to evaluate the solid hydrogen storage performance on the nanotube surface by various structural design factors. This is accomplished through molecular dynamics simulations (MD) with the aim of uncovering the underlying ism. The simulation incorporates diverse carbon nanotubes (CNTs) - encompassing various diameters, multi-walled structures (MWNT), single-walled structures (SWNT), and boron-nitrogen nanotubes (BNNT). Analyzing the storage and effective release of hydrogen under different conditions via the radial density function (RDF) revealed that a reduction in radius and the implementation of a double-wall configuration contribute to heightened solid hydrogen storage. While the hydrogen storage capacity of boron-nitrogen nanotubes falls short of that of carbon nanotubes, they notably surpass carbon nanotubes in terms of effective hydrogen storage capacity.

• Transactions of the Korean hydrogen and new energy society
• /
• v.33 no.6
• /
• pp.827-837
• /
• 2022

If the hydrogen industry is activated, the introduction of C-type and pressurized liquefied hydrogen (LH2) tank suitable for small and medium-sized transp- ortation and storage will be given priority in the future. Therefore in this paper, the behavior for the LH2 property changes and boil-off gas (BOG) treatment of the C-type cargo tank through voyage of the LH2 carrier and pressurized tank of the LH2 receiving terminal were analyzed through computational simulations by making assumptions about the carrier operation and unloading conditions.

• Transactions of the Korean hydrogen and new energy society
• /
• v.12 no.3
• /
• pp.169-176
• /
• 2001

The purpose of study is to obtain low-emission and high-efficiency in LPG engine with hydrogen enrichment. The test engine was named heavy-duty variable compression ratio single cylinder engine (VCSCE). The fuel supply system provides LPG/hydrogen mixtures based on same heating value. Various sensors such as crank shaft position sensor (CPS) and hall sensor supply spark timing data to ignition controller. Displacement of VCSCE is $1858.2cm^3$. VCSCE was runned 1400rpm with compression ratio 8. Spark timing was set MBT without knocking. Relative air-fuel ratio(${\lambda}$) of this work was varied between 0.76 and 1.5. As a result, i) Maximum thermal efficiency occurred at ${\lambda}$ value 1.0. It was shown that thermal efficiency was increased approximately 5% with hydrogen enrichment at same ${\lambda}$ value. ii) Engine-out carbon monoxide (CO) emissions were decreased at a great rate under LPG/hydrogen mixture fuelling. iii) Total hydrocarbon (THC) emission was much exhausted in rich zone, same as CO. But THC was exhausted a little bit more in lean zone. iv) Finally, engine-out oxides of nitrogen (NOx) was increased with ${\lambda}$ value 1.0 zone at a greater rate with hydrogen enrichment due to high adiabatic flame temperature.

• Transactions of the Korean hydrogen and new energy society
• /
• v.31 no.4
• /
• pp.363-371
• /
• 2020

Recently, the technologies to utilize the cold energy of liquefied natural gas (LNG) have attracted significant attention. In this paper, thermodynamic performance analysis of combined cycles consisting of ammonia Rankine cycle (AWR) and organic Rankine cycle (ORC) with LNG Rankine cycle to recover low-grade heat source and the cold energy of LNG. The mathematical models are developed and the effects of the important system parameters such as turbine inlet pressure, ammonia mass fraction, working fluid on the system performance are systematically investigated. The results show that the thermal efficiency of AWR-LNG cycle is higher but the total power production of ORC-LNG cycle is higher.

• Transactions of the Korean hydrogen and new energy society
• /
• v.30 no.4
• /
• pp.297-302
• /
• 2019

In this paper, the power generation efficiency increase has been studied for a Rankine cycle using both supercritical carbon dioxide as a working fluid and LNG as a coolant with PRO/II with PROVISION release 10.0 from Aveva company. Peng-Robinson equation of the state model with Twu's alpha function was selected for the modeling of the power generation cycle using LNG cold heat. Power generation efficiency was increased from 24.82% to 57.76% when using LNG as a coolant for supercritical carbon dioxide power generation cycle.